Nanocatalysis : Synthesis and Applications.
Title:
Nanocatalysis : Synthesis and Applications.
Author:
Polshettiwar, Vivek.
ISBN:
9781118610930
Personal Author:
Edition:
1st ed.
Physical Description:
1 online resource (753 pages)
Contents:
NANOCATALYSIS -- CONTENTS -- FOREWORD -- PREFACE -- LIST OF CONTRIBUTORS -- 1 INTRODUCTION TO NANOCATALYSIS -- WHAT IS NANOCATALYSIS? -- NANOCATALYSIS: TRUTH OR HYPE? -- REFERENCES -- 2 NANOCATALYSTS FOR THE HECK COUPLING REACTIONS -- INTRODUCTION -- HETEROGENEOUS CATALYSTS FOR THE HECK REACTION -- SYNTHETIC METHODS TO CATALYSTS FOR THE HECK COUPLING -- Homogeneous Catalysts for the Heck Coupling Reaction -- Heterogeneous Catalysis for the Heck Coupling Reaction -- Some Commercial Applications of the Heck Reaction -- Mechanisms of the Heck Coupling Reaction -- NANOPARTICLES FOR THE HECK COUPLING REACTION -- Pd-NPs-Catalyzed Heck Reaction -- Nanoparticles Composed of Metals Other than Pd for the Heck Coupling Reaction -- CORE-SHELL NANOPARTICLES FOR THE HECK COUPLING REACTION -- MESOPOROUS MATERIALS FOR THE HECK COUPLING REACTIONS -- POLYMERIC-BASED NANOCATALYSTS FOR THE HECK COUPLING REACTIONS -- CARBON NANOMATERIAL-SUPPORTED HECK COUPLING REACTIONS -- REFERENCES -- 3 NANOCATALYSTS FOR THE SUZUKI COUPLING REACTIONS -- SUZUKI COUPLING REACTION -- FROM HOMOGENEOUS TO NANOPARTICLE CATALYSTS -- NANOPARTICLE ACTIVITY IN SUZUKI C-C COUPLING REACTION -- Influence of the Preparation Method on the Catalytic Activity -- Influence of the NP Size on the Catalytic Activity -- Influence of the NP Shape on the Catalytic Activity -- Influence of the Support Material on the Catalytic Activity -- STABILITY AND REUSABILITY OF NANOCATALYSTS -- INSIGHT ON MECHANISTIC ASPECTS -- ACTIVE Pd-NPs AND OTHER METAL NPs FOR SUZUKI C-C COUPLING -- Palladium Nanocatalysts -- Other Metals and Bimetallic Nanocatalysts -- SUMMARY AND FUTURE OUTLOOK -- REPRESENTATIVE EXPERIMENTAL PROCEDURES -- Representative Procedures in Terms of Reusability -- Representative Procedures in Terms of Chloroarene Activation -- Representative Procedure in Terms of Green Synthesis -- REFERENCES.
