COORDINATION POLYMERS AND METAL ORGANIC FRAMEWORKS: PROPERTIES, TYPES AND APPLICATIONS -- CHEMICAL ENGINEERING METHODS AND TECHNOLOGY -- MATERIALS SCIENCE AND TECHNOLOGIES -- COORDINATION POLYMERS AND METAL ORGANIC FRAMEWORKS: PROPERTIES, TYPES AND APPLICATIONS -- Library of Congress Cataloging-in-Publication Data -- CONTENTS -- PREFACE -- CHAPTER 1. HYBRID VANADATES, TOWARDS METAL-ORGANIC FRAMEWORKS -- ABSTRACT -- 1. INTRODUCTION -- 2. VANADIUM OXIDE CRYSTAL CHEMISTRY -- 2.1. Coordination Environment of Vanadium -- 2.2. Vanadium Oxide (VxOy) Subunits -- 3. HYDROTHERMAL SYNTHESIS OF HYBRID VANADATES -- 3.1. High-Throughput (HT) Methods: Compositional Space Diagrams -- 3.1.1. Ni/4Bpy/ VxOy System (4Bpy = 4,4-́Bipyridine) -- 3.1.2. Ni/Bpe/VxOy System Bpe = 1,2 Di(4-Pyridyl)Ethylene -- 3.1.3. Ni/Bpa/VxOy System Bpa = 1,2-Di(4-Pyridyl)Ethane -- 4. STRUCTURAL ARQUETYPES: FROM ZEOTYPES TO MOFS -- 4.1. A Architectures: Hybrid Vanadates Archetypes Containing Three-Dimensional Inorganic Scaffolds -- 4.2. B Architectures: Hybrid Vanadates Archetypes ContainingTwo-Dimensional Inorganic Layers -- 4.3. C Architectures: Hybrid Vanadates Archetypes Containing One-Dimensional Inorganic Chains -- 4.4. D Architectures: Hybrid Vanadates Archetypes Containing Discrete Inorganic Units -- 5. PHYSICOCHEMICAL PROPERTIES OF HYBRIDVANADIUM OXIDES -- 5.1. Thermal Response of the Crystal Structure to the Loss of Crystallization and Coordinated Water Molecules -- 5.1.1. Rigid A1 Crystal Architectures Containing Crystallization and Coordinated Water Molecules: [{Ni6(H2O)10(4Bpy)6}(V18O51)]·1.5H2O and [{Ni(H2O)2(Bpe)} (V4O11)]·0.5H2O -- 5.1.2. Flexible A3 Crystal Architectures: The Effect of the Rigidity-Flexibility of the Organic Ligand, [{Ni8(4Bpy)16}(V24O68)]·8.5H2O and {Ni3(H2O)3(Bpa)4}(V6O18)]·8H2O.

5.1.3. B2 Crystal Architectures: The Reorganization of Layered-Like Hybrid Vanadates due to the Loss of Crystallization and Coordinated Water Molecules:[{Mn(4Bpy)}(VO3)2]·1.16H2O, [{Mn(4Bpy)}0.5(VO3)2]·0.62H2O, {Ni2(H2O)2(Pz)}(V4O12) -- 5.1.4. Negative Thermal Expansion in {Ni(Bpe)}(VO3)2 -- 5.2. Magnetic Properties -- 5.3. Catalytic and Photocatalytic Activity of Hybrid Vanadates -- CONCLUSION -- ACKNOWLEDGMENTS -- REFERENCES -- CHAPTER 2. STRUCTURE AND MAGNETIC PROPERTIES OF MONO-AND POLYNUCLEAR COMPLEXES CONTAINING RHENIUM(IV) -- ABSTRACT -- INTRODUCTION -- RHENIUM(IV) -- SYNTHESIS AND STRUCTURE OF HEXAHALORHENATES -- MAGNETIC PROPERTIES OF HEXAHALORHENATE SALTS -- Hexahalorhenate(IV) Salts of Diamagnetic Cations with MagneticallyIsolated Anions -- Hexahalorhenate(IV) Salts of Diamagnetic Cations with Significant MagneticInteraction between Anions -- Hexahalorhenate(IV) Salts of Paramagnetic Cations without SignificantMagnetic Interactions between Oppositely Charged Ions -- Hexahalorhenate(IV) Salts of Paramagnetic Cations with Magnetic Interactions between Oppositely Charged Ions -- OTHER RHENIUM(IV) MONONUCLEAR COMPLEXES -- POLYNUCLEAR RHENIUM(IV) COMPLEXES -- Dinuclear Re(IV)-M(II) Complexes -- Discrete-Size Heterometallic Clusters -- Magnetic Chains -- CONCLUSION -- ACKNOWLEDGEMENT -- REFERENCES -- CHAPTER 3. THE APPLICATIONS OF METAL ORGANIC FRAMEWORKKS IN THE FIELDS OF HYDROGEN STORAGE AND CATALYSIS -- ABSTRACT -- 1. INTRODUCTION -- 2. MOFS USED AS HYDROGEN STORAGE MATERIALS -- 2.1. [M(Pyz) { Ni(CN)4 }] (M =Fe, Co, Ni) -- 2.2. Prussian Blue Analogues -- 2.3. (M(HBTC)(4,4'-Bipy).3DMF(M = Ni and Co) -- 2.4. Ni2(BTEC)(Bipy)3·3DMF·2H2O and Ni2(BDC)2(Dabco)·4DMF·1.5H2O -- 3. MOFS USED AS CATALYST PRECURSORS -- 3.1. MOF-Based Catalyst Used in the NH3BH3 Hydrolysis System -- 3.2. MOF-Based Catalyst Used in the NH3BH3Thermal Decomposition System.

