Chemical Thermodynamics : Advanced Applications.
Title:
Chemical Thermodynamics : Advanced Applications.
Author:
Ott, J. Bevan.
ISBN:
9780080500997
Personal Author:
Physical Description:
1 online resource (465 pages)
Series:
Chemical Thermodynamics
Contents:
Front Cover -- Chemical Thermodynamics: Advanced Applications -- Copyright Page -- Contents -- Preface to the Two-Volume Series -- Preface to the Second Volume -- Chapter 11. Summary of Thermodynamic Relationships -- 11.1 Thermodynamic Relationships -- 11.2 Phase Equilibria Relationships -- 11.3 Fugacity -- 11.4 Activity and Standard States -- 11.5 Thermodynamics of Mixtures -- 11.6 Chemical Equilibrium -- 11.7 Electrochemical Cells -- 11.8 Calculations from Statistical Thermodynamics -- References -- Chapter 12. Thermodynamics of Other Variables -- 12.1 Effect of Gravitational Fields -- 12.2 Effect of Centrifugal Fields -- 12.3 Thermodynamics of Surfaces -- References -- Chapter 13. Applications of Thermodynamics to Phase Equilibria Studies of Pure Substances -- 13.1 Classification of Phase Transitions in Pure Materials -- 13.2 Modern Theories of Phase Transformations -- References -- Chapter 14. Applications of Thermodynamics to Phase Equilibria Studies of Mixtures -- 14.1 Phase Changes for Mixtures -- 14.2 (Vapor + Liquid) Equilibria -- 14.3 (Liquid + Liquid) Equilibrium -- 14.4 (Fluid + Fluid) Equilibrium -- 14.5 (Solid + Liquid) Phase Equilibrium -- References -- Chapter 15. Applications of Thermodynamics to Chemical Processes -- 15.1 The Haber Cycle: Application to an Industrial Process -- 15.2 The Synthesis of Diamond: Application to Phase Changes -- 15.3 Applications of Thermodynamics to Geological Systems -- 15.4 Thermodynamics of Complexation with Macrocyclic Ligands -- References -- Chapter 16. Applications of Thermodynamics to Biological Processes -- 16.1 Metabolism and Work -- 16.2 Biopolymer Stabilities -- References -- Chapter 17. Applications of Thermodynamics to Nonelectrolyte Solutions -- 17.1 Excess Thermodynamic Properties -- 17.2 The Excess Thermodynamic Properties and (Liquid + Liquid) Phase Equilibrium.
17.3 The Excess Thermodynamic Properties and (Fluid + Fluid) Phase Equilibrium -- References -- Chapter 18. Applications of Thermodynamics to Solutions Containing Electrolyte Solutes -- 18.1 Electrolyte Solutions -- 18.2 Ion Association -- 18.3 Surfactant Solutions -- References -- APPENDIX 5. Thermodynamic Properties of Selected Chemical Substances -- Table A5.1 Thermodynamic Functions -- Table A5.2 Standard Heat Capacities, Entropies, Enthalpies, and Gibbs Free Energies of Formation of Selected Substances at T = 298.15 K -- Table A5.3 Standard Heat Capacities, Entropies, Enthalpies, and Gibbs Free Energies of Formation of Some Common Ions at T = 298.15 K -- Table A5.4 Enthalpies and Temperatures of Fusion and Vaporization -- Table A5.5 Coefficients at P = 0.1 MPa for the Heat Capacity Equation -- Table A5.6 Standard Reduction Potentials at T = 298.15 K -- APPENDIX 6. Calculations from Statistical Thermodynamics -- A6.1 Atomic and Molecular Energy Levels -- A6.2 The Partition Function -- A6.3 Relationship Between the Partition Function and the Thermodynamic Functions for the Ideal Gas -- A6.4 Partition Functions for the Ideal Gas -- A6.5 Calculation of the Thermodynamic Properties from the Energy Levels -- Table A6.1 Thermodynamic Functions of an Ideal Gas -- Table A6.2 Moments of Inertia and Rotational Constants of Some Common Molecules -- Table A6.3 Fundamental Vibrational Frequencies of some Common Molecules -- Table A6.4 Electronic Energy Levels of Some Common Molecules or Atoms with Unpaired Electrons -- Table A6.5 Anharmonic Oscillator and Nonrigid Rotator Corrections -- Table A6.6 Contributions to the Thermodynamic Properties Due to Internal Rotation -- Table A6.7 The Debye Thermodynamic Functions Expressed in Terms of θD/T -- APPENDIX 7. Coefficients for Pitzer's Equations.