4 SONOGASHIRA REACTIONS USING NANOCATALYSTS -- INTRODUCTION -- CATALYTIC ACTIVITY, STABILITY, AND REUSABILITY -- Unimmobilized Palladium Nanocatalysts from Palladium Complexes -- Unimmobilized Palladium Nanocatalysts from Ligand-Free Palladium Compounds -- Immobilized Palladium Nanocatalysts -- Other Metal-Based Nanoparticles as Catalysts -- MECHANISTIC ASPECTS -- SUMMARY AND FUTURE OUTLOOK -- REPRESENTATIVE EXPERIMENTAL PROCEDURES -- Sonogashira Reaction Catalyzed by Unimmobilized Pd-NPs from a Ligand-Free Palladium Salt48 -- Sonogashira Reaction Catalyzed by Pd-NPs Immobilized on a Polymer67 -- Sonogashira Reaction Catalyzed by Pd-NPs Immobilized on Carbon88 -- Carbonylative Sonogashira Reaction Catalyzed by Pd-NPs Immobilized on Paramagnetic Nanoparticles112 -- Sonogashira Reaction Catalyzed by Magnetite Nanoparticles124 -- REFERENCES -- 5 NANOCATALYSTS FOR HIYAMA, STILLE, KUMADA, AND NEGISHI C-C COUPLING REACTIONS -- INTRODUCTION -- CATALYTIC NANOPARTICLES FOR C-C CROSS-COUPLINGS -- Synthesis -- Characterization of Catalytic Metal Nanoparticles -- HIYAMA COUPLING -- NEGISHI COUPLING -- STILLE COUPLING -- KUMADA-CORRIU COUPLING -- MECHANISMS -- OUTLOOK -- CONCLUSIONS -- REFERENCES -- 6 ARYL CARBON-HETEROATOM COUPLING REACTIONS USING NANOMETAL CATALYST -- INTRODUCTION -- METAL NANOPARTICLE-CATALYZED ARYL-SULFUR BOND FORMATION -- METAL NANOPARTICLE-CATALYZED ARYL-NITROGEN BOND FORMATION -- METAL NANOPARTICLE-CATALYZED ARYL-OXYGEN BOND FORMATION -- METAL NANOPARTICLE-CATALYZED ARYL-SELENIUM BOND FORMATION -- MISCELLANEOUS C N BOND FORMATION REACTIONS CATALYZED BY METAL NANOPARTICLES -- CONCLUSION -- REFERENCES -- 7 NANOSTRUCTURED CATALYSTS FOR THE ALDOL, KNOEVENAGEL, AND HENRY REACTIONS -- INTRODUCTION -- RECENT PROGRESS ON NANOPARTICLE-BASED HETEROGENEOUS CATALYSTS FOR THE ALDOL, KNOEVENAGEL, AND HENRY REACTIONS.
MESOPOROUS SILICA-SUPPORTED CATALYSTS FOR THE ALDOL, HENRY, AND KNOEVENAGEL REACTIONS -- Henry Reaction -- Asymmetric Henry Reaction -- Aldol Condensation -- Mesoporous Silica-Supported Proline Catalyst for Asymmetric Aldol Condensation -- Knoevenagel Condensation -- POLYMERIC-BASED NANOCATALYSTS FOR THE HENRY COUPLING REACTIONS -- REFERENCES -- 8 NANOCATALYSTS FOR REARRANGEMENT REACTIONS -- INTRODUCTION -- SYNTHESIS AND CHARACTERIZATION OF NANOCATALYSTS -- Synthesis of the Nanocatalysts -- Techniques Employed for the Characterization of the Nanocatalysts -- CATALYTIC ACTIVITY, STABILITY, AND REUSABILITY -- Olefin Isomerization Processes -- Cycloisomerizations and Related Cyclization Processes -- Other Rearrangements -- INSIGHT ON MECHANISTIC ASPECTS -- SUMMARY AND FUTURE OUTLOOK -- REPRESENTATIVE EXPERIMENTAL PROCEDURES -- cis-to-trans-Isomerization of But-2-Ene Catalyzed by Tetrahedral and Cubic Pt-NPs Dispersed onto a High-Surface-Area Silica Xerogel Support30-32 -- Isomerization of Allylbenzenes Catalyzed by RhCl3·3H2O/Aliquat-336 Ion-Pair Encaged within Silica Sol-Gel55 -- Isomerization of Cyclohexene into Methylcyclopentene Catalyzed by Bimetallic Pt-Pd-NPs Supported on TiO2 68 -- Redox Isomerization of Allylic Alcohols Catalyzed by the Nanoferrite-Supported RAPTA Complex 126 -- Intramolecular Cyclization of Alkynoic Acids Catalyzed by Au-NPs Supported on Zeolite β-NH4+83 -- Cycloisomerization of N,N-diallylamides and N,N-Diallylsulfonamides Catalyzed by Pd-NPs93 -- Intramolecular Hydroalkoxylation of Alkenes Catalyzed by Au-NPs Stabilized by PVP94 -- Hydroisomerization of n-Octane Catalyzed by Pt-NPs Dispersed on Mesoporous Al-MCM-48123 -- Beckmann Rearrangement of Ketoximes Using Tungstated Zirconia Solid Acid Nanocatalysts130,131.
