Hyphenated Techniques In Speciation Analysis -- Contents -- Part I Principles and Fundamentals -- Chapter 1 The Concept of Speciation Analysis and Hyphenated Techniques -- 1 Introduction -- 2 Speciation Analysis: The Definition -- 3 Occurrence and Classification of Metal Species -- 4 The Concept of Hyphenated Techniques -- 5 The Choice of a Hyphenated Technique -- References -- Chapter 2 Element Specific Detection in Chromatography -- 1 Introduction -- 2 Element Selective Detection in Gas Chromatography -- 3 Element Selective Detection in HPLC -- 4 ICP MS Detection in Chromatography and Electrophoresis -- References -- Chapter 3 Gas Chromatography with ICP MS Detection -- 1 Introduction -- 2 Derivatisation Techniques for Gas Chromatography of Organometallic Species -- 3 Separation of Organometallic Species by GC -- 4 Interfacing GC to ICP MS -- 5 Choice of the Mass Spectrometer -- 6 GC-ICP MS Studies Using Stable Isotopes -- References -- Chapter 4 Liquid Chromatography with ICP MS Detection -- 1 Introduction -- 2 Separation of Element Species by Liquid Chromatography -- 3 Interface Between HPLC and ICP MS -- References -- Chapter 5 Electrophoretic Techniques with Element Selective Detection -- 1 Introduction -- 2 Flatbed Gel Electrophoresis -- 3 Capillary Zone Electrophoresis (CZE) -- 4 Areas of Applications -- References -- Chapter 6 Electrospray Mass Spectrometry in Elemental Speciation Analysis -- 1 Introduction -- 2 Principles of Electrospray Mass Spectrometry -- 3 Speciation-Relevant Information from Electrospray MS -- 4 Areas of Application -- References -- Chapter 7 Quality Control and Assurance in Speciation Analysis -- 1 Introduction -- 2 Definition of the Target Moiety -- 3 Stability of Species -- 4 Recovery -- 5 Contamination Risk -- 6 Standardisation -- 7 Isotope Dilution Analysis.

8 Interlaboratory Studies and Certified Reference Materials -- References -- Part II Applications -- Chapter 8 Multielement Analysis of Organometallic Species in the Environment -- 1 Introduction -- 2 Cryogenic Trapping Followed by Low Temperature GC-ICP MS -- 3 Identification, Calibration and Quantification -- 4 Overview of Applications -- References -- Chapter 9 Speciation of Organotin Compounds -- 1 Introduction -- 2 Analytical Techniques -- 3 Overview of Applications -- 4 Method Validation -- References -- Chapter 10 Speciation of Organolead Compounds -- 1 Introduction -- 2 Analytical Techniques -- 3 Overview of Applications -- 4 Method Validation -- References -- Chapter 11 Speciation of Organomercury Compounds -- 1 Introduction -- 2 Analytical Techniques -- 3 Overview of Applications -- 4 Sources of Error and Method Validation -- References -- Chapter 12 Metal Speciation in Petroleum-Related Samples -- 1 Introduction -- 2 Mercury in Natural Gas and Gas Condensates -- 3 Arsenic in Natural Gas and Gas Condensates -- 4 Metalloporphyrins in Coal and Shale Oil -- 5 Organolead and Organomanganese Species in Petrol -- References -- Chapter 13 Speciation of Redox States -- 1 Introduction -- 2 Analytical Methodology -- 3 Overview of Applications -- References -- Chapter 14 Speciation of Organoarsenic Compounds in Biological Materials -- 1 Introduction -- 2 Determination of Arsenic Species by HPLC-ICP MS -- 3 Identification of Arsenic Species by Electrospray MS/MS -- 4 Validation of Arsenic Speciation Analysis -- References -- Chapter 15 Speciation of Organoselenium Compounds in Biological Materials -- 1 Introduction -- 2 Volatile Selenium Species in Plants -- 3 SelenoAmino Acids and SelenoPeptides in Yeast and Plants -- 4 Selenoproteins -- 5 Selenium Metabolites in Urine -- 6 Optically Active Selenospecies -- References.

Chapter 16 Speciation of Metal Complexes in Microorganisms, Plants and Food of Plant Origin -- 1 Introduction -- 2 Metal Complexes with Water-Soluble Proteins and Polypeptides -- 3 Metal Complexes with Polysaccharides -- 4 Metal Complexes with Phytometallophores -- 5 Other Metal Species in Plant Tissues -- References -- Chapter 17 Speciation of Metal Complexes with Metallothioneins -- 1 Introduction -- 2 Recovery of Metal Complexes with Metallothioneins from Biological Tissues -- 3 Liquid Chromatography with ICP MS Detection -- 4 Capillary Electrophoresis-ICP MS -- 5 Identification of MT Isoforms by Electrospray MS -- 6 Analysis of Human and Animal Tissue Samples -- References -- Chapter 18 Speciation of Metal Complexes in Human Body Fluids and Tissues -- 1 Introduction -- 2 Analytical Techniques -- 3 Overview of Applications -- References -- Chapter 19 Metal Speciation in Pharmacology: Metallodrugs -- 1 Introduction -- 2 Analytical Techniques -- References -- Subject Index.