CONCLUSION -- REFERENCES -- CHAPTER 4. MOF-BASED MIXED-MATRIX-MEMBRANES FOR INDUSTRIAL APPLICATIONS -- ABSTRACT -- 1. INTRODUCTION -- 2. MIXED-MATRIX-MEMBRANES -- 3. MOF-BASED MEMBRANES -- 4. MOF-5 OR IRMOF-1BASEDMIXED-MATRIX-MEMBRANES -- 5. CU(HFIPBB)(H2HFIPBB)0.5BASED MIXED-MATRIX-MEMBRANES -- 6. ZN(BDC)(TED)0.5BASED MIXED-MATRIX-MEMBRANES -- 7. CU3(BTC)2OR HKUST-1BASED MIXED-MATRIX-MEMBRANES -- 8. CU-BPY-HFSBASED MIXED-MATRIX-MEMBRANES -- 9. MOP-18BASED MIXED-MATRIX-MEMBRANES -- 10. ZIF-8BASED MIXED-MATRIX-MEMBRANES -- 11. V-MIL-47 AND AL-MIL-53 BASED MIXED-MATRIX-MEMBRANES -- 12. ZIF-90BASED MIXED-MATRIX-MEMBRANES -- 13. SUMMARY AND FUTURE OPPORTUNITIES -- BIBLIOGRAPHY -- CHAPTER 5. COORDINATION POLYMERS: OPPORTUNITIES IN HETEROGENEOUS CATALYSIS -- ABSTRACT -- 1. INTRODUCTION -- 1.1. Why Do We Want to Use CPs in Heterogeneous Catalysis? -- 1.2. Bridging the Gap between Homogeneousand Heterogeneous Catalysis with CPs -- 2. SYNTHESIS OF CPS -- 2.1. Synthesis Methods -- 2.2. Systematic Design of Pore Size -- 2.3. Structure Directing Effects -- 3. DESIGNING CPS FOR CATALYTIC APPLICATIONS -- 3.1. Catalysis at the Metallic Site -- 3.1.1. As-Synthesized Active CPs -- 3.1.2. CPs Containing Metal Nodes with Semiconducting Properties -- 3.1.3. CPs with Coordinatively Unsaturated Metal Sites -- 3.1.4. Anchoring of Catalytic Active Species to the Metal Nodes -- 3.2. Catalysis at the Organic Linker -- 3.2.1. CPs with Organic Functional Groups -- 3.2.2. CPs Containing Metal Coordination Complexes as Building Blocks -- 3.2.3. CPs with Chelating Linkers -- 3.3. CPs as Host Matrices or Nanometric Reaction Cavities -- 3.3.1. Encapsulated Metal Nanoparticles -- 3.3.2. Encapsulated Metal Oxide Nanoparticles -- 3.3.3. Encapsulated Catalytic Active Molecular Species -- 3.3.4. CPs as Nanometric Reaction Cavities -- 3.4. Post-Synthesis Modification of CPs -- CONCLUSION.