Claisen Rearrangement of Allyl Phenyl Ether Using TPA Nanocrystals Encapsulated over a TiO2/SBA-15 Nanocomposite137 -- ACKNOWLEDGMENTS -- REFERENCES -- 9 OXIDATION OF ALCOHOLS USING NANOCATALYSTS -- INTRODUCTION -- RUTHENIUM-CATALYZED ALCOHOL OXIDATION -- Supported RuOx Species -- Supported Perruthenate Species -- Organic Polymer-Supported Ruthenium Catalysts -- PALLADIUM-CATALYZED ALCOHOL OXIDATION -- Supported Pd-NPs -- Supported Pd(II) Species -- Au-CATALYZED ALCOHOL OXIDATION -- Inorganic Material-Supported Au-NPs -- Organic Polymer-Supported Au-NPs -- BIMETALLIC NANOPARTICLE-CATALYZED ALCOHOL OXIDATION -- SUMMARY AND FUTURE OUTLOOK -- REFERENCES -- 10 TUNING THE MORPHOLOGY OF METAL OXIDES FOR CATALYTIC APPLICATIONS -- INTRODUCTION -- COBALT OXIDES -- Co3O4-NPs and Cubes -- Co3O4 Nanorods and Nanotubes -- Multidimensional Co3O4 Nanostructures -- Co3O4 Nanocatalysts -- FERRIC OXIDES -- α-Fe2O3-NPs -- α-Fe2O3 Nanorods and Nanotubes -- Hierarchical α-Fe2O3 -- γ-Fe2O3 Nanomaterials -- Fe2O3 Nanocatalysts -- CERIUM DIOXIDE -- CeO2-NP and Nanocubes -- CeO2 Nanorods and Nanotubes -- Multidimensional CeO2 Nanostructures -- CeO2 Nanocatalysts -- Au/CeO2 Nanocatalysts -- CONCLUDING REMARKS -- REFERENCES -- 11 NANOCATALYSTS FOR HYDROGENATION REACTIONS -- INTRODUCTION -- HYDROGENATION OF VARIOUS UNSATURATED COMPOUNDS -- Hydrogenation of Alkenes -- Hydrogenation of Alkynes -- Hydrogenation of Aromatic Compounds -- CONCLUSIONS -- REFERENCES -- 12 HYDROGENOLYSIS REACTIONS USING NANOCATALYSTS -- NANOCATALYSIS FOR GLYCEROL HYDROGENOLYSIS -- Introduction -- First-Row Transition Metal Catalysts -- Noble Metal Catalysts -- Metal Oxide-Modified Supported Noble Metal Catalysts -- Metal Catalysts Supported on Carbon Nanotubes -- Conclusions and Outlook -- NANOCATALYSIS FOR ALKANE HYDROGENOLYSIS -- Introduction -- Alkane Hydrogenolysis over Transition Metals.
