Chemical Bonding at Surfaces and Interfaces.
Title:
Chemical Bonding at Surfaces and Interfaces.
Author:
Nilsson, Anders.
ISBN:
9780080551913
Personal Author:
Physical Description:
1 online resource (533 pages)
Contents:
Front Cover -- Chemical Bonding at Surfaces and Interfaces -- Copyright Page -- Table of Contents -- Preface -- Chapter 1 Surface Structure -- 1. Why surface structure? -- 2. Methods of surface adsorbate structure determination -- 2.1. General comments -- 2.2. Electron scattering -- 2.3. X-ray scattering -- 2.4. Ion scattering -- 2.5. Spectroscopic methods and scanning probe microscopy -- 3. Adsorbate-induced surface reconstruction -- 4. Molecular adsorbates - local sites, orientations and intramolecular bondlengths -- 4.1. General issues and the case of CO on metals -- 4.2. Simple hydrocarbons on metals -- 4.3. Carboxylates on metals -- 4.4. Other substrates: molecules on Si -- 5. Chemisorption bondlengths -- 5.1. Metal surfaces -- 5.2. Oxide surfaces -- 6. Conclusions -- Chapter 2 Adsorbate Electronic Structure and Bonding on Metal Surfaces -- 1. Introduction -- 2. Probing the electronic structure -- 3. Adsorbate electronic structure and chemical bonding -- 4. Adsorbate systems -- 5. Radical atomic adsorption -- 5.1. The electronic structure of N on Cu(100) -- 5.2. Chemical bonding of atomic adsorbates -- 6. Diatomic molecules -- 6.1. N2 adsorbed on Ni(100) -- 6.2. CO adsorbed on Ni(100) -- 6.3. CO adsorbed on Cu(100) and other metals -- 6.4. CO adsorbed in different sites -- 6.5. Coadsorption of CO and K on Ni(100) -- 7. Unsaturated hydrocarbons -- 7.1. Ethylene (C2H4) adsorbed on Ni(110) and Cu(110) -- 7.2. Benzene on Ni and Cu surfaces -- 7.3. Bond energetics and rehybridization from spin-uncoupling -- 8. Saturated hydrocarbons -- 8.1. n-Octane adsorbed on Cu(110) -- 8.2. Difference between octane on Ni and Cu surfaces -- 9. Lone pair interactions -- 9.1. Water adsorption on Pt and Cu surfaces -- 9.2. Adsorption of ammonia and the amino group in glycine on Cu(110) -- 10. Summary.
Chapter 3 The Dynamics of Making and Breaking Bonds at Surfaces -- 1. Introduction -- 2. Theoretical background -- 2.1. Adiabatic dynamics (Born-Oppenheimer approximation) -- 2.2. Generic PES topologies -- 2.3. Dynamics vs. kinetics -- 2.3.1. Direct dissociation -- 2.3.2. Precursor-mediated dissociation -- 2.4. Detailed balance -- 2.5. Lattice coupling -- 2.5.1. Energy transfer in adsorption/scattering -- 2.5.2. Lattice coupling in direct molecular dissociation -- 2.6. Non-adiabatic dynamics -- 2.6.1. Hot electrons from chemistry -- 2.6.2. Chemistry from hot electrons -- 3. Experimental background -- 3.1. Experimental techniques -- 3.2. Typical measurements -- 3.2.1. Rate measurements -- 3.2.2. Adsorption-trapping and sticking -- 3.2.3. Desorption -- 3.2.4. Scattering -- 3.2.5. Initial state preparation -- 3.2.6. Photochemistry/femtochemistry -- 3.2.7. Single molecule chemistry (STM) -- 4. Processes -- 4.1. Atomic adsorption/desorption/scattering -- 4.1.1. Ar/Pt(111) -- 4.1.2. H/Cu(111) -- 4.2. Molecular adsorption/desorption/scattering -- 4.2.1. NO/Ag(111) -- 4.2.2. NO/Pt(111) -- 4.3. Direct dissociation/associative desorption -- 4.3.1. Activated dissociation -- 4.3.2. Weakly activated dissociation -- 4.3.3. Non-activated dissociation -- 4.4. Precursor-mediated dissociation/associative desorption -- 4.4.1. O2/Pt(111) -- 4.5. Direct and precursor-mediated dissociation -- 4.5.1. N2/W(100) -- 4.5.2. NH3/Ru(0001) -- 4.6. Langmuir-Hinschelwood chemistry -- 4.6.1. (O+CO)/Pt(111) -- 4.7. Eley-Rideal/Hot atom chemistry -- 4.7.1. H+H/Cu(111) -- 4.8. Hot electron chemistry -- 4.8.1. Photochemistry/femtochemistry -- 4.8.2. Single molecule chemistry -- 5. Summary and outlook -- Chapter 4 Heterogeneous Catalysis -- 1. Introduction -- 2. Factors determining the reactivity of a transition metal surface.
