Contents -- Part I. Problems -- 1 Warmup for Inorganic Chemists -- 1. Safety of Hydrogen Fluoride Cylinders -- 2. Bond Dissociation Energy of the Molecule of Fluorine -- 2 Introduction of Fluorine -- 3. Addition of Fluorine to Diphenylethylenes -- 4. Rearrangement in the Replacement of Hydroxyl by Fluorine in Saccharides -- 5. Reaction of β-Dicarbonyl Compounds with Diethylaminosulfur Trifluoride -- 3 Reductions -- 6. Reduction of Unsaturated Fluorinated Compounds -- 7. Reduction of 3-Chlorotetrafluoropyridine -- 8. Reaction of Isopropyl Alcohol with 2-Fluorocyclohexanone -- 4 Oxidations -- 9. Oxidation of Chlorotrifluoroethylene with Oxygen -- 10. Reaction of Perfluoro-o-phenylenediamine with Lead Tetraacetate -- 11. Reaction of Fluorinated Aromatic Diamines with Nitrous Acid -- 5 Preparation of Halogen Derivatives -- 12. Addition of Iodine Fluoride to Chlorotrifluoroethylene -- 13. Addition of Hydrogen Bromide to Chlorotrifluoroethylene -- 14. Addition of Hydrogen Chloride to 3,3,3-Trifluoropropene -- 15. Addition of Hydrogen Halides to Perfluoropropene -- 16. Reaction of Perfluoroalkenes with Metal Fluorides -- 17. Chlorination of o-Fluorotoluene -- 18. Chlorination of 3,4-Difluoronitrobenzene -- 19. Reaction of Fluoropentanitrobenzene with Hydrogen Chloride -- 20. Reaction of 1,1-Difluoroethylene with Trifluoroacetyl Hypochlorite -- 21. Reaction of Pentafluorophenol with tert-Butyl Hypobromite -- 22. Reaction of Perfluorocycloalkenes with Aluminum Halides -- 23. Reaction of Perfluoro-2-butyltetrahydrofuran with Aluminum Chloride -- 24. Reaction of Perfluorotetrahydropyran with Aluminum Chloride -- 6 Nitration -- 25. Nitration of o-Fluorotoluene -- 7 Reactions of Sulfur Trioxide -- 26. Reaction of Sulfur Trioxide with Enol Ethers -- 27. Reaction of Sulfur Trioxide with Perfluoro-tert-butylacetylene.

28. Reaction of Sulfur Trioxide with Perfluoroisobutylene -- 29. Reaction of Sulfur Trioxide with Perfluoropropylene Oxide -- 30. Reaction of Sulfur Trioxide with Perfluorotoluene -- 8 Acid-Catalyzed Additions and Substitutions -- 31. Reaction of Benzene with 1-Chloro-2-fluoropropane -- 32. Reaction of Benzene with 2-Chloro-1,1,1-trifluoropropane -- 33. Reaction of Benzene with 3,3,3-Trifluoropropene -- 34. Reaction of 1-Phenylperfluoropropene with Aluminum Chloride -- 9 Hydrolyses -- 35. Hydrolysis of Benzyl Halides -- 36. Hydrolysis of ω-Fluorocarboxylic Acids and Their Nitriles -- 37. Hydrolysis of Perfluorocycloalkenes -- 38. Reaction of 3,5-Dichlorotrifluoropyridine with Potassium Hydroxide -- 39. Reaction of 2,5-bis(Trifluoromethyl)aniline with Sodium Hydroxide -- 40. Reaction of Heptafluorobutyraldehyde Hydrate with Potassium Hydroxide -- 41. Reaction of Pentafluoroethyl Iodide with Potassium Hydroxide and Water -- 42. Hydrolysis of Unsaturated Fluorinated Compounds -- 43. Hydrolysis of Geminal Difluorides -- 44. Hydrolysis of Difluoromethylene Group in Enol Ethers -- 45. Reaction of Alkalis with Fluorinated Cyclopropanes -- 46. Product of Treatment of p-Trifluoromethylphenol with Potassium Hydroxide -- 10 Alkylations -- 47. Reaction of 1-Chloro-3,3,4,4-tetrafluorocyclobutene with Potassium Hydroxide and Ethanol -- 48. Reaction of 1-Bromo-2-chlorotetrafluorocyclobutene with Potassium Hydroxide -- 49. Reaction between 1-Chloro-2-fluoroethane and Ethyl Acetoacetate -- 50. Reaction of Pentafluorophenol with Chlorodifluoromethane and Sodium Hydroxide -- 51. Reaction of 1,4-Dibromohexafluoro-2-butene with Sodium Ethoxide -- 52. Reaction of Perfluoro-3,4-dimethyl-3-hexene with Methanol -- 53. Reaction of Chlorotrifluoroethylene with Sodium Ethoxide -- 54. Reaction of Perfluoro-γ-butyrolactone with Perfluoropropylene Oxide.