Conclusions and Outlook -- REPRESENTATIVE EXPERIMENTAL DETAILS -- Biodiesel-Derived Glycerol Hydrogenolysis to 1,2-PD on Cu/MgO Catalysts19 -- Hydrogenolysis of Glycerol over Hydrotalcite Cu0.4/Mg5.6Al2O8.6 Catalysts20 -- Hydrogenolysis of Glycerol over Titania-Supported Ruthenium33 -- Hydrogenolysis of Glycerol over Cu-Ru/CNT45 -- Hydrogenolysis of n-Hexane over Titania and Silica-Supported Nickel72 -- REFERENCES -- 13 NANOMATERIAL-BASED PHOTOCATALYSTS -- INTRODUCTION -- HISTORICAL PERSPECTIVES IN PHOTOCATALYSIS -- CURRENT STATE OF PHOTOCATALYSIS (FROM 2000 TO NOW) -- MECHANISTIC DETAILS -- USE OF VISIBLE LIGHT -- SYNTHETIC METHODS -- Sol-Gel -- Hydrothermal Synthesis -- Chemical Vapor Deposition and Atomic Layer Deposition -- Ion Beam Techniques -- FUTURE DIRECTIONS -- CONCLUDING REMARKS -- REFERENCES -- 14 NANOCATALYSTS FOR WATER SPLITTING -- INTRODUCTION -- KNOWLEDGE ON PHOTOCATALYTIC WATER SPLITTING -- Principles of Photocatalytic Water Splitting -- Types of Photocatalytic Water Splitting -- Photocatalytic Performance Evaluation -- General Synthesis Method of Semiconductor Photocatalysts -- Methods of Loading Cocatalyst on Semiconductor Photocatalysts -- ELEMENTS CONSTRUCTING SEMICONDUCTOR PHOTOCATALYSTS -- UV-RESPONSIVE SEMICONDUCTOR NANOCATALYSTS FOR WATER SPLITTING -- Titanium (Ti)-Based Oxides -- Niobium (Nb)-Based Oxides -- Tantalum (Ta)-Based Oxides -- Other Transition Metal-Based Oxides -- Main Group Metal Oxides -- Nonoxide Photocatalysts -- VISIBLE LIGHT-RESPONSIVE SEMICONDUCTOR NANOCATALYSTS FOR WATER SPLITTING -- Semiconductors with Suitable Energy Levels for Water Splitting (Type A) -- Doping Strategies (Type B) -- Solid Solution Materials (Type C) -- SUMMARY AND FUTURE PERSPECTIVE -- REFERENCES -- 15 PROPERTIES OF NANOCATALYTIC MATERIALS FOR HYDROGEN PRODUCTION FROM RENEWABLE RESOURCES -- INTRODUCTION -- BIOMASS GASIFICATION.
Water Gas Shift.
Abstract:
Exhibiting both homogeneous and heterogeneous catalytic properties, nanocatalysts allow for rapid and selective chemical transformations, with the benefits of excellent product yield and ease of catalyst separation and recovery. This book reviews the catalytic performance and the synthesis and characterization of nanocatalysts, examining the current state of the art and pointing the way towards new avenues of research. Moreover, the authors discuss new and emerging applications of nanocatalysts and nanocatalysis, from pharmaceuticals to fine chemicals to renewable energy to biotransformations. Nanocatalysis features contributions from leading research groups around the world. These contributions reflect a thorough review of the current literature as well as the authors' first-hand experience designing and synthesizing nanocatalysts and developing new applications for them. The book's nineteen chapters offer a broad perspective, covering: Nanocatalysis for carbon-carbon and carbon-heteroatom coupling reactions Nanocatalysis for various organic transformations in fine chemical synthesis Nanocatalysis for oxidation, hydrogenation, and other related reactions Nanomaterial-based photocatalysis and biocatalysis Nanocatalysts to produce non-conventional energy such as hydrogen and biofuels Nanocatalysts and nano-biocatalysts in the chemical industry Readers will also learn about the latest spectroscopic and microscopy tools used in advanced characterization methods that shed new light on nanocatalysts and nanocatalysis. Moreover, the authors offer expert advice to help readers develop strategies to improve catalytic performance. Summarizing and reviewing all the most important advances in nanocatalysis over the last two decades, this book explains the many advantages of nanocatalysts over conventional homogeneous and heterogeneous catalysts, providing
the information and guidance needed for designing green, sustainable catalytic processes.
Local Note:
Electronic reproduction. Ann Arbor, Michigan : ProQuest Ebook Central, 2017. Available via World Wide Web. Access may be limited to ProQuest Ebook Central affiliated libraries.
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