NEW DEVELOPMENTS IN ALDEHYDES RESEARCH -- NEW DEVELOPMENTS IN ALDEHYDES RESEARCH -- CONTENTS -- PREFACE -- SYNTHESIS AND PROPERTIES OF INTERMEDIATES IN REACTIONS OF ALDEHYDES WITH P (III) CHLORIDES -- ABSTRACT -- INTRODUCTION -- 1. THE BRIEF HISTORICAL SURVEY OF REACTIONS OF ALDEHYDES WITH P(III) CHLORIDES -- 2. SYNTHETIC METHODS AND STRUCTURE OF PRIMARY INTERMEDIATES -- 3. CHEMICAL PROPERTIES OF THEPRIMARY INTERMEDIATES -- 3.1. Interaction of Intermediates 12with Ethylene Oxide, Acetal, Trialkyl Orthoformates and Trialkyl Phosphites -- 3.2. Reactions of Intermediates10b-C with Acetals and Trialkyl Orthoformates -- 3.3. Oxidation of Primary Intermediates (R -- 3.4. Interaction of Intermediates 12f-Iwith Phosphorus Pentachloide and Chlorine -- 4. REACTIONS OF THE PRIMARY INTERMEDIATESWITH ALDEHYDES AND DETECTION OF THE SECONDARY INTERMEDIATES -- Conclusion -- 5. DESCRIPTION OF THE EXPERIMENTS -- 5.1. Removing of HCl Contaminant from P(III) Chlorides -- 5.1.1. By Treatment with Tertiary Amines -- 5.1.2. By Treatment with AVE Ethy -- 5.2. Reactions of P(III) Chlorides with Aldehydes -- 5.2.1. Interaction of P(III) Chlorides with Acetaldehyde in the Absence of Catalyst -- 5.2.2. Reaction of P(III) Chloride with Aldehydes in the Presence of Tertiary Amines -- General Procedure The -- 1-Chloro-2-Methylpropyl Phosphorodichloridite 10c -- 1-Chlorobutyl Phosphorodichloridite 10b -- 1-Chloroethyl Phosphorodichloridite 10a -- Di(1-chloroethyl) phosphorochloridite 11a The rea -- Tri(1-chloroethyl) Phosphite 12a 3 -- 5.2.3. Reaction of P(III) Chlorides with Aldehydes in Presence of EVE -- General Procedure Ethy -- Catechol 1-chloro-2,2-dimethylpropyl Phosphite 12i -- Catechol 1-chloro-2-methylpropyl Phosphite 12f. The reac -- 1-Chloro-2-methylpropyl bis(2,2,2-trichloroethyl) Phosphite 12b -- Di(1-chloroethyl) 2,2,2-trichloroethyl Phosphite 12e.

5.3. Reactions of Primary Intermediates with Nucleophiles -- 5.3.1. With Ethylene Oxide -- 5.3.2. With Trialkylphosphite -- 5.3.3. With the Acetals -- 5.3.4. With Trialkyl Orthoformate -- 5.3.5. With α-Chlorodiethyl Ether -- 5.4. Oxidation of the Primary Intermediates -- 5.4.1. With Dimethylsulfoxide (DMSO) -- 1-Chloroethyl Dichlorophosphate 65a Benz -- 1-Chlorobutyl Dichlorophosphate 65b On anal -- 1-Chloro-2-methylpropyl Dichlorophosphate65c -- Catechol 1-chloroethyl Phosphate 65f O -- Catechol 1-chlorobutyl Phosphate 65g -- 1,2,2,2-Tetrachloroethyl Dichlorophosphate 65l -- Di(1-chloroethyl) Chlorophosphate 65d O -- Di(1-Chloro-2-Methylpropyl) 2,2,2-Trichloroethyl Phosphate 65n -- 1-Chloro-2-Methylpropyl Bis (2,2,2-Trichloroethyl) Phosphate 65h. -- Di(1-Chloroethyl) 2,2,2-Trichloroethyl Phosphate 65o. -- 