Metal Mediated Template Synthesis of Ligands.
Title:
Metal Mediated Template Synthesis of Ligands.
Author:
Costisor, Otilia.
ISBN:
9789812794819
Personal Author:
Physical Description:
1 online resource (307 pages)
Contents:
Contents -- Preface -- The Template Effect -- 1.1. Types of Template Effects -- 1.2. The Template Effect as a Molecular Organizer Effect -- 1.3. Factors Affecting the Product of a Template Reaction -- 1.3.1. Coordination of ligands -- 1.3.2. The chelate effect -- 1.3.3. Macrocyclic effect -- 1.4. The Negative Template Effect -- 1.5. Advantages of Metal Template Reaction -- Alkylation Reactions -- 2.1. Alkylation of the Nitrogen Atom -- 2.2. Alkylation of the Sulfur Atom -- 2.2.1. Open chain systems -- 2.2.2. Macrocyclic ligands -- Schiff Condensation -- 3.1. Mechanistic Aspects -- 3.2. Open-chain Ligands -- 3.3. Macrocyclic Ligands -- 3.3.1 Diimine macrocycles -- 3.3.2. Tetraimine macrocycles -- 3.4. Cage Ligands -- 3.5 Compartmental Ligands -- 3.5.1. Closed-chain ligands -- 3.5.2. Open chain ligands -- Mannich Condensation -- 4.1. Mechanistic Aspects -- 4.2 Acyclic Ligands -- 4.2.1. Polyamine ligands -- 4.2.2. NO donor ligands -- 4.2.3. SN donor ligands -- 4.3. Monocyclic Ligands -- 4.3.1. Tetraaza macrocycles -- 4.3.2. Pentaaza macrocycles -- 4.3.3. Hexaaza macrocycles -- 4.3.4. Octaaza macrocycles -- 4.3.5. Azaether macrocycle -- 4.3.6. Azathioether macrocycle -- 4.3.7. Reinforced macrocycles -- 4.3.8. Macromonocyclic dicompartmental ligands -- 4.4. Isolated Dimacrocycles -- 4.5.Condensed Polymacrocyclic Ligands -- 4.5.1. Carbon and nitrogen caped amine ligands -- 4.5.2. P- As amine cage ligands -- 4.5.3. Thioamine cage ligands -- 4.5.4. Cage complexes of other metal ions -- Self Condensation of Nitriles -- 5.1. Phthalocyanines -- 5.1.1. Mechanism -- 5.2. Porphyrins -- 5.3. Corrole -- Self-Assembled Systems -- 6.1. Catenanes -- 6.1.1. Two interlocked rings -- 6.1.2. Three interlocked rings -- 6.2. Rotaxanes -- 6.3. Helicates -- 6.3.1. Acyclic helicates -- 6.3.2. Circular helicates -- 6.4. Knots.
6.5. Macrocycles and Cages -- 6.6. Racks Ladder and Grids -- References -- Index.
Abstract:
This book surveys the relatively new area of the synthesis of organic ligands when metal ions act as a template. In the last fifty years this field has undergone an explosive development, marked by a great amount of literature. The material in the book has been arranged according to the type of chemical reaction involved. In this frame, the basic principles of metal template reactions and the shape of the molecules are considered. Designed to satisfy the demands of students, young researchers doing their PhDs, and those working in the field of coordination chemistry, the book details the role of the metal ions and the specific properties of the formed complexes. Metal Mediated Template Synthesis of Ligands offers a comprehensive analysis with wide-ranging references and provides an extensive overview of research on metal-directed organic ligands over the past five decades. Contents: The Template Effect; Alkylation Reactions; Schiff Condensation; Mannich Condensation; Self Condensation of Nitriles; Self-Assembled Systems. Readership: Upper level undergraduates, graduate students, academics, researchers industrialists in inorganic, solid-state, supramolecular and organic chemistry.
Local Note:
Electronic reproduction. Ann Arbor, Michigan : ProQuest Ebook Central, 2017. Available via World Wide Web. Access may be limited to ProQuest Ebook Central affiliated libraries.
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