KINETICS AND THERMODYNAMICS FORCHEMISTRY AND BIOCHEMISTRY -VOL.2 (A FESTSCHRIFT IN HONOR OFTHE 75TH BIRTHDAY OF PROFESSORGENNADY E. ZAIKOV) -- KINETICS AND THERMODYNAMICS FORCHEMISTRY AND BIOCHEMISTRY -VOL.2 (A FESTSCHRIFT IN HONOR OFTHE 75TH BIRTHDAY OF PROFESSORGENNADY E. ZAIKOV) -- CONTENTS -- PREFACE -- Chapter 1 -- REGULARITIES OF PHOTOINITIATEDCOPOLYMERIZATION OF (METH)ACRYLATES TILLHIGH CONVERSIONS. KINETIC MODEL OF THEPROCESS AT LINEAR CHAIN TERMINATION -- ABSTRACT -- 1. INTRODUCTION -- 2. KINETIC REGULARITIES OF PHOTOINITIATEDCOPOLYMERIZATION OF MONO- AND DI(METH)ACRYLATESTILL HIGH CONVERSIONS -- 3. KINETIC EQUATION OF COPOLYMERIZATION AT LINEAR CHAINTERMINATION DERIVATION -- CONCLUSIONS -- REFERENCES -- REPARATION AND CHARACTERIZATION OFMETAL SILICATES: REVIEW -- ABSTRACT -- INTRODUCTION -- 2. SODIUM SILICATE AS A SILICA SOURCE -- 2.1. Silicate Hydrolysis -- 3. PREPARATION OF SYNTHETIC SILICA AND SILICATES -- 3.1. Silica Precipitation -- 3.2. Silica Precipitation with Metal Salts -- 4. APPLICATIONS OF SYNTHETIC SILICATES -- Pigments -- Corrosion Protection by Silicate Coating: -- Medical Uses -- CONCLUSION -- REFERENCES -- DEVELOPMENT OF POSSIBLE STATIONARY STATESIDENTIFICATION METHOD IN INDUSTRIAL REACTIVEDISTILLATION PROCESSES -- ABSTRACT -- NOTATION -- INTRODUCTION -- EXPERIMENTAL -- RESULTS -- CONCLUSIONS -- ACKNOWLEDGMENT -- REFERENCES -- THE NEW TYPE OF NONEQUILIBRIUM PHASETRANSITION IN DIFFERING NATURE SYSTEMS WITHLOW-COUPLED MAGNETIC MOMENTS -- ABSTRACT -- REFERENCES -- EFFECT OF UV IRRADIATION ON ERYTHROCYTES INTHE PRESENCE OF ANTIOXIDANTS-CONTAININGSILICA -- INTRODUCTION -- EXPERIMENTAL -- RESULTS AND DISCUSSION -- REFERENCES -- INTERACTIONS BETWEEN PRION PROTEINS ANDMOLECULAR CHAPERONES BY THE EXAMPLE OFOVINE PRION VARIANTS VRQ AND ARR,AND CHAPERONIN GROEL -- ABSTRACT -- 1. INTRODUCTION -- 2. EXPERIMENTAL -- 2.1. Chemicals.

2.2. Dilution of Dried Prion Isoformes VRQ and ARR -- 2.3. Isolation of Chaperonin GroEL and Co-Chaperonin GroES -- 2.4. GroEL Immobilization -- 2.5. Isolation of GAPDH -- 2.6. Denaturation of GAPDH in the Presence of Guanidine Hydrochloride -- 2.7. Enzymatic Activities of GAPDH -- 2.8. GroEL-Assisted Reactivation of GAPDH -- 2.9. SDS - PAGE -- 2.10. Protein Thermoaggregation Kinetics -- 2.11. Differential Scanning Calorimetry (DSC) -- 2.12. Dynamic Light Scattering Analysis (DLS) -- 3. RESULTS AND DISCUSSION -- CONCLUSIONS -- ACKNOWLEDGMENT -- REFERENCES -- OPTIMIZATION OF DICHLOROACETIC ACIDSHYDROGENATION REACTOR -- ABSTRACT -- INTRODUCTION -- EXPERIMENTAL -- RESULTS -- CONCLUSIONS -- REFERENCES -- RUBBER-TIRE PARTICLES AS CONCRETEAGGREGATE -- ABSTRACT -- INTRODUCTION -- MATERIALS PROPERTIES -- MIXTURE DESIGN -- TESTING METHODS -- Compressive and Tensile Strength -- Flexural Toughness -- RESULTS AND DISCUSSIONS -- Compressive and Tensile Strength of Concrete -- MODULUS OF ELASTICITY -- WORKABILITY OF CONCRETE -- EFFECT OF WASTE TIRE ON TOUGHNESS OF CONCRETE -- CONCLUSIONS -- REFERENCES -- EXPERIMENTAL INVESTIGATION ON CEMENT-BASEDCOMPOSITE CONTAINING POLYPROPYLENE FIBERSEXPOSED TO HIGH TEMPERATURE -- ABSTRACT -- INTRODUCTION -- RECYCLED GLASS -- RECYCLED FIBERS -- EFFECT OF HIGH TEMPERATURE ON CEMENT-BASED MATRIX -- MATERIALS PROPERTIES -- TEST PROGRAM -- RESULTS AND DISCUSSIONS -- Density -- Compressive Strength -- Flexural Strength -- CONCLUSIONS -- REFERENCES -- POLYMER RESEARCH INSTITUTE.CELEBRATION OF 60 YEARS IN EDUCATION ANDRESEARCH (1947 - 2007) -- HERMAN F. MARK -- FREDERICK ROLAND EIRICH -- APPENDIX. POLYMER RESEARCH INSTITUTE FACULTY2007-2008 -- THE NEW EQUIPMENT FOR CLEARING INDUSTRIALEMISSIONS -- ABSTARCT -- INTRODUCTION -- CONCLUSIONS -- REFERENCES -- CONCLUSIONS -- REFERENCES.