55. Reaction of Alkali Thiophenoxides with Polyfluorohalomethanes -- 56. Reaction of Perfluorodecalin with Sodium Thiophenoxide -- 57. Reaction of Perfluorocyclobutene with Hydrazine -- 58. Reaction of 1,2,3,5-tetrakis(Trifluoromethyl)benzene with Ammonia -- 59. Reaction of Perfluoroisobutylene with Dimethyl Malonate -- 60. Reaction of Perfluorobenzotrichloride and Chlorodifluoromethane -- 61. Reaction of Enamines with Trifluoromethanesulfenyl Chloride -- 62. Reaction of 1,1-Dichlorodifluoroethylene with Methanol -- 63. Reaction of Chlorotrifluoroethylene with Aniline -- 64. Reaction of Chlorotrifluoroethylene with Dimethylamine -- 65. Reaction of Alcohols with Perfluoroalkenes -- 66. Reaction of Fluoroalkenes with Azides -- 11 Arylations -- 67. Reaction of 1,2-Difluorotetrachlorobenzene with Sodium Methoxide -- 68. Reaction of 2,4-Dinitrohalobenzenes with Sodium Methoxide -- 69. Reaction of Fluoropentachlorobenzene with Potassium p-Methoxyphenoxide -- 70. Reaction of Perfluoronaphthalene with Sodium Alkoxides or Aryloxides -- 71. Reaction of Perfluoropyridine with Methanol -- 72. Arylation at Sulfur -- 12 Acylations -- 73. Acylations with Mixed Anhydrides of Trifluoroacetic Acid -- 13 Aldol-Type Condensations -- 74. Reaction of 1,1,1-Trifluoroacetone, Formaldehyde, and Piperidine -- 75. Reaction of α,α,α -Trifluoroacetophenone with Tributylphosphine -- 76. Reaction of Dibromodifluoromethane and tris(Dimethylamino)phosphine with Fluorinated Ketones -- 77. Reactions of Phosphorus Ylides with Fluorinated Nitriles -- 78. Reaction of tris(Trifluoromethyl)methane with Acrylonitrile -- 14 Organometallic Syntheses -- 79. Reaction of Ethyl Chlorofluoroacetate with Grignard Reagents -- 80. Reaction of 3-Chloropentafluoropropene with Phenylmagnesium Bromide -- 81. Reaction of 1,2-Dichlorohexafluorocyclopentene with Ethylmagnesium Bromide.

82. Reaction of 1,2-Dichloro-1-fluoroethylene with Butyllithium and Acetone -- 83. Reaction of Trifluoroethylene with Butyllithium and Acetone -- 84. Reaction of 1-Chloro-1,2-difluoroethylene with Butyllithium and Carbon Dioxide -- 85. Reaction of Aldehydes with 1,1,1 -Trichlorotrifluoroethane and Zinc in the Presence of Acetic Anhydride -- 86. Reaction of Aldehydes with 1,1,1-Trichlotrifluororoethane and Zinc in the Presence of Aluminum Chloride -- 87. Reaction of Dibromodifluoromethane and 4-Chloro-3-nitrobenzotrifluoride with Copper -- 15 Additions -- 88. Reaction of 2-Aminoethanol with Ethyl 4,4,4-Trifluoro-3-trifluoromethyl-2-butenoate -- 89. Reaction of 1,1-Dichlorodifluoroethylene with 1,3-Butadiene -- 90. Reaction of 1,2-Dichlorodifluoroethylene with Perfluoropropylene Oxide -- 91. Reaction between Perfluorovinylsulfur Pentafluoride and 1,3-Butadiene -- 92. Reaction between Trifluoroethylene and 1,3-Butadiene -- 93. Reaction between Hexafluoroacetone Azine and Acetylene -- 94. Reaction of tris(tert-Butyl)azete and Trifluoroacetonitrile -- 95. Dimerization of Perfluoro-1,3-butadiene -- 16 Eliminations -- 96. Reaction of Alkalis with Fluorinated Cyclopropanes -- 97. Reaction of Diethy1 threo-2-Bromo-3-fluorosuccinate with Potassium Acetate -- 98. Reaction of 1-Bromo-2-fluorocyclohexanes with Bases -- 17 Rearrangements -- 99. Reaction of Fluorohaloethanes with Aluminum Chloride -- 100. Treatment of 3-Chloropentafluoropropene with Antimony Halides -- 101. Reaction of Trifluoronitrosomethane with Ammonia -- 102. The Hofmann Degradation of Perfluorobutyramide -- 103. Irradiation of hexakis(Trifluoromethyl)benzene -- 104. Reaction of 2-Bromoperfluoronaphthalene with Antimony Pentafluoride -- 105. Claisen Rearrangement of Fluoroaromatic Acetylenic Ethers -- Part II. Solutions -- REFERENCES -- AUTHOR INDEX -- A -- B -- C -- D -- E -- F -- G -- H -- I.

J -- K -- L -- M -- N -- O -- P -- R -- S -- T -- V -- W -- Y -- Z -- SUBJECT INDEX -- A -- B -- C -- D -- E -- F -- G -- H -- I -- L -- M -- N -- O -- P -- R -- S -- T -- U -- V -- W -- Y.