Catalysis by Ceria and Related Materials.
Title:
Catalysis by Ceria and Related Materials.
Author:
Trovarelli, Alessandro.
ISBN:
9781860949654
Personal Author:
Physical Description:
1 online resource (527 pages)
Series:
Catalytic Science Series ; v.2
Catalytic Science Series
Contents:
CONTENTS -- Preface -- 1. Mining, Production, Application and Safety Issues of Cerium-based Materials -- 1.1. Mining -- 1.2. Production and Application -- 1.3. Safety Issues -- 1.4. References -- 2. Structural Properties and Nonstoichiometric Behavior of CeO2 -- 2.1. Structural Properties -- 2.2. Defect Structure Analysis -- 2.3. Transport Properties -- 2.4. References -- 3. Synthesis and Modification of Ceria-based Materials -- 3.1. Introduction -- 3.2. Solid to Solid Synthesis -- 3.3. Liquid to Solid Synthesis -- 3.4. Gas to Solid Synthesis -- 3.5. Modification of Bulk and Surface -- 3.6. References -- 4. Chemical and Nanostructural Aspects of the Preparation and Characterisation of Ceria and Ceria-Based Mixed Oxide-Supported Metal Catalysts -- 4.1. Introduction -- 4.2. Preparation of M/CeO2 and Closely Related Catalysts -- 4.3. Characterisation of M/CeO2 and Closely Related Catalysts -- 4.4. References -- 5. Studies of Ceria-containing Catalysts Using Magnetic Resonance and X-ray Spectroscopies -- 5.1. Introduction -- 5.2. EPR -- 5.3. NMR -- 5.4. XPS -- 5.5. XAFS -- 5.6. References -- 6. Structural Properties and Thermal Stability of Ceria-Zirconia and Related Materials -- 6.1. The CeO2-ZrO2 Phase Diagram -- 6.2. Effects of High Temperature Reducing and Oxidising Treatments -- 6.3. Effects of Aliovalent Doping on Thermal and Phase Stability -- 6.4. Effects of Addition of Al2O3 to CeO2-ZrO2 Mixed Oxides -- 6.5. References -- 7. Oxygen Storage/Redox Capacity and Related Phenomena on Ceria-Based Catalysts -- 7.1. Introduction -- 7.2. Oxygen Storage Capacity Measurements -- 7.3. Elementary Steps Involved in OSC Processes -- 7.4. OSC and Catalysis -- 7.5. References -- 8. Computer Simulation Studies of Ceria-based Oxides -- 8.1. Introduction -- 8.2. Computational Techniques -- 8.3. Bulk Defect Chemistry.
8.4. Oxygen Ion Migration -- 8.5. Surface Properties -- 8.6. Conclusion -- 8.7. References -- 9. Ceria Surfaces and Films for Model Catalytic Studies Using Surface Analysis Techniques -- 9.1. Introduction and Scope -- 9.2. Techniques for Preparation of Ceria Films and Model Catalysts -- 9.3. Structure of Ceria Surfaces -- 9.4. Chemisorption Studies on Clean Ceria Surfaces -- 9.5. Reducibililty of Ceria Surfaces -- 9.6. Studies of Chemisorption on Metal Loaded Ceria Surfaces -- 9.7. Coadsorption and Reaction Studies on Ceria Model Catalysts -- 9.8. Overview -- 9.9. References -- 10. Ceria and Other Oxygen Storage Components in Automotive Catalysts -- 10.1. Origin and Evolution of "Oxygen Storage" in Automotive Catalysts -- 10.2. Interaction of Ceria with the Active Noble Metals -- 10.3. Deactivation of Oxygen Storage -- 10.4. Other Materials Providing Oxygen Storage -- 10.5. Special Uses of Oxygen Storage -- 10.6. Oxygen Storage and NOx Traps -- 10.7. Outlook -- 10.8. References -- 11. S02 Poisoning of Ceria-Supported, Metal Catalysts -- 11.1. Introduction -- 11.2. Effect of SO2 on Catalytic Activity -- 11.3. Chemistry of SO2 Poisoning of Ceria -- 11.4. Lessons from Catalysts for SO2 Reduction -- 11.5. Future Directions -- 11.6. Subject Index -- 11.7. References -- 12. Cerium and Platinum Based Diesel Fuel Additives in the Diesel Soot Abatement Technology -- 12.1. Introduction -- 12.2. Experimental -- 12.3. Results -- 12.4. Discussion -- 12.5. Conclusions -- 12.6. References -- 13. Fundamentals and Applications of Ceria in Combustion Reactions -- 13.1. Introduction -- 13.2. Catalytic combustion on Ceria -- 13.3. Catalytic Combustion on Ceria Containing Oxides -- 13.4. Ceria Associated with Noble Metals -- 13.5. The Future of Ceria in Catalytic Combustion -- 13.6. Conclusions -- 13.7. References -- 14. Ceria Based Wet-Oxidation Catalysts.
