Cover image for Electrochemistry of Metal Complexes : Applications from Electroplating to Oxide Layer Formation.
Electrochemistry of Metal Complexes : Applications from Electroplating to Oxide Layer Formation.
Title:
Electrochemistry of Metal Complexes : Applications from Electroplating to Oxide Layer Formation.
Author:
Survila, Arvydas.
ISBN:
9783527691265
Personal Author:
Edition:
1st ed.
Physical Description:
1 online resource (306 pages)
Contents:
Cover -- Title Page -- Copyright -- Contents -- Preface -- Symbols and Abbreviations -- Chapter 1 Introduction -- 1.1 Equilibrium Properties of Complex Systems -- 1.1.1 General Definitions -- 1.1.2 Equilibrium in the Solutions of Complex Compounds -- 1.1.3 Distribution of Complexes and Ligands in the Solution -- References -- Chapter 2 Equilibrium Electrode Potentials -- 2.1 Electrodes of the First Kind -- 2.2 Equilibria Involving Ions of the Intermediate Oxidation State -- 2.3 Electrodes of the Second Kind -- 2.4 Open-Circuit Potentials: Examples of Experimental Investigations -- 2.4.1 System Cu/Cu(I),CN- -- 2.4.2 System Cu/Cu(II), β-Alanine -- References -- Chapter 3 Mass Transport -- 3.1 Two Models of Linear Mass Transport -- 3.2 Other Cases of Diffusional Mass Transport -- 3.3 Mass Transport of Chemically Interacting Particles -- 3.4 Concentration Profiles -- 3.4.1 Concentration Profiles in Ideally Labile Systems -- 3.4.2 Concentration Profiles in Systems of Limited Lability -- References -- Chapter 4 Peculiarities of Electrochemical Processes Involving Labile Complexes -- 4.1 Steady-State Voltammograms -- 4.2 Potential Transients -- 4.3 Current Transients -- References -- Chapter 5 Quantitative Modeling of Quasi-Reversible Electrochemical Processes Involving Labile Complexes of Metals -- 5.1 Kinetic Equations -- 5.2 Employment of Voltammetric Data -- 5.2.1 Tafel Plots Normalized with Respect to the Surface Concentration of EAC -- 5.2.2 Analysis of LPS Current Maxima -- 5.3 Techniques Based on the Control of the Intensity of Forced Convection -- 5.3.1 Isosurface Concentration Voltammetry -- 5.3.2 Determination of the Exchange Current Density from Polarization Resistance.

5.3.3 Electrochemical Impedance Spectroscopy (EIS) under Forced Convection Conditions -- References -- Chapter 6 Determination of Mechanism of Electrochemical Processes Involving Metal Complexes -- 6.1 Determination of the Mechanism by Reaction Orders -- 6.2 Method of Isopotential Solutions -- References -- Chapter 7 Adsorption -- 7.1 Thermodynamic Aspects -- 7.2 Model Aspects -- References -- Chapter 8 Electrochemical Processes in Real Systems -- 8.1 Experimental Details -- 8.2 Cyanide Systems -- 8.2.1 System Cu

Chapter 11 Hydrogen Evaluation Involving Ligands as Proton Donors -- References -- Concluding Remarks -- Index -- EULA.
Abstract:
A systematic analysis of electrochemical processes involving metal complexes. Starting with general considerations on equilibria in solutions and at interfaces as well as on mass transport, the text acquaints readers with the theory and common experimental practice for studying electrochemical reactions of metals complexes. The core part of the book deals with all important aspects of electroplating, including a systematic discussion of co-deposition of metals and formation of alloys. It also discusses such related subjects as oxide layer formation and hydrogen evolution as a side reaction.
Local Note:
Electronic reproduction. Ann Arbor, Michigan : ProQuest Ebook Central, 2017. Available via World Wide Web. Access may be limited to ProQuest Ebook Central affiliated libraries.
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