Cover image for Nanoscale Interface for Organic Electronics.
Nanoscale Interface for Organic Electronics.
Title:
Nanoscale Interface for Organic Electronics.
Author:
Iwamoto, Mitsumasa.
ISBN:
9789814322492
Personal Author:
Physical Description:
1 online resource (400 pages)
Contents:
CONTENTS -- PREFACE -- Part 1 Nanoscale Interface -- CHAPTER 1 INTRODUCTION TO NANOSCALE INTERFACE -- 1. Introduction -- 2. Order Parameter and Organic Device Application -- 3. Nanoscale Interface for Organic Electronic Devices -- 4. Outlook -- References -- CHAPTER 2 ANALYSIS OF CONTACT RESISTANCE AND SPACE-CHARGE EFFECTS IN ORGANIC FIELD-EFFECT TRANSISTORS -- 1. Introduction -- 2. Contact Resistance Definition -- 3. Effect of Electric Field on Contact Resistance -- 4. Measurements of Contact Resistance -- 4.1. Transmission Line Method (TLM) -- 4.2. Other Electrical Measurements -- 4.3. Kelvin Probe Force Microscopy (KFM) -- 4.4. Time-Resolved Microscopic Second-Harmonic Generation (TRM-SHG) -- 5. Design of Contact Resistance -- 5.1. Influence of Device Setup -- 5.2. Where is the Limit for Contact Resistance? -- 6. Conclusions and Outlook -- References -- CHAPTER 3 INTERFACE CONTROL OF VERTICAL-TYPE ORGANIC TRANSISTORS -- 1. Introduction -- 2. Vertical-Type Organic Transistors -- 3. Interface Control of Vertical-Type Organic Transistor -- 4. Organic Inverter Based on Vertical-Type Organic Transistors -- 5. Vertical-Type Organic Light-Emitting Transistor -- 6. Summary -- References -- CHAPTER 4 ELECTROCHEMICAL PROPERTIES OF SELF-ASSEMBLED VIOLOGEN DERIVATIVE AND ITS APPLICATION TO HYDROGEN PEROXIDE DETECTING SENSOR -- 1. Introduction -- 2. Principle of QCM Technique -- 2.1. Overview -- 2.2. Theory and Equivalent Circuit of QCM -- 2.3. Measurement Principle of Resonance Parameters -- 3. Experimental -- 3.1. Reagents -- 3.2. Electrode Modification -- 3.3. Apparatus and Measurement System -- 4. Results and Discussions -- 4.1. Verification of Self-Assembly by Resonant Frequency Shift -- 4.2. Redox Reaction and Electrochemical QCM Response -- 4.3. Electrochemistry of the Hb/Viologen-Modified Gold Electrode.

4.4. Catalytic Properties of the Sensor Towards H2O2 -- 4.5. Optimum Conditions of the Biosensor for Detecting H2O2 -- 4.6. Amperometric Response of the Biosensor -- 4.7. Stability of the Biosensor -- 5. Conclusions -- Acknowledgment -- References -- CHAPTER 5 ZINC (II), IRIDIUM (III) AND TIN (IV) COMPLEXES FOR NANOSCALE OLED DEVICES -- 1. Introduction -- 1.1. Structure and Operation of OLED Device -- 1.2. Emission Mechanism of OLED Device -- 2. Ligands Coordinated to Ir(III), Zn(II) and Sn(IV) -- 3. Light Emitting Ir(III), Zn(II), and Sn(IV) Materials -- 3.1. Blue Emitting Materials -- 3.2. Green Emitting Materials -- 3.3. Red Emitting Materials -- 3.4. White Emitting Diodes by Ir(III), Zn(II) and Sn(IV) Complexes -- 4. Conclusion -- Acknowledgments -- References -- CHAPTER 6 STRUCTURE OPTIMIZATION FOR HIGH EFFICIENCY WHITE ORGANIC LIGHT-EMITTING DIODES -- 1. Introduction -- 2. WOLEDs with Small Molecules Based on Dry-Process -- 2.1. Two Complementary Colors versus Three Primary Colors -- 2.2. All Fluorescent- versus All Phosphorescent versus Hybrid-WOLEDs -- 2.3. Excimer- versus Exciplex-WOLEDs -- 2.4. PIN- and Tandem-WOLEDs -- 2.5. Sensitizer- and Microcavity-WOLEDs -- 3. WOLEDs Based on Wet-Process -- 3.1. White Emission from Single Polymer -- 3.2. White Emission from Blended Red, Green, and Blue Emitters -- 3.2.1. Polymer/Polymer Blending -- 3.2.2. Polymer Host/Phosphorescent Small Molecular Dopants Blending -- 3.2.3. Small Molecular Host/Phosphorescent Small Molecular Dopants/Polymer Binder Blending -- 3.3. WOLEDs Based on Color Conversion Method -- 3.4. Wet-Coating Techniques for the Multilayer Formation -- 4. Conclusions and Outlook -- Acknowledgments -- References -- Part 2 Molecular Electronics -- CHAPTER 7 STATISTICAL ANALYSIS OF ELECTRONIC TRANSPORT PROPERTIES OF ALKANETHIOL MOLECULAR JUNCTIONS -- 1. Introduction.

