Reactions of oxomolybdenum compounds with nitrogen donor ligands and related computational calculational calculations
Title:
Reactions of oxomolybdenum compounds with nitrogen donor ligands and related computational calculational calculations
Author:
Öcal, Jale.
Personal Author:
Publication Information:
[s.l.]: [s.n.], 2009.
Physical Description:
ix, 78 leaves.: ill. + 1 computer laser optical disc.
Abstract:
Reactions of the dioxomolybdenum(VI) compound, MoCl2O2 with phenylenediamine derivatives the bidentate N-N nitrogen ligands 1-8 (ophenylenediamine, N-phenyl-o-phenylenediamine, 4-Methyl-o-phenylenediamine, 4-Nitro-o-phenylenediamine, p-phenylenediamine, N-phenyl-p-phenylenediamine, 2,6- dichloro-p-phenylenediamine, 2,3,5,6-tetramethyl-p-phenylenediamine, respectively) have been examined under nitrogen in THF solution. The novel dioxomolybdenum complexes were characterized by elemental analysis, FT-IR, 1H-NMR and 13C-NMR spectroscopy. In addition, molecular mechanics and quantum chemical calculations including semi empirical PM3 and DFT methods were carried out to discuss the stability of the compounds.
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Thesis (Master)--İzmir Institute of Technology:Chemistry.
İzmir Institute of Technology:Chemistry--Thesis (Master).
Electronic Access:
Access to Electronic Version.