This thesis presents studies of the defect centers in hBN and design of nonlinear waveguide. The multilayer hBN flakes and Si3N4 waveguide are available materials in modern nanophotonics applications. The color centers in hBN are consisted of quantized states because each defect center has different saturation power and dipole polarization. The line shape of emission from defect centers is directly depended photon vibrations and temperature of sample. Moreover, phonon bands in the color centers affect the wavelength of emission and we statistically worked on the phonon effects on ZPL. The Si3N4 waveguide can be more efficient chip scale photon pair sources to create entangled photons in visible band. The zero dispersion wavelength calculations give an efficient waveguide geometry as 650×600 nm2 for 780 nm pump wavelength.