
Chemistry of Explosives.
Title:
Chemistry of Explosives.
Author:
Akhavan, Jacqueline.
ISBN:
9781847552020
Personal Author:
Edition:
2nd ed.
Physical Description:
1 online resource (192 pages)
Series:
RSC Paperbacks ; v.35
RSC Paperbacks
Contents:
CONTENTS -- Chapter 1 -- Introduction to Explosives -- Development of Blackpowder -- Development of Nitroglycerine -- Development of Mercury Fulminate -- Development of Nitrocellulose -- Development of Dynamite -- Development of Ammonium Nitrate -- Development of Commercial Explosives -- Development of Permitted Explosives -- Development of ANFO and Slurry Explosives -- Development of Military Explosives -- Development of Picric Acid -- Development of Tetryl -- Development of TNT -- Development of Nitroguanidine -- Development of PETN -- Development of RDX and HMX -- Polymer Bonded Explosives -- Recent Developments -- Insensitive Munitions -- Pollution Prevention -- Chapter 2 -- Classification of Explosive Materials -- Explosions -- Atomic Explosions -- Physical Explosions -- Chemical Explosions -- Chemical Explosives -- Classification of Chemical Explosives -- Primary Explosives -- Secondary Explosives -- Propellants -- Chemical Data on Explosive Materials -- Primary Explosives -- Mercury Fulminate -- Lead Azide -- Lead Styphnate -- Silver Azide -- Tetrazene -- Secondary Explosives -- Nitroglycerine -- Nitrocellulose -- Picric Acid -- Tetryl -- TNT -- Nitroguanidine -- PETN -- RDX -- HMX -- TATB -- HNS -- NTO -- TNAZ -- Other Compounds used in Explosive Compositions -- Chapter 3 -- Combustion, Deflagration and Detonation -- Combustion -- Physical and Chemical Aspects of Combustion -- Combustion of Explosives and Propellants -- Deflagration -- Detonation -- Burning to Detonation -- Shock to Detonation -- Propagation of the Detonation Shockwave -- Effect of Density on the Velocity of Detonation -- Effect of Diameter of the Explosive Composition on the Velocity of Detonation -- Effect of Explosive Material on the Velocity of Detonation -- Classification of Explosives -- Chapter 4 -- Ignition, Initiation and Thermal Decomposition -- Ignition.
Hotspots -- Mechanisms for the Formation of Hotspots -- Ignition by Impact and Friction -- Friction -- Impact -- Classification of Explosives -- Initiation Techniques -- Explosive Train -- Detonators -- Igniters -- Thermal Decomposition -- Chapter 5 -- Thermochemistry of Explosives -- Oxygen Balance -- Decomposition Reactions -- Kistiakowsky-Wilson Rules -- Modified Kistiakowsky-Wilson Rules -- Springall Roberts Rules -- Heats of Formation -- Heat of Explosion -- Effect of Oxygen Balance -- Volume of Gaseous Products of Explosion -- Explosive Power and Power Index -- Temperature of Chemical Explosion -- Mixed Explosive Compositions -- Atomic Composition of the Explosive Mixture -- Oxygen Balance -- Decomposition Reaction -- Heat of Explosion -- Volume of Gaseous Products -- Energized Explosives -- Addition of Aluminium -- Force and Pressure of Explosion -- Chapter 6 -- Equilibria and Kinetics of Explosive Reactions -- Equilibria -- Products of Decomposition -- The Water-Gas Equilibrium -- Heat of Explosion -- Temperature of Explosion -- Kinetics of Explosive Reactions -- Activation Energy -- Rate of Reaction -- Kinetics of Thermal Decomposition -- Measurement of Kinetic Parameters -- Differential Thermal Analysis -- Thermogravimetric Analysis -- Differential Scanning Calorimetry -- Chapter 7 -- Manufacture of Explosives -- Nitration -- C-Nitration -- Picric Acid -- Tetryl -- TNT -- TATB -- HNS -- O-Nitration -- Nitroglycerine -- Nitrocellulose -- PETN -- N-Nitration -- RDX -- HMX -- Nitroguanidine -- Ammonium Nitrate -- Primary Explosives -- Lead Azide -- Mercury Fulminate -- Tetrazene -- Commercial Explosive Compositions -- Ammonium Nitrate -- Ammonium Nitrate Slurries -- Ammonium Nitrate Emulsion Slurries -- Dynamite -- Military Explosive Compositions -- Casting -- Pressing -- Ram and Screw Extrusion -- Chapter 8.
Introduction to Propellants and Pyrotechnics -- Introduction to Propellants -- Gun Propellants -- Performance -- Composition -- Single-base Propellants -- Double-base Propellants -- Triple-base Propellants -- Propellant Additives -- High Energy Propellants -- Liquid Propellants -- Composite Propellants -- Rocket Propellants -- Performance -- Composition -- Double-base Propellants -- Composite Propellants -- Liquid Propellants -- Gas-generating Propellants -- Introduction to Pyrotechnics -- Heat-producing Pyrotechnics -- Primers and First Fires -- Heat-generating Devices -- Delay Compositions -- Smoke-generating Compositions -- Light-generating Compositions -- Coloured Light -- White Light -- Noise-generating Pyrotechnics -- Bang -- Whistle -- Bibliography -- Subject Index.
Abstract:
Revised and expanded to reflect new developments in the field, this book outlines the basic principles required to understand the chemical processes of explosives. The Chemistry of Explosives provides an overview of the history of explosives, taking the reader to future developments. The text on the classification of explosive materials contains much data on the physical parameters of primary and secondary explosives. The explosive processes of deflagration and detonation, including the theory of 'hotspots' for the detonation process, are introduced and many examples are provided in the detailed description on the thermochemistry of explosives. New material includes coverage of the latest explosive compositions, such as high temperature explosives, nitrocubanes, energetic polymers, plasticizers and insensitive munitions (IM). This concise, readable book is ideal for 'A' level students and new graduates with no previous knowledge of explosive materials. With detailed information on a vast range of explosives in tabular form and an extensive bibliography, this book will also be useful to anyone needing succinct information on the subject. Extracts from reviews of 1st Edition: "... this succinct introductory paperback manual on the chemistry, physics, and functioning of explosives is most welcome ... eminently readable ..." Angewandte Chemie, International Edition "...an excellent book for A Level students and new graduates." International Journal of Environmental Studies.
Local Note:
Electronic reproduction. Ann Arbor, Michigan : ProQuest Ebook Central, 2017. Available via World Wide Web. Access may be limited to ProQuest Ebook Central affiliated libraries.
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