3. Trends in adsorption energies on transition metal surfaces -- 4. The d-band model -- 4.1. One-electron energies and bond energy trends -- 4.2. The Newns-Anderson model -- 5. Trends in chemisorption energies -- 5.1. Variations in adsorption energies from one metal to the next -- 5.2. Ligand effects in adsorption - changing the d band center -- 5.2.1. Variations due to changes in surface structure -- 5.2.2. Variations due to alloying -- 5.3. Ensemble effects in adsorption - the interpolation principle -- 6. Trends in activation energies for surface reactions -- 6.1. Electronic effects in surface reactivity -- 6.2. Geometrical effects in surface reactivity -- 7. Brønsted-Evans-Polanyi relationships in heterogeneous catalysis -- 7.1. Correlations from DFT calculations -- 7.2. Universal relationships -- 8. Activation barriers and rates -- 8.1. Transition state theory -- 8.2. Variational transition state theory and recrossings -- 8.3. Harmonic transition state theory (HTST) -- 9. Variations in catalytic rates - volcano relations -- 9.1. Dissociation rate-determined model -- 9.2. A Le Chatelier-like principle for heterogeneous catalysis -- 9.3. Including molecular precursor adsorption -- 9.4. Sabatier analysis -- 9.5. A realistic desorption model -- 9.6. Database of chemisorption energies -- 10. The optimization and design of catalyst through modeling -- 10.1. The low-temperature water gas shift (WGS) reaction -- 10.2. Methanation -- 11. Conclusions and outlook -- Chapter 5 Semiconductor Surface Chemistry -- 1. Inroduction -- 2. Structure of semiconductor surfaces -- 2.1. Silicon surface structure -- 2.2. Germanium surface structure -- 3. Surface oxidation -- 3.1. Silicon -- 3.2. Germanium -- 4. Passivation of semiconductor surfaces -- 4.1. Silicon passivation -- 4.1.1. Hydride termination of silicon -- 4.2. Germanium passivation.
4.2.1. Sulfide passivation of germanium -- 4.2.2. Chloride passivation of germanium -- 4.2.3. Hydride termination of germanium -- 5. Reactions at passivated semiconductor surfaces -- 5.1. Organic functionalization of semiconductor surface -- 5.2. Reaction with passivated silicon (Si−H and Si−Cl) -- 5.2.1. Hydrosilylation -- 5.2.2. Grignard reactions on silicon -- 5.3. Reaction with passivated germanium (Ge−H and Ge−Cl) -- 5.3.1. Grignard reactions on germanium -- 5.3.2. Hydrogermylation -- 5.3.3. Alkanethiol reactions on germanium -- 5.4. Reaction with compound semiconductors -- 6. Adsorption of organic molecules under vacuum conditions -- 6.1. Silicon surface chemistry -- 6.1.1. Cycloaddition reaction on Si(100)-2×1 -- 6.1.2. Heterocycloadditions -- 6.1.3. Nucleophilic/electrophilic reactions -- 6.2. Germanium surface chemistry -- 6.2.1. Cycloaddition reactions on Ge(100)-2×1 -- 6.2.2. Heterocycloadditions -- 6.2.3. Nucleophilic/electrophilic reactions -- 6.2.4. Multiple-layer reactions -- 6.3. Summary of concepts in organic functionalization -- Chapter 6 Surface Electrochemistry -- 1. Introduction -- 2. Special features of electrochemical reactions -- 2.1. Electrochemical current and potential -- 2.2. Electrochemical interfaces -- 2.3. Models of electrochemical electron transfer kinetics -- 3. Electrochemistry at the molecular scale -- 3.1. Surface structure -- 3.2. Bonding of ions -- 3.3. Bonding of water -- 3.4. Experimental aspects of current/voltage properties -- 4. Electrocatalytic reaction processes -- 4.1. The electrocatalytic reduction of oxygen -- 4.1.1. Background -- 4.1.2. Mechanistic pathways -- 4.1.3. Electroreduction of oxygen on Pt and Pt alloys -- 4.1.4. Recent quantum chemical studies of the ORR mechanism -- 4.1.5. State-of-the-art ORR electrocatalyst concepts -- 4.2. The electrochemical oxidation of small organic molecules.
