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Hydrogen-Bonded Interpolymer Complexes : Formation, Structure and Applications.
Title:
Hydrogen-Bonded Interpolymer Complexes : Formation, Structure and Applications.
Author:
Khutoryanskiy, Vitaliy V.
ISBN:
9789812709776
Personal Author:
Physical Description:
1 online resource (377 pages)
Contents:
CONTENTS -- ABOUT THE EDITORS -- Preface -- Chapter 1: pH- and Ionic Strength Effects on Interpolymer Complexation via Hydrogen-Bonding Vitaliy V. Khutoryanskiy, Artem V. Dubolazov and Grigoriy A. Mun -- 1. Methods used for determination of critical pH values -- 2. Factors affecting the critical pH values -- 3. pH-induced complexation - miscibility - immiscibility transitions -- 4. Concluding remarks -- References -- Chapter 2: Hydrogen-Bonded Interpolymer Complexes Soluble at Low pH Georgios Staikos, Maria Sotiropoulou, Georgios Bokias, Frederic Bossard, Julian Oberdisse -- 1. Introduction -- 2. Structure of the graft copolymers -- 3. Complexes formed between PAA and P(AA-co-AMPSA)-g- PDMAM graft copolymers -- 3.1. Dilute solution study -- 3.2. Small angle neutron scattering study -- 3.3. Characterization of the particles formed as soluble hydrogenbonded IPCs at low pH -- 3.4. Semi-dilute solution study -- 5. Complexes formed between PEG and PAA grafted with negatively charged PAMPSA chains -- 5.1. Investigation of the complexes using turbidimetry and viscometry, Influence of pH and ionic strength -- 5.2. Influence of the structural characteristics of the graft copolymers -- 5.3. Size of the colloidal nanoparticles formed -- 6. Conclusions -- References -- Chapter 3: Potentiometric Investigation of Hydrogen-Bonded Interpolymer Complexation Georgios Staikos, Gina-Gabriela Bumbu and Georgios Bokias -- 1. Introduction -- 2. Evaluation of potentiometric data -- 2.1. Potentiometric investigation of stoichiometric mixtures -- 2.2. Potentiometric titrations -- 2.2.1. Potentiometric titration of a polyacid with a Lewis polybase -- 2.2.2. Potentiometric titration of a Lewis polybase with a polyacid -- 2.3. Potentiometric investigation under "iso-pH" conditions -- 3. Concluding remarks -- References.

Chapter 4: Polarized Luminescence and Nanosecond Dynamics in the Studies of Interpolymer Complexes Elizaveta V. Anufrieva, Mark G. Krakovyak, Tatiana N. Nekrasova and Ruslan Yu. Smyslov -- 1. Structure and designation of polymers -- 2. Influence of chemical nature and IMM of individual polymer chains on their structure in IPC in aqueous solutions or in methanol -- 3. Influence of IPC tertiary structure in water on the efficiency of addition reactions -- 4. Formation of IPC consisting of homo- and copolymers -- 5. IPC stability -- 6. Supramolecular chemical reactions with interpolymer complexes -- 6.1. Exchange reactions -- 6.2. Substitution reactions -- 6.3. Addition reactions -- 7. Conclusion -- References -- Chapter 5: Intramolecular Polycomplexes in Block and Graft Copolymers Tatyana Zheltonozhskaya, Nataliya Permyakova and Lesya Momot -- 1. Introduction -- 2. Intramolecular polycomplexes -- 3. Matrix phenomena in synthesis of block and graft copolymers -- 4. Hydrogen-bonding system in IntraPC stabilization -- 5. Peculiarities of the bulk structure of IntraPC -- 6. Stimuli-responsive behavior of IntraPC in solutions -- 7. The application spectrum of intramolecular polycomplexes -- References -- Chapter 6: Interpolymer Complexes Obtained by Template Polymerization Stefan Połowiński -- 1. Introduction -- 2. Radical template polymerization -- 3. Template polycondensation -- 4. Template radical copolymerization -- 5. Separation of the template and the daughter polymer -- References -- Chapter 7: Interpolymer Complexes Containing Copolymers Gina-Gabriela Bumbu, John Eckelt and Cornelia Vasile -- 1. Introduction -- 2. IPC containing the copolymer as a polybase -- 2.1. Random copolymers -- 2.2. Graft-copolymers -- 2.3. Block copolymers -- 3. IPC based on polyacid copolymers in water -- 3.1. Alternating or random copolymers -- 3.2. Graft-copolymers.