14.1. Introduction - Background of Wet-Oxidation -- 14.2. Catalysts -- 14.3. Summary - Role of the Catalysts -- 14.4. References -- 15. Ceria-based Electrodes -- 15.1. Background -- 15.2. The Chemistry of Ceria -- 15.3. Electrical Conductivity -- 15.4. Ceria Based Fuel Electrodes for SOFC -- 15.5. References -- 16. The Use of Ceria in FCC, Dehydrogenation and Other Catalytic Applications -- 16.1. Introduction -- 16.2. Treatment of SOx -- 16.3. Ethylbenzene Dehydrogenation -- 16.4. Other Catalytic Reactions -- 16.5. Conclusions -- 16.6. References -- Index.
Abstract:
The use of CeO 2 -based materials in catalysis has attracted considerable attention in recent years, particularly in applications like environmental catalysis, where ceria has shown great potential. This book critically reviews the most recent advances in the field, with the focus on both fundamental and applied issues. The first few chapters cover structural and chemical properties of ceria and related materials, i.e. phase stability, reduction behaviour, synthesis, interaction with probe molecules (CO, O 2 , NO), and metal-support interaction - all presented from the viewpoint of catalytic applications. The use of computational techniques and ceria surfaces and films for model catalytic studies are also reviewed. The second part of the book provides a critical evaluation of the role of ceria in the most important catalytic processes: three-way catalysis, catalytic wet oxidation and fluid catalytic cracking. Other topics include oxidation-combustion catalysts, electrocatalysis and the use of cerium catalysts/additives in diesel soot abatement technology. Contents: Mining, Production, Application and Safety Issues of Cerium-based Materials (K Schermanz); Structural Properties and Nonstoichiometric Behavior of CeO 2 (A Trovarelli); Synthesis and Modification of Ceria-based Materials (G Adachi & T Masui); Chemical and Nanostructural Aspects of the Preparation and Characterisation of Ceria and Ceria-Based Mixed Oxide-Supported Metal Catalysts (S Bernal et al.); Studies of Ceria-containing Catalysts Using Magnetic Resonance and X-ray Based Spectroscopies (J C Conesa et al.); Structural Properties and Thermal Stability of Ceria-Zirconia and Related Materials (J Ka©par & P Fornasiero); Oxygen Storage/Redox Capacity and Related Phenomena on Ceria-based Catalysts (D Duprez & C Descorme); Computer Simulation Studies of Ceria-based Oxides (M Saiful Islam &
G Balducci); Ceria Surfaces and Films for Model Catalytic Studies Using Surface Analysis Techniques (S H Overbury & D R Mullins); Ceria and Other Oxygen Storage Components in Automotive Catalysts (M Shelef et al.); SO 2 Poisoning of Ceria-Supported, Metal Catalysts (R J Gorte & T Luo); Cerium and Platinum Based Diesel Fuel Additives in the Diesel Soot Abatement Technology (M Makkee et al.); Fundamentals and Applications of Ceria in Combustion Reactions (M Primet & E Garbowski); Ceria-based Wet-Oxidation Catalysts (S Imamura); Ceria-based Electrodes (M Mogensen); The Use of Ceria in FCC, Dehydrogenation and Other Catalytic Applications (M Boaro et al.). Readership: Graduate students, researchers, academics and industrialists in catalyst, industrial, physical and solid state chemistry, as well as chemical engineering and materials science.
Local Note:
Electronic reproduction. Ann Arbor, Michigan : ProQuest Ebook Central, 2017. Available via World Wide Web. Access may be limited to ProQuest Ebook Central affiliated libraries.
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