5.4.2. With t-BuOCl -- 1-Chloroethyl Dichlorophosphate 65a BuO -- 1-Chlorobutyl Dichlorophosphate 65b O -- 1-Chloro-2-Methylpropyl Dimethyl Phosphate 65i -- 1-Chloro-2-Methylprophyl Diethyl Phosphate 65j -- Di(1-Chloroethyl) Methyl Phosphate 65m -- 1-Chloroethyl Dimethyl Phosphate 65k O -- 5.5. With PCl5 and Chlorine -- 5.6. Reactions of the Intermediates 11a, 12a and 12b with Aldehydes. Detection of the Secondary Intermediates -- REFERENCES -- SYNTHESIS OF HETEROCYCLIC COMPOUNDS BY INTERACTION OF ALDEHYDES WITH MONOTERPENOIDS -- ABSTRACT -- INTRODUCTION -- INTERACTION OF ALDEHYDES WITH ACYCLIC MONOTERPENOIDS -- INTERACTION OF ALDEHYDES WITH MONOCYCLIC MONOTERPENOIDS -- INTERACTION OF ALDEHYDES WITH BICYCLIC MONOTERPENOIDS -- Interaction of Aldehydes with Monoterpenoids with Pinane Framework -- INTERACTION OF ALDEHYDES WITH MONOTERPENOIDS WITH CAMPHANE FRAMEWORK -- INTERACTION OF ALDEHYDES WITH MONOTERPENOIDS CONTAINING CYCLOPROPANE RING -- CONCLUSION -- REFERENCES -- UPDATE ON ALIPHATIC ALDEHYDES IN LIPID FOODS -- ABSTRACT -- 1. INTRODUCTION.

2. SHORT-CHAIN ALIPHATIC ALDEHYDES -- Short-Chain Aldehyde Activities -- Volatile Aldehyde Isolation and Quantitative Determination -- 2. MEDIUM-CHAIN ALDEHYDES -- 3. LONG-CHAIN ALDEHYDES -- Analysis of Long-Chain Aldehydes -- Gas Chromatography Studies -- High Performance Liquid Chromatography -- Studies of LCAA by TLC -- Studies on the Identification of LCAA by GC-MS -- Studies on the Relationship of LCAA and Other Minor Compounds It has -- REFERENCES -- INHIBITION OF MICROBIAL BIOCATALYSTS BYBIOMASS-DERIVED ALDEHYDES AND METHODS FOR ENGINEERING TOLERANCE -- ABSTRACT -- INTRODUCTION -- FORMATION AND RELEASE OF ALDEHYDES DURING BIOMASS PROCESSING -- INHIBITION OF MICROBIAL BIOCATALYSTS BY ALDEHYDES -- SELECTIVE REMOVAL OF ALDEHYDES -- INCREASING MICROBIAL TOLERANCE TO ALDEHYDES -- Ethanologenic E. coli -- Yeast -- Clostridium -- CONCLUSION -- ACKNOWLEDGMENTS -- REFERENCES -- CO-OXIDATION PROCESSES PROMOTED BY N-HYDROXYPHTHALIMIDE/ ALDEHYDE SYSTEM -- ABSTRACT -- 1. INTRODUCTION -- 2. OXYGEN ACTIVATION USING SACRIFICIAL ALDEHYDES -- 2.1. Epoxidation of Olefins -- 2.2. Oxidation of Sulfides, Alcohols and Alkanes -- 3. SELECTIVE AEROBIC OXIDATION PROMOTED BY NHPI/ALDEHYDE SYSTEMS -- 3.1. Molecule-Induced Homolysis of NHPI -- 3.2. Selective Epoxidation of Olefins with NHPI -- 3.3. Selective Hydroperoxidation of Secondary and Tertiary Alkylaromatics -- CONCLUSION -- REFERENCES -- SYNTHESIS AND STRUCTURE OF GOSSYPOL CONDENSATION BIS-PRODUCT WITH 2-AMINO-4,6-DIOXYPYRIMIDINE IN ACIDIC ENVIRONMENT -- ABSTRACT -- INTRODUCTION -- RESULTS AND DISCUSSION -- EXPERIMENTAL PART -- CONCLUSION -- REFERENCES -- INDEX.