Table A7.1 Debye-Hükel Parameters for the Osmotic Coefficient, Volume, Enthalpy, and Heat Capacity -- Table A7.2 Pitzer Coefficients for 1:1 Electrolytes -- Table A7.3 Pitzer Coefficients for 2:1 Electrolytes -- Table A7.4 Pitzer Coefficients for 3:1 Electrolytes -- Table A7.5 Pitzer Coefficients for 4:1 and 5:1 Electrolytes -- Table A7.6 Pitzer Coefficients for 2:2 Electrolytes -- Table A7.7 Temperature Derivatives of Pitzer Coefficients for 1:1 Electrolytes -- Table A7.8 Temperature Derivatives of Pitzer Coefficients for 2:1 and 1:2 Electrolytes -- Table A7.9 Temperature Derivatives of Pitzer Coefficients for 3:1, 2:2, 3:2, and 4:2 Electrolytes -- Table A7.10 Volumetric Properties and the Pressure Derivatives of Pitzer Coefficients for Salts.
Abstract:
This book is an excellent companion to Chemical Thermodynamics: Principles and Applications. Together they make a complete reference set for the practicing scientist. This volume extends the range of topics and applications to ones that are not usually covered in a beginning thermodynamics text. In a sense, the book covers a "middle ground" between the basic principles developed in a beginning thermodynamics textbook, and the very specialized applications that are a part of an ongoing research project. As such, it could prove invaluable to the practicing scientist who needs to apply thermodynamic relationships to aid in the understanding of the chemical process under consideration. The writing style in this volume remains informal, but more technical than in Principles and Applications. It starts with Chapter 11, which summarizes the thermodynamic relationships developed in this earlier volume. For those who want or need more detail, references are given to the sections in Principles and Applications where one could go to learn more about the development, limitations, and conditions where these equations apply. This is the only place where Advanced Applications ties back to the previous volume. Chapter 11 can serve as a review of the fundamental thermodynamic equations that are necessary for the more sophisticated applications described in the remainder of this book. This may be all that is necessary for the practicing scientist who has been away from the field for some time and needs some review. The remainder of this book applies thermodynamics to the description of a variety of problems. The topics covered are those that are probably of the most fundamental and broadest interest. Throughout the book, examples of "real" systems are used as much as possible. This is in contrast to many books where "generic" examples are used almost exclusively.
A complete set of references to all sources of data and to supplementary reading sources is included. Problems are given at the end of each chapter. This makes the book ideally suited for use as a textbook in an advanced topics course in chemical thermodynamics. Key Features * An excellent review of thermodynamic principles and mathematical relationships along with references to the relevant sections in Principles and Applications where these equations are developed * Applications of thermodynamics in a wide variety of chemical processes, including phase equilibria, chemical equilibrium, properties of mixtures, and surface chemistry * Case-study approach to demonstrate the application of thermodynamics to biochemical, geochemical, and industrial processes * Applications at the "cutting edge" of thermodynamics * Examples and problems to assist in learning * Includes a complete set of references to all literature sources.
Local Note:
Electronic reproduction. Ann Arbor, Michigan : ProQuest Ebook Central, 2017. Available via World Wide Web. Access may be limited to ProQuest Ebook Central affiliated libraries.
Genre:
Added Author:
Electronic Access:
Click to View