REFERENCES -- CHAPTER 6. HIGH PRESSURE GAS STORAGE ON POROUS SOLIDS: A COMPARATIVE STUDY OF MOFs AND ACTIVATED CARBONS -- ABSTRACT -- INTRODUCTION -- ADSORPTION CAPACITY AND GAS STORAGECAPACITY CORRELATIONS -- MATERIAL AND METHODS -- Samples Used -- Sample Characterization -- Gas Storage Experiments -- RESULTS AND DISCUSSION OF SAMPLE CHARACTERIZATION -- HYDROGEN ADSORPTION AT 77 K -- At Sub-Atmospheric Pressures (< 0.1MPa) -- At Moderate Pressures (< 4MPa) -- At Moderate Pressures (< 4MPa) Using Different Packing Densities -- Gas Adsorption at Room Temperature -- Hydrogen at High Pressures (< 20MPa) -- Methane at Moderate Pressures (< 4MPa) -- Carbon Dioxide at Moderate Pressures (< 4MPa) -- FINAL REMARKS -- Volumetric Gas Storage Comparison with Best MOFs -- Samples Stability -- CONCLUSIONS -- ACKNOWLEDGEMENTS -- REFERENCES -- CHAPTER 7. METAL-ORGANIC FRAMEWORKS FOR CO2 CAPTURE: WHAT ARE LEARNED FROM MOLECULAR SIMULATIONS -- ABSTRACT -- 1. INTRODUCTION -- 2. SIMULATION METHODS -- 3. MOF SORBENTS FOR CO2 CAPTURE -- 3.1. Catenated MOFs -- 3.2. Functionalized MOFs -- 3.3. Metal-Exposed MOFs -- 3.4. Ionic MOFs -- 3.5. Metal-Doped MOFs -- 4. MOF MEMBRANES FOR CO2 CAPTURE -- 5. EFFECTS OF H2O ON CO2 CAPTURE -- CONCLUSION AND OUTLOOK -- ACKNOWLEDGMENTS -- REFERENCES -- CHAPTER 8. HALOGEN BONDING IN THE ASSEMBLY OF HIGH-DIMENSIONAL SUPRAMOLECULAR COORDINATION POLYMERS -- ABSTRACT -- INTRODUCTION -- 1. HALOGEN-RELATED INTERACTIONS -- 1.1. Halogen···N (Or O, S) Halogen Bonding -- 1.2. Halogen·Halogen Interactions -- 1.3. Halogen···p Interactions -- 2. HALOGEN RELATED INTERACTIONSIN METAL-ORGANIC NETWORKS -- 2.1. Halogen Molecules or Anions Systems -- 2.2. Metal-Halide and Metal-Pseudohalide Systems -- 2.3. Metal-Tetrathiafulvalenium (TTF) Systems -- 2.4. Silver-Ethynide Systems -- 2.5. Metal-Porphyrin Systems -- 2.6. Cu2(3-Iodobenzoate)4 Systems.

2.7. Metal-5-iipa Systems -- CONCLUSION AND OUTLOOK -- ACKNOWLEDGMENTS -- REFERENCES -- CHAPTER 9. SUBRACTIVE APPROACH FOR INTRODUCING FUNCTIONAL GROUPS ONTO METAL-ORGANIC FRAMEWORK -- 1. INTRODUCTION -- 2. RESULTS AND DISCUSSIONS -- Synthesis and Structure of [Zn4O(Dacobdc)3] -- Syntheses and Crystal Structures of [Zn(Dhybdc)(Bpy)]·4DMF and [Cd(Dhybdc)(Bpy)] -- Spectroscopic Analyses -- Elucidation of Deprotection Condition -- 3. SUMMARY -- 4. EXPERIMENTAL -- Preparation of 2,5-Diacetoxyterephthalic Acid (H2dacobdc) -- Preparation of 2,5-Bis(Pivaloyloxy)Terephthalic Acid (H2dpivobdc) -- Preparation of [Zn(Dhybdc)(Bpy)]·4DMF -- Preparation of [Cd(Dhybdc)(Bpy)] -- Preparation of [Zn4O(Dacobdc)3] -- Evaluation of Deprotection Condition -- REFERENCES -- CHAPTER 10. PERFORMANCE OF METAL-ORGANIC FRAMEWORK MIL-101 IN THE LIQUID PHASE ADSORPTION OF HETEROCYCLIC NITROGEN COMPOUNDS -- ABSTRACT -- EXPERIMENTAL DETAILS -- REFERENCES -- INDEX.