2. Fabrication of Molecular Devices -- 3. Theoretical Basis -- 3.1. Possible Conduction Mechanisms -- 3.2. Tunneling Models -- 4. Statistical Approach on Charge Transport Through Alkanethiols -- 4.1. Statistical Analysis of Electronic Properties of Alkanethiols in Metal-Molecule-Metal Junctions -- 4.2. Statistical Method for Determining Intrinsic Electronic Properties of Alkanethiols in Nanoscale Molecular Junctions -- 5. Analysis of Metal-Molecular Junctions by Multi-Barrier Tunneling Model -- 5.1. Statistical Analysis of Electronic Properties of Alkanethiols and Alkanedithols -- 5.2. Length-Dependent Decay Coefficients by Multi-Barrier Tunneling Model -- 6. Conclusions and Outlook -- Acknowledgment -- References -- CHAPTER 8 A HYSTERIC CURRENT/VOLTAGE RESPONSE OF REDOX-ACTIVE RUTHENIUM COMPLEX MOLECULES IN SELF-ASSEMBLED MONOLAYERS -- 1. Introduction -- 1.1. A Redox-Active Ruthenium Complex as a Molecular Switch -- 1.2. Design of a Monolayer Non-Volatile Memory Device with a Ruthenium Complex -- 2. Materials and Surface Chemistry -- 2.1. Material Synthesis and Characterization -- 2.2. Surface Chemical Analysis -- 3. UHV-Scanning Tunneling Microscopy and Spectroscopy -- 3.1. Current/Voltage Response of Single Ruthenium Complexes -- 3.2. A Proposed Model for Electron Trapping in RuII Terpyridine Complexes -- 4. A MMNVM Device of RuII Terpyridine Complexes -- 4.1. Fabrication of a Large-Area Molecular Device -- 4.2. Current/Voltage Response of a MMNVM Device with RuII Terpyridine Complexes -- 5. Conclusion -- Acknowledgment -- References -- CHAPTER 9 CHARACTERISTICS OF CHARGE TRANSPORT AND ELECTRIC CONDUCTION IN VIOLOGEN SELF-ASSEMBLED MONOLAYERS -- 1. Introduction -- 2. Materials and Experiment -- 2.1. Materials -- 2.2. Experiment -- 2.2.1. Analysis of Self-Assembled Monolayers Using QCM and STM.

2.2.2. Cyclic Voltammetry Test and Charge Transport Measurement -- 2.2.3. Analysis of the Characteristics of Electric Conduction -- 3. Analysis of Self-Assembled Monolayers Using STM -- 4. Cyclic Voltammetry and Charge Transport -- 4.1. Oxidation and Reduction According to Changes in Electrolytes -- 4.2. Characteristics of Interfacial Charge Transport Caused by the Change in Mass -- 5. Electric Conductive Characteristics of Viologen Derivatives -- 6. Conclusion -- Acknowledgment -- References -- CHAPTER 10 TIME-AVERAGED DEUTERIUM NMR STUDIES OF THE DYNAMIC PROPERTIES FOR A LOW MOLAR MASS NEMATIC -- 1. Introduction -- 2. Theory -- 3. The Experiments -- 4. Results and Discussion -- 5. Conclusions -- Acknowledgments -- References -- CHAPTER 11 TRAINING AND FATIGUE OF CONDUCTING POLYMER ARTIFICIAL MUSCLES -- 1. Introduction -- 2. Electrochemomechanical Deformation of Conducting Polymers -- 3. Stress-Strain Characteristics of Polymer Actuators -- 4. Energy Conversion Efficiency -- 5. Training of PPy Actuators Under high Tensile Loads -- 6. Training of PANi Film -- 7. Fatigue of Artificial Muscles -- 8. Prospect of Soft Actuators -- References -- Part 3 Polymer Electronics -- CHAPTER 12 SURFACE PLASMON EXCITATIONS AND EMISSION LIGHTS IN NANOSTRUCTURED ORGANIC FILMS -- 1. Introduction -- 2. SP Excitation and ATR Method -- 2.1. SP Excitation -- 2.2. Method of ATR, Scattered Light and Emission Light Measurements Utilizing SP Excitations -- 3. Evaluation of Organic Ultrathin Films on Metal Thin Films by ATR Method -- 3.1. Evaluation of Surface Roughness of Organic Ultrathin Films by Scattered Light Measurement -- 3.2. Evaluation of Orientations of Liquid Crystal Molecules in a Cell by ATR Method -- 3.3. Application of SP Excitations to Organic Photoelectric Cell -- 4. SP Emission Lights -- 4.1. Emission Lights from Organic Ultrathin Films.

