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Experimental methods in kinetic studies
Title:
Experimental methods in kinetic studies
Author:
Wojciechowski, Bohdan W., 1935-
ISBN:
9780444513144
Edition:
Rev. ed.
Publication Information:
Amsterdam ; Boston : Elsevier, 2003.
Physical Description:
xii, 310 p. : ill. ; 25 cm.
Contents:
1. Reactor Types and their Characteristics -- 2. Collecting Data under Isothermal Operation -- 3. Using Kinetic Data in Reaction Studies -- 4. Difficulties with Mechanistic Rate Expressions -- 5. The Theory of Temperature Scanning Operation -- 6. Verification of Kinetic Dominance -- 7. Processing of Data -- 8. Fitting Rate Expressions to TSR Data -- 9. Interpretation of Rate Parameters -- 10. Statistical Evaluation of Multiparameter Fits -- 11. Experimental Studies Using TSR Methods -- 12. Using a Mechanistic Rate Expression -- 13. TSR Hardware Configurations -- References -- Index.
Abstract:
This book is a guide to kinetic studies of reaction mechanisms. It reviews conventional reactor types and data collection methods, and introduces a new methodology for data collection using Temperature Scanning Reactors (TSR). It provides a theoretical and practical approach to temperature scanning (TS) methodology and supports a revival of kinetic studies as a useful approach to the fundamental understanding of chemical reaction mechanisms and the consequential reaction kinetics. Describes a new patented technology Of interest to industrial and academic researchers in the fields of kinetics and catalysis No existing competitor for this title.
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