SIMULATION OF ORGANIC COMPOUND OXIDATIONON THE SURFACES OF IRON AND CHROMIUMNANOCLUSTERS -- ABSTRACT -- INTRODUCTION -- COMPUTATIONAL METHOD -- CATALYTIC FEATURES OF TRANSITION METAL NANOCLUSTERS -- CONCLUSIONS -- REFERENCES -- KINETICS AND MOLECULAR MODELLING OF1-HYDROXYCYCLOHEXYL HYDROPEROXIDEDECOMPOSITION ACTIVATED BY ALK4NBR -- ABSTRACT -- INTRODUCTION -- EXPERIMENTAL -- RESULTS AND DISCUSSION -- CONCLUSIONS -- REFERENCES -- EFFECTS OF POLYPROPYLENE FIBERS ONEXPANSION PROPERTIES OF CEMENT BASEDCOMPOSITE CONTAINING WASTE GLASS -- ABSTRACT -- 1. INTRODUCTION -- 2. MATERIAL SPECIFICATIONS -- 3. MIX DESIGN -- 4. RESULTS AND DISCUSSION -- 4.1. Analysis of the Expansion Characteristics -- 4.2. ASR Characteristics of Composite Containing Reinforcing Fiber -- CONCLUSION -- REFERENCES -- WATER INTERACTION OF BIODEGRADABLE FILMSBASED ON COMPOSITION OFPOLYHYDROXYBUTYRATE / POLYAMIDE RESIN -- ABSTRACT -- INTRODUCTION -- EXPERIMENTAL -- RESULTS AND DISCUSSION -- Water Sorption PA-54R / PHB Different Compositions Films -- Development of Determination Method of PHB Weight Part in Blend FilmsPA-54R / PHB with Fourier - IR Spectroscopy Technique -- Water Sorption PA-54R / PHB Samples Produced from Powders -- Influence of PHB on the Supermolecular Structure of PA-54R in the BlendCompositions -- CONCLUSIONS -- REFERENCES AND NOTES -- PARTIAL REPLACEMENT OF AGGREGATES BYRECYCLED POLYMER FIBERS IN CEMENT-MATRIXCOMPOSITES -- ABSTRACT -- 1. INTRODUCTION -- 1.1. Recycled Glass -- 1.2. Recycled Fibers -- 2. EXPERIMENTAL APPROACH -- 2. 1. Material Sspecifications -- 2.2. Test Program -- 3. RESULTS AND DISCUSSION -- 3.1. Compressive Strength -- 3.2. Flexural Strength -- 3.3. Flexural Toughness -- 3.4. Water Absorption -- CONCLUSION -- REFERENCES -- RELEASE OF VOLATILE COMPOUNDS FROM THEBREAD -- ABSTRACT -- 1. INTRODUCTION -- 2. MATERIALS AND METHODS.