4.2.1. The electrooxidation of carbon monoxide -- 4.2.2. The electrooxidation of formic acid and methanol -- 5. Summary and outlook -- Chapter 7 Geochemistry of Mineral Surfaces and Factors Affecting Their Chemical Reactivity -- 1. Introduction -- 2. Environmental interfaces -- 2.1. Common minerals in Earth's crust, soils, and atmosphere, weathering mechanisms and products, and less common minerals that contain or adsorb -- 2.2. Solubilities of Al- and Fe(III)-oxides and Al and Fe(III)-(oxy)hydroxides -- 2.3. Dissolution mechanisms at feldspar-water interfaces -- 2.4. The nature of metal oxide-aqueous solution interfaces - some basics -- 3. Factors affecting the chemical reactivity of mineral surfaces -- 3.1. The reaction of water vapor with metal oxide surfaces - surface science and theoretical studies of simplified model systems illustrating effects of -- 3.2. Grazing incidence EXAFS spectroscopic studies of Pb(II)aq adsorption on metal oxide surfaces - effect of differences in surface functional groups on -- 3.3. The structure of hydrated metal oxide surfaces from X-ray diffraction studies -- 3.4. X-ray standing wave studies of the electrical double layer at solid-aqueous solution interfaces and in situ measurements of surface reactivity -- 3.5. Effect of organic coatings and microbial biofilms on metal oxide surface reactivity - X-ray standing wave studies of metal ion partitioning between -- 4. Conclusions -- Index.
Abstract:
Molecular surface science has made enormous progress in the past 30 years. The development can be characterized by a revolution in fundamental knowledge obtained from simple model systems and by an explosion in the number of experimental techniques. The last 10 years has seen an equally rapid development of quantum mechanical modeling of surface processes using Density Functional Theory (DFT). Chemical Bonding at Surfaces and Interfaces focuses on phenomena and concepts rather than on experimental or theoretical techniques. The aim is to provide the common basis for describing the interaction of atoms and molecules with surfaces and this to be used very broadly in science and technology. The book begins with an overview of structural information on surface adsorbates and discusses the structure of a number of important chemisorption systems. Chapter 2 describes in detail the chemical bond between atoms or molecules and a metal surface in the observed surface structures. A detailed description of experimental information on the dynamics of bond-formation and bond-breaking at surfaces make up Chapter 3. Followed by an in-depth analysis of aspects of heterogeneous catalysis based on the d-band model. In Chapter 5 adsorption and chemistry on the enormously important Si and Ge semiconductor surfaces are covered. In the remaining two Chapters the book moves on from solid-gas interfaces and looks at solid-liquid interface processes. In the final chapter an overview is given of the environmentally important chemical processes occurring on mineral and oxide surfaces in contact with water and electrolytes. Gives examples of how modern theoretical DFT techniques can be used to design heterogeneous catalysts This book suits the rapid introduction of methods and concepts from surface science into a broad range of scientific disciplines where the interaction
between a solid and the surrounding gas or liquid phase is an essential component Shows how insight into chemical bonding at surfaces can be applied to a range of scientific problems in heterogeneous catalysis, electrochemistry, environmental science and semiconductor processing Provides both the fundamental perspective and an overview of chemical bonding in terms of structure, electronic structure and dynamics of bond rearrangements at surfaces.
Local Note:
Electronic reproduction. Ann Arbor, Michigan : ProQuest Ebook Central, 2017. Available via World Wide Web. Access may be limited to ProQuest Ebook Central affiliated libraries.
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