4.2. SP Emission Lights due to Molecular Luminescence and Interaction -- 4.3. Application of SP Emission Lights to Organic Devices -- 4.4. Electrochemical SP Excitations and Emission Lights -- 4.5. Grating Coupling SP Excitations and SP Emission Lights -- 5. Conclusions -- Acknowledgments -- References -- CHAPTER 13 MORPHOLOGY CONTROL OF NANOSTRUCTURED CONJUGATED POLYMER FILMS -- 1. Introduction -- 2. Conjugated Polymer and Experimental Procedure -- 3. Uniform Film of PDOF-MEHPV by Electrophoretic Deposition -- 3.1. Optical Absorption Spectra of PDOF-MEHPV Films -- 3.2. Atomic Force Microscope Images of PDOF-MEHPV Films -- 4. Preparation of Flat and Dense Conjugated Polymer Films from Dilute Solution -- 4.1. Scanning Electron Micrographs of PDOF-MEHPV -- 4.2. Deposition of PDOF-MEHPV from Dilute Solution -- 4.3. PEDOT Coating Effect on Deposition -- 5. Fabrication of PDOF-MEHPV Light-Emitting Devices by Electrophoretic Deposition -- 5.1. Structure of PDOF-MEHPV Light-Emitting Devices -- 5.2. Chracterization of PDOF-MEHPV Light-Emitting Devices -- 6. Electric Current in PDOF-MEHPV Suspensions -- 7. Conclusions -- Acknowledgments -- References -- CHAPTER 14 WAY OF ROLL-TO-ROLL PRINTED 13.56 MHzOPERATED RFID TAGS -- 1. Introduction -- 2. Matrerials, Substrates and R2R Printer -- 2.1. Conducting Silver Ink -- 2.2. Dielectric Ink -- 2.3. Semiconductive Ink -- 2.4. Substrate -- 2.5. R2R Gravure -- 3. R2R Gravure Printed Circuits on PET Foils -- 3.1. R2R Gravure Printed p-Channel SWNT-TFTs for Circuit Design Simulations -- 3.2. 2R Gravure Printed Inverters -- 3.3. R2R Gravure Printed Ring Oscillators -- 3.4. R2R Gravure Printed D Flip-Flop -- 4. Conclusions -- Acknowledgments -- References -- CHAPTER 15 PHYSICAL VAPOR DEPOSITION OF POLYMER THIN FILMS AND ITS APPLICATION TO ORGANIC DEVICES -- 1. Introduction -- 2. PVD of Polymer Thin Films.

3. Direct Evaporation of Polymers.
Abstract:
The scope of this book will be focused on the interface issues and problems in organic materials as electronic device applications. The organic material electronics is a rapidly progressing field for potential applications in flexible field effect transistors, plastic solar cells, organic luminescent devices, etc. However, the performance of these organic devices is still not sufficient. To enhance the understanding and practical applications of organic devices, we need to understand the fundamental organic device physics which is somewhat different from the conventional inorganic device physics. This book will discuss the detailed progress in these topics.
Local Note:
Electronic reproduction. Ann Arbor, Michigan : ProQuest Ebook Central, 2017. Available via World Wide Web. Access may be limited to ProQuest Ebook Central affiliated libraries.
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