Removal of heavy metals from wastewaters by use of natural zeolites
by
 
Türkmen, Müşerref.

Title
Removal of heavy metals from wastewaters by use of natural zeolites

Author
Türkmen, Müşerref.

Personal Author
Türkmen, Müşerref.

Publication Information
[s.l.]: [s.n.], 2001.

Physical Description
x, 72 leaves.: ill.+ 1 computer laser optical disc.

Abstract
In the present study, clinoptilolite rich local natural zeolite was proposed as an ion-exchanger for the removal of heavy metals (Pb2+, Cu2+, Zn2+) from wastewaters.Natural zeolite samples were exposed to a simple pretreatment process which included washing and drying to remove impurities and dust.Thermal and adsorption related properties of washed and original zeolite samples were determined by TGA and N2 adsorption analyses. In TGA analyses, average water content for washed and original samples were found as 9.44 and 10.13 % respectively. In N2 adsorption studies, both washed and original samples showed the characteristic Type IIb isotherm. BET surface areas of the samples were calculated as 39.73 and 47.72 m2/g for washed and original samples respectively.Pretreatment process was found to improve the adsorption capacity of clinoptilolite due to the removal of impurities and dust.In ion-exchange studies, efficiency of natural zeolite in removal of heavy metals from the solutions was investigated based on some physical and chemical variables. For this purpose, particle size and the amount of zeolite in the solution, contact time of the metal containing solution with zeolite were selected as physical variables and pH, metal concentration of the solution, and the presence of other ions were selected as chemical variables. The chemical analyses of all exchange solutions were performed by using ICP-AES. Removal % of the metal ions from the solutions were obtained. Based on the experimental results, zeolite exhibited a significant affinity to Pb2+, followed by Cu2+ and Zn2+ even in the presence of competing cations.To test the applicability of natural zeolite for the treatment of Acid Mine Drainage (AMD), zeolite samples were allowed to contact with simulated AMD solutions.Consequently, natural zeolite was found to be an efficient ion exchanger for removing lead, copper and zinc ions from aqueous solutions.

Subject Term
Water -- Purification -- Ion exchange process
 
Ion-exchange.
 
Sevage -- Purification -- Heavy metals removal.
 
Zeolites.

Added Author
Ülkü, Semra

Added Corporate Author
İzmir Institute of Technology. Environmental Engineering.

Added Uniform Title
Thesis (Master)--İzmir Institute of Technology: Environmental Engineering.
 
İzmir Institute of Technology: Environmental Engineering--Thesis (Master).

Electronic Access
Access to Electronic Version


LibraryMaterial TypeItem BarcodeShelf NumberStatus
IYTE LibraryThesisT000028TD468 .T87 2001Tez Koleksiyonu
IYTE LibrarySupplementary CD-ROMROM0690TD468 .T87 2001 EK1Tez Koleksiyonu