Magnetic Isotope Effect in Chemistry and Biochemistry -- Contents -- Preface -- Introduction -- Energy and Angular Momentum as the Reaction Controlling Factors -- 1.1. Energy -- 1.2. Angular Momentum -- Spin Control of Chemical Reactions -- 2.1. Spin States and Chemical Reactivity -- 2.2. Magnetic Interactions and Magnetic Effects -- Magnetic Isotope Effect (MIE) -- 3.1. How to Discriminate Classical and Magnetic Isotope Effects -- 3.2. MIE: How It Functions -- 3.3. MIE as a Test of Reaction Mechanism -- 3.4. Nuclear Spin Polarization -- 3.5. MIE and Isotope Technology -- 3.6. MIE: The Road of Discoveries -- Kinetics of Isotope Fractionation -- 4.1. Measurement of Isotope Composition -- 4.2. Analysis of the Kinetic Schemes -- 4.3. Absolute Measure of Isotope Separation -- 4.4. Dynamic Characteristics of Spin Selective Nanoreactor -- 4.5. Is There a Limit in MIE Induced Isotope Fractionation? -- Physics of the MIE -- 5.1. Spin-Selective Nanoreactor: How It Functions? -- 5.2. Spin Dynamics -- 5.3. Molecular Dynamics -- 5.4. Chemical Dynamics -- 5.5. Generalized Spin Dynamics -- MIE for Deuterium-Hydrogen Dyad -- 13C MIE: Controlling Factors -- 7.1. Spin Prohibition: How It Is Rigorous -- 7.2. Hyperfine Coupling and Chemical Reactivity -- 7.3. MIE as a Function of the Magnetic Field -- 7.4. Viscosity, Lifetime of Radicals and a Size of Microreactors -- 7.5. Spin Multiplicity and Competition of Radical and Non-Radical Reaction Channels -- 7.6. MIE as a Function of Molecular Energy -- Oxygen MIE -- 8.1. Fractionation of Isotopes in Chain Reactions of Molecular Oxygen -- 8.2. Addition of Molecular Oxygen to Radicals -- 8.3. Interaction of Peroxy Radicals (Chain Termination Reaction) -- 8.4. Temperature and Viscosity as Controlling Factors of Chemical Spin Selectivity -- 8.5. Nonchain Processes: Endoperoxides - Synthesis and Decomposition.

8.6. Geochemical Anomalies of 17O -- Silicon MIE -- 9.1. Photolysis of Phenylsilylketone -- 9.2. Photolysis of Benzylsilylketone -- 9.3. Spin Multiplicity and The Sign of MIE -- MIE for Sulfur, Germanium and Tin Nuclei -- 10.1. Sulfur -- 10.2. Germanium -- 10.3. Tin -- Uranium MIE -- 11.1. Spin-Selective Reactions to Uranyl -- 11.2. Uranium Nanoreactor -- 11.3. Fractionation of Uranium Isotopes -- Mercury MIE -- 12.1. MIE in Photochemical Reactions -- 12.2. Mercury MIE in Enzymatic Phosphorylation by Creatine Kinase -- Magnesium Isotope Effects -- 13.1. Classical Isotope Effects -- 13.2. Magnetic Isotope Effects in Enzymatic Phosphorylation -- Microwave Effects -- 14.1. Microwave MIE -- Acknowledgements -- References -- Index.