Title Page -- Contents -- Preface -- PART 1. TRANSPORT PROCESSES -- Chapter 1. Assessing Seal Rock Integrity for CO2 Geological Storage Purposes -- 1.1. Introduction -- 1.2. Gas breakthrough experiments in water-saturated rocks -- 1.3. Interfacial properties involved in seal rock integrity -- 1.3.1. Brine-gas IFT -- 1.3.2. Wetting behavior -- 1.4. Maximum bottomhole pressure for storage in a depleted hydrocarbon reservoir -- 1.5. Evidences for capillary fracturing in seal rocks -- 1.6. Summary and prospects -- 1.7. Bibliography -- Chapter 2. Gas Migration through Clay Barriers in the Context of Radioactive Waste Disposal: Numerical Modeling of an In Situ Gas Injection Test -- 2.1. Introduction -- 2.2. Field experiment description -- 2.3. Boundary value problem -- 2.3.1. 1D and 3D geometry and boundary conditions -- 2.3.2. Hydraulic model -- 2.3.3. Hydraulic parameters -- 2.4. Numerical results -- 2.4.1. 1D modeling -- 2.4.2. 3D modeling -- 2.5. Discussion and conclusions -- 2.6. Bibliography -- Chapter 3. Upscaling Permeation Properties in Porous Materials from Pore Size Distributions -- 3.1. Introduction -- 3.2. Assembly of parallel pores -- 3.2.1. Presentation -- 3.2.2. Permeability -- 3.2.3. Case of a sinusoidal multi-modal pore size distribution -- 3.3. Mixed assembly of parallel and series pores -- 3.3.1. Presentation -- 3.3.2. Permeability -- 3.4. Comparisons with experimental results -- 3.4.1. Electrical fracturing tests -- 3.4.2. Measurement of the pore size distribution -- 3.4.3. Model capabilities to predict permeability and comparisons with experiments -- 3.5. Conclusions -- 3.6. Acknowledgments -- 3.7. Bibliography -- PART 2. FRACTURE, DEFORMATION AND COUPLED EFFECTS -- Chapter 4. A Non-Local Damage Model for Heterogeneous Rocks - Application to Rock Fracturing Evaluation Under Gas Injection Conditions -- 4.1. Introduction.

4.2. A probabilistic non-local model for rock fracturing -- 4.3. Hydromechanical coupling scheme -- 4.4. Application example and results -- 4.4.1. Effect of Weibull modulus -- 4.5. Conclusions and perspectives -- 4.6. Acknowledgments -- 4.7. Bibliography -- Chapter 5. Caprock Breach: A Potential Threat to Secure Geologic Sequestration of CO2 -- 5.1. Introduction -- 5.2. Caprock flexure during injection -- 5.2.1. Numerical results for the caprock-geologic media interaction -- 5.3. Fluid leakage from a fracture in the caprock -- 5.3.1. Numerical results for fluid leakage from a fracture in the caprock -- 5.4. Concluding remarks -- 5.5. Acknowledgment -- 5.6. Bibliography -- Chapter 6. Shear Behavior Evolution of a Fault due to Chemical Degradation of Roughness: Application to the Geological Storage of CO2 -- 6.1. Introduction -- 6.2. Experimental setup -- 6.3. Roughness and chemical attack -- 6.4. Shear tests -- 6.5. Peak shear strength and peak shear displacement: Barton's model -- 6.6. Conclusion and perspectives -- 6.7. Acknowledgment -- 6.8. Bibliography -- Chapter 7. CO2 Storage in Coal Seams: Coupling Surface Adsorption and Strain -- 7.1. Introduction -- 7.2. Poromechanical model for coal bed reservoir -- 7.2.1. Physics of adsorption-induced swelling of coal -- 7.2.2. Assumptions of model for coal bed reservoir -- 7.2.3. Case of coal bed reservoir with no adsorption -- 7.2.4. Derivation of constitutive equations for coal bed reservoir with adsorption -- 7.3. Simulations -- 7.3.1. Simulations at the molecular scale: adsorption of carbon dioxide on coal -- 7.3.2. Simulations at the scale of the reservoir -- 7.3.3. Discussion -- 7.4. Conclusions -- 7.5. Bibliography -- PART 3. AGING AND INTEGRITY -- Chapter 8. Modeling by omogenization of the Long erm Rock Dissolution and eomechanical Effects -- 8.1. Introduction.

8.2. Microstructure and modeling by homogenization -- 8.3. Homogenization of the H-M-T problem -- 8.3.1. Formulation of the problem at the microscopic scale -- 8.3.2. Asymptotic developments method -- 8.3.4. Summary of the macroscopic "H-M-T model" -- 8.4. Homogenization of the C-M problem -- 8.4.1. Formulation of the problem at the microscopic scale -- 8.4.2. Homogenization -- 8.4.3. Summary of the macroscopic "C-M model" -- 8.5. Numerical computations of the time degradation of the macroscopic rigidity tensor -- 8.5.1. Definition of the problem -- 8.5.2. Results and discussion -- 8.6. Conclusions -- 8.7. Acknowledgment -- 8.8. Bibliography -- Chapter 9. Chemoplastic Modeling of Petroleum Cement Paste under Coupled Conditions -- 9.1. Introduction -- 9.2. General framework for chemo-mechanical modeling -- 9.2.1. Phenomenological chemistry model -- 9.3. Specific plastic model for petroleum cement paste -- 9.3.1. Elastic behavior -- 9.3.2. Plastic pore collapse model -- 9.3.3. Plastic shearing model -- 9.4. Validation of model -- 9.5. Conclusions and perspectives -- 9.6. Bibliography -- Chapter 10. Reactive Transport Modeling of CO2 Through Cementitious Materials Under Supercritical Boundary Conditions -- 10.1. Introduction -- 10.2. Carbonation of cement-based materials -- 10.2.1. Solubility of the supercritical CO2 in the pore solution -- 10.2.2. Chemical reactions -- 10.2.3. Carbonation of CH -- 10.2.4. Carbonation of C-S-H -- 10.2.5. Porosity change -- 10.3. Reactive transport modeling -- 10.3.1. Field eq -- 10.3.2. Transport of the liquid phase -- 10.3.3. Transport of the gas phase -- 10.3.4. Transport of aqueous species -- 10.4. Simulation results and discussion -- 10.4.1. Sandstone-like co -- 10.4.2. Limestone-like conditions -- 10.4.3. Study of CO2 concentration and initial porosity -- 10.4.4. Supercritical boundary conditions.

10.5. Conclusion -- 10.6. Acknowledgment -- 10.7. Bibliography -- Chapter 11. Chemo-Poromechanical Study of Wellbore Cement Integrity -- 11.1. Introduction -- 11.2. Poromechanics of cement carbonation in the context of CO2 storage -- 11.2.1. Context and definitions -- 11.2.2. Chemical reactions -- 11.2.3. Chemo-poromechanical behaviour -- 11.2.4. Balance equations -- 11.3. Application to wellbore cement -- 11.3.1. Description of the problem -- 11.3.2. Initial state and boundary conditions -- 11.3.3. Illustrative results -- 11.4. Conclusion -- 11.5. Acknowledgments -- 11.6. Bibliography -- List of Authors -- Index.