4. IPC in organic solvents -- References -- Chapter 8: Inter- and Intramolecular Polycomplexes in Polydispersed Colloidal Systems Tatyana Zheltonozhskaya, Nataliya Permyakova and Boris Eremenko -- 1. Introduction -- 2. Stability of polymer-colloidal systems from some points of view -- 3. Behavior of Inter- and IntraPC in polydispersed suspensions -- 4. Inter- and IntraPC in monodispersed silica suspensions -- 5. Possible reasons for the high flocculating ability of polycomplexes -- References -- Chapter 9: Pharmaceutical Applications of Interpolymer Complexes Vitaliy V. Khutoryanskiy -- 1. Mucoadhesive dosage forms: tablets, films and microspheres -- 2. Formulation of poorly water-soluble drugs -- 3. Formulation of hydrophilic drugs -- 4. Encapsulation of biomacromolecules and microorganisms -- 5. Nanoparticles and nanogels -- 6. In-situ gelling systems -- 7. Hydrogels with interpolymer complexation -- 8. Conclusions -- References -- Chapter 10: Radiation Cross-Linked Hydrogen-Bonding Interpolymer Complexes Artur Henke, Piotr Ulański and Janusz M. Rosiak -- 1. Stability of hydrogen-bonding interpolymer complexes -- 2. Chemical- and UV-induced permanent stabilization of hydrogen-bonded interpolymer complex systems -- 2.1. Synthesis of hydrogels -- 2.2. Synthesis of nano/microgels -- 3. Radiation-induced synthesis of materials based on hydrogenbonded interpolymer complex systems -- 3.1. Radiation-induced processes in aqueous solution of polymers -- 3.2. Radiation-induced cross-linking of hydrogen-bonding interpolymer complexes in a blend -- 3.3. Radiation-induced cross-linking of hydrogen-bonded interpolymer complexes and monomer systems in aqueous solutions -- 3.4. Radiation-induced synthesis of two-component nanogels based on poly(N-vinylpyrrolidone)-poly(acrylic acid) interpolymer complexes.

3.4.1. Formation of poly(N-vinylpyrrolidone)-poly(acrylic acid) interpolymer complexes and their aggregates -- 3.4.2. Structure of poly(N-vinylpyrrolidone)-poly(acrylic acid) interpolymer complexes and their aggregates -- 3.4.3. Radiation-induced stabilization of poly(N-vinylpyrrolidone)- poly(acrylic acid) interpolymer complexes in dilute aqueous solution -- 4. Concluding remarks -- Acknowledgments -- References -- Chapter 11: Prevention of Soil Migration and Capturing of Radionuclides by Interpolymer Complexes Sarkyt E. Kudaibergenov, Larisa A. Bimendina and Marziya G. Yashkarova -- 1. Using of polymers and composites for soil aggregation -- 2. Interpolymer complexes as soil structuring agents -- 3. Ternary polymer-metal complexes and capturing of 90Sr from radioactively polluted topsoils -- 4. Conclusion -- References -- Chapter 12: Hydrogen-Bonded Layer-by-Layer Polymer Films and Capsules Veronika Kozlovskaya, Eugenia Kharlampieva and Svetlana A. Sukhishvili -- 1. Introduction -- 1.1 Chemical nature of multilayer components -- 1.2. Molecular weight of polymers -- 1.3. The pH of polymer solutions -- 1.4. Ionic strength of polymer solutions -- 1.5. Concentration of assembly solution -- 1.6. Temperature of polymer solutions -- 2. Hydrogen-Bonded Polymer/Polymer Films -- 2. Hydrogen-Bonded Polymer/Particle Films -- 3. Response of Hydrogen-Bonded Polymer Films to Environmental Stimuli -- 3.1. Response of uncross-linked hydrogen-bonded films -- 3.1.1. pH-Response -- 3.1.2. Effect of salts -- 3.1.3. Effects of temperature -- 3.1.4. Humidity response -- 3.1.5. Incorporation of small functional molecules -- 3.2. Hydrogen-Bonded Capsules -- 3.2.1. The effect of template -- 3.2.2. The effect of pH -- 3.2.3. Crosslinked hydrogen-bonded capsules -- 3.2.4. Mechanical properties of hydrogen-bonded capsules.

3.2.5. pH-Controlled permeability of hydrogen-bonded capsules -- 4. Conclusions -- Acknowledgment -- References -- Index.
Abstract:
There has been an increased interest among researchers in hydrogen-bonded interpolymer complexes since the first pioneering papers were published in the early 1960s. Several hundred research papers have been published on various aspects of complex formation reactions in solutions and interfaces, properties of interpolymer complexes and their potential applications. This book focuses on the latest developments in the area of interpolymer complexation via hydrogen bonding. It represents a collection of original and review articles written by recognized experts from Germany, Greece, Kazakhstan, Poland, Romania, Russia, UK, Ukraine, and the USA. It highlights many important applications of interpolymer complexes, including the stabilization of colloidal systems, pharmaceuticals, and nanomaterials.
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Electronic reproduction. Ann Arbor, Michigan : ProQuest Ebook Central, 2017. Available via World Wide Web. Access may be limited to ProQuest Ebook Central affiliated libraries.
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