2.1. Materials and Bread Preparation -- 2.2. Model Mixture of Odorants -- 2.3. Introduction of Odorants into the Bread -- 2.4. Cumulative Static Headspace Analysis -- 2.5. Gas Chromatographic Analysis (GC) -- 2.6. Statistical Analysis -- 3. RESULTS AND DISCUSSION -- 3.1. Trapping of Odorants in the Breads -- 3.2. Release of Aroma Compounds from the Bread -- ACKNOWLEDGMENTS -- REFERENCES -- IMPACT OF TRANSITION METALS IN THE FREERADICALDEGRADATION OF HYALURONANBIOPOLYMER∗ -- ABSTRACT -- 1. BIOGENIC ELEMENTS -- 2. TRANSITION METALS -- Vanadium -- Manganese -- Iron -- Cobalt -- Nickel -- Copper -- Zinc -- Molybdenum -- 3. NON-ENZYMATIC PEROXIDATION - A RADICAL CHAIN REACTION -- Initiation Reaction(s) -- Propagation Reaction(s) -- 4. JOINT - ROLE OF HYALURONAN -- 5. HYPOXIA AND RE-OXYGENATION OF THE JOINT -- 6. PARTICIPATION OF BIOGENIC TRANSITION METALS INPHYSIOLOGIC CATABOLISM OF HYALURONAN -- Actors of Physiologic Catabolism of Hyaluronan in the Synovial Fluid -- 7. PATHOPHYSIOLOGIC CATABOLISM OF HYALURONAN INYNOVIAL FLUID -- ACKNOWLEDGMENTS -- REFERENCES -- HYALURONAN DEGRADATION BY ASCORBATE:PROTECTIVE EFFECTS OF MANGANESE(II)CHLORIDE∗ -- ABSTRACT -- 1. INTRODUCTION -- EXPERIMENTAL -- Biopolymers -- Chemicals -- Hyaluronan Degradation/Rotational Viscometry -- RESULTS -- DISCUSSION -- CONCLUDING REMARKS -- ACKNOWLEDGMENTS -- REFERENCES -- POLYPROPYLENE AND NATURAL FIBERS FORSTABILIZATION OF SOIL-CEMENT COMPOSITES -- 1. INTRODUCTION -- 2. EXPERIMENTAL PROGRAM AND RESULTS -- 3. BACKGROUND TO MICROMECHANICAL MODELS -- 3.1. Rule of Mixture (ROM) -- 3.2. Inverse Rule of Mixture -- 3.3. Cox's Model (Modified Rule of Mixture) -- 3.4. Halpin-Tsai Equation -- 3.5. Development of a New Model Suitable for Green Composites -- Model 1 -- Model 2 -- 4. MATHEMATICAL MODELS -- 5. DISCUSSION OF RESULTS -- CONCLUSION -- APPENDIX -- REFERENCES.

NEW CONDENSATION MONOMERS AND POLYMERSBASED ON TNT-DERIVATIVES -- ABSTRACT -- I. INTRODUCTION -- II. SYNTHESIS OF CONDENSATION MONOMERS BASED ONTNT AND ITS DERIVATIVES -- II. 1. TNB-BASED CONDENSATION MONOMERS -- II. 2. TNT-BASED CONDENSATION MONOMERS -- III. POLYMERS SYNTHESIS -- III. 1. Polymers Based on TNB Derivatives -- III. 2. Polymers Based on TNT Derivatives -- CONCLUSIONS -- ACKNOWLEDGMENTS -- REFERENCES -- INFLUENCE OF PORPHYRIN AND ITS METALCOMPLEXES ON THE RADICAL POLYMERIZATION OFMETHYL METHACRYLATE -- ABSTRACT -- INTRODUCTION -- EXPERIMENTAL SECTION -- RESULTS AND DISCUSSION -- CONCLUSION -- ACKNOWLEDGMENTS -- REFERENCES -- SYNTHESIS AND USE OF NEWFERROCENECONTAINING CATALYSTS ANDPLASTICIZERS FOR BURNING OF THE SOLID FUELSOF SPECIAL PURPOSE -- ABSTRACT -- INTRODUCTION -- EXPERIMENTAL -- GENERAL RESULTS -- USE OF SYNTHESIZED FEROCENECONTAINING ALCOHOLS -- CONCLUSIONS -- REFERENCES -- ANALYSIS OF SOLVENTS PROPERTIES INFLUENCE ONKINETICS OF SOME HOMOLYTIC REACTIONS -- ABSTRACT -- I. DECOMPOSITION OF PERACIDS ESTERS -- REFERENCES -- THE INFLUENCE OF MEDIUM ON THE THERMOLYSISOF DIACYL- AND DIALKYLPEROXIDES -- ABSTRACT -- Table 1. Constants of the benzoil peroxide decomposition -- Table 2. The rate of acetyl peroxide decomposition into n-alkanes at80 0С accordingly to [6] -- Table 3. Constants of rate at 80 0С and energies of activation for the reactions of benzoylperoxide and furoyl peroxide decomposition [8] -- Table 4. Logarithms of the rate constants for homolytic decomposition of benzoylperoxide at 80 0С (k, h-1) -- Table 5. Data for non-initiated decomposition of benzoyl peroxide -- Table 6. The rate constants of the initiated decomposition of benzoil peroxide at80 0С, k3/2, (mol/l)-.

Table 7. Rate constants of the propionyl and butyryl peroxides thermolysis in accordance with the data [22] and iso-butyryl peroxidethermolysis accordingly to data [20] and also characteristics of the used solvents at 20 0С.