Cover -- Handbook of Electrochemistry -- Copyright page -- Preface -- Contents -- Corresponding Authors -- Part I: Fundamentals -- Chapter 1. Fundamentals -- 1.1 Conventions in Electrochemistry -- 1.2 Terminology -- 1.3 Fundamental Equations -- 1.4 Factors Affecting Reaction Rate and Current -- 1.5 Equations Governing Modes of Mass Transfer -- 1.6 Electrochemical Cells -- 1.7 Cell Resistance -- Capacitance -- Uncompensated Resistance -- 1.8 Overview of Electrochemical Experiments -- 1.9 Electrochemistry Literature -- Textbooks -- Specialized Books -- References -- Part II: Laboratory Practical -- Chapter 2. Practical Electrochemical Cells -- 2.1 Materials -- 2.2 General Cell Designs -- 2.3 Electrochemical Cells for Specific Applicatons -- 2.4 Establishing and Maintaining an Inert Atmosphere -- References -- Chapter 3. Solvents and Supporting Electrolytes -- 3.1 Introduction -- 3.2 Electrolyte Conductivity -- 3.3 Cells, Electrodes, and Electrolytes -- 3.4 Cell Time Constants -- 3.5 Solvents -- 3.6 Salts -- 3.7 "Exotic" Electrolytes -- 3.8 Purification Procedures for some Commonly Used Solvents in Electrochemistry -- 3.9 Purification Procedures for some Commonly Used Salts in Electrochemistry -- References -- Chapter 4. Reference Electrodes -- 4.1 Introduction -- 4.2 Basic Components of a Reference Electrode -- 4.3 Electrode Details and Fabrication -- 4.4 Junctions -- 4.5 Reference Electrodes: Nonaqueous Solvents -- 4.6 Reference Electrode Calibration -- 4.7 Maintenance -- 4.8 Troubleshooting -- References -- Chapter 5. Solid Electrode Materials: Pretreatment and Activation -- 5.1 Introduction -- 5.2 Carbon Electrodes -- 5.3 Metal Electrodes -- 5.4 Semiconductor Electrodes -- 5.5 Conclusions -- Acknowledgments -- References -- Chapter 6. Ultramicroelectrodes -- 6.1 Behavior of Ultramicroelectrodes -- References -- 6.2 Microelectrode Applications.

References -- 6.3 UME Fabrication/Characterization Basics -- References -- References -- References -- References -- References -- References -- References -- References -- References -- References -- References -- Chapter 7. Potentiometric Ion-Selective Electrodes -- 7.1 Introduction -- 7.2 Classification and Mechanism -- 7.3 Equilibrium Potentiometric Responses -- 7.4 Non-Equilibrium Potentiometric Responses -- 7.5 Conclusions -- References -- Chapter 8. Chemically Modified Electrodes -- 8.1 Introduction -- 8.2 Substrate Materials and Preparation -- 8.3 Modified Electrode Types -- 8.4 Conclusions and Prospects -- References -- Chapter 9. Semiconductor Electrodes -- 9.1 Introduction -- 9.2 Semiconductor Basics -- 9.3 Energetics of a Semiconductor -- 9.4 Semiconductor Electrodes -- 9.5 Types of Semiconductor Electrodes -- 9.6 Nanostructured Semiconductor Electrodes (NSSE) -- 9.7 Semiconductor Electrode Applications -- Acknowledgments -- References -- Chapter 10. Microelectrode Arrays -- 10.1 Introduction -- 10.2 Classification of Microelectrode Arrays -- 10.3 Theory: Diffusion at Microelectrode Arrays -- 10.4 Fabrication of Microelectrode Arrays -- 10.5 Electrochemical Characterisation of Microelectrode Arrays -- 10.6 Conclusion and Prospects -- References -- Part III: Techniques -- Chapter 11. Classical Experiments -- 11.1 Introduction -- 11.2 Selected Experimental Techniques -- 11.3 Simulations -- 11.4 Trouble Shooting Electrochemical Experiments:A Checklist -- References -- Chapter 12. Scanning Electrochemical Microscopy -- 12.1 Introduction and Principles -- 12.2 Instrumentation -- 12.3 Methods and Operational Modes -- 12.4 Applications -- References -- Chapter 13. Electrogenerated Chemiluminescence -- 13.1 Concepts and History -- 13.2 Types of Luminescence -- 13.3 Fundamental Reactions -- 13.4 Experimental Setup -- 13.5 Types of Experiments.

13.6 Applications -- Acknowledgments -- References -- Chapter 14. Spectroelectrochemistry -- 14.1 Introduction -- 14.2 Light Transmission and Reflection at an Electrode Surface -- 14.3 Electronic Spectroscopy -- 14.4 Luminescence Spectroelectrochemistry -- 14.5 Vibrational Spectroelectrochemistry -- 14.6 Outlook -- References -- Part IV: Applications -- Chapter 15. Determination of Electrode Kinetics -- 15.1 Introduction to Kinetic Measurements -- 15.2 Heterogeneous Electron Transfer: Transient Methods -- 15.3 Heterogeneous Electron Transfer: Steady-State Methods -- 15.4 Processes with Coupled Homogeneous Reactions -- References -- Chapter 16. Metal Deposition -- 16.1 Electrodeposition of Nanostructures and Microstructures on Highly Oriented Pyrolytic Graphite (HOPG) -- References -- 16.2 Template Deposition of Metals -- References -- 16.3 Single Particle Deposition on Nanometer Electrodes -- References -- Chapter 17. Electrochemistry in Small Places and at Novel Interfaces -- 17.1 Electrochemistry in and at Single Biological Cells -- References -- 17.2 Single Molecule Electrochemistry -- References -- 17.3 Electrochemistry at Liquid/Liquid Interfaces -- Acknowledgments -- References -- Part V: Data -- Chapter 18. Electrode Potentials -- 18.1 Overview -- 18.2 Estimated Potential Ranges: Aqueous an Non-Aqueous Solutions -- 18.3 Standard Electrode Potentials: Aqueous Solutions -- 18.4 Formal Electrode Potentials: Aprotic Solvents -- 18.5 Formal Electrode Potentials: Common Organic Mediators -- 18.6 Electrode Potentials: Inorganic One-Electron Complexes -- 18.7 Formal Electrode Potentials: Biological Redox Species -- 18.8 Formal Electrode Potentials: Common Vitamins, Drugs, Neurochemicals -- 18.9 Abbreviations -- 18.10 Chemical Structures -- References -- Chapter 19. Diffusion Coefficients -- 19.1 Introduction -- 19.2 Fundamental Equations.

19.3 General Considerations -- 19.4 Electrochemical Methods -- 19.5 Tables of Diffusion Coefficients -- References -- Chapter 20. Liquid Junction Potentials -- 20.1 Types of Liquid Junctions -- 20.2 Transference Numbers and Conductivity -- 20.3 Minimization of Liquid Junction Potential -- 20.4 Junctions of Immiscible Liquids -- 20.5 Non-Classical Electrolytes: Polymer-Based Electrolytes and Ionic Liquids -- References -- Subject Index -- Colour Section to be found at the end of the book.