HETEROGENEOUS CATALYSIS RESEARCH PROGRESS -- NOTICE TO THE READER -- CONTENTS -- PREFACE -- APPLICATION OF PEROVSKITES FOR AUTOMOBILE EXHAUST PURIFICATION -- ABSTRACT -- 1. BASIC CONCEPT OF PEROVSKITES -- 2. PEROVSKITE SYNTHESIS -- 2.1. Methods -- 2.2. Physical Properties -- 3. OXYGEN NONSTOICHIOMETRY -- 3.1. O2-TPD Study -- 3.2. H2-TPR Study -- 3.3. XPS study -- 3.4. Isotopic Exchange Experiments -- 3.5. Redox Properties -- 4. NO REDUCTION BY HCS IN THE PRESENCE OF OXYGEN OVER PEROVSKITES -- 4.1. Adsorption of Reactant Molecules -- 4.2. Catalytic Performance -- 4.3. Reaction Mechanism -- 5. NO CATALYTIC REDUCTION BY CO OVER PEROVSKITES -- 5.1. Adsorption of Reactant Molecules -- 5.2. Catalytic Performance -- 5.3. Reaction Mechanism -- VOCS COMBUSTION OVER PEROVSKITES -- 7. DEACTIVATION OF DENOX PEROVSKITE CATALYSTS BY WATER VAPOR -- 7.1. Effect of Steam on Reactants Adsorption over LaFe0.8Cu0.2O3 -- 7.2. Catalytic Performance -- 8. SULFUR DIOXIDE POISONING OF PEROVSKITES -- 8.1. SO2 Poisoning During C3H6 + NO + O2 Reaction -- 8.2. Resistance of LaCo1-xFexO3 To SO2 Poisoning During Methane Oxidation -- 9. LEAN NO REDUCTION OVER THE PEROVSKITE-AG/ALUMINA COMBINED CATALYSTS -- 9.1. Relationship between Redox Properties and Catalytic Behavior of Ag-Containing Perovskite and Alumina -- 9.2. Synergistic Effect of Perovskite and Alumina -- 10. RECENT ADVANCES ON NO REDUCTION RELATED TO MIXED OXIDES, SUPPORTED METALS AND ION-EXCHANGE MESOPOROUS MATERIALS -- 10.1. Ga-Based Mixed Perovskites -- 10. 2. Alumina Supported Silver Catalysts -- 10.3. Cu-MCM-41 -- 11. CONCLUSIONS -- REFERENCES -- NEW SYNTHETIC METHODS TO EFFICIENT NANOPOROUS AND NANOSTRUCTURED CATALYSTS: SELF-ASSEMBLY AND CO-ASSEMBLY OF MULTIPLE SITE-ISOLATED CATALYTIC SITES ON MESOPOROUS MATERIALS -- ABSTRACT -- 1. INTRODUCTION -- 1.1. Mesoporous Silica -- 1.2. Mesoporous SBA-15.

2. ORGANIC FUNCTIONALIZED MESOPOROUS MATERIALS AND SITE-ISOLATION OF FUNCTIONAL GROUPS -- 2.1. Molecular Imprinting -- 2.3. Spacer-Mediated Site-Isolation -- 2.4. Solvent Assisted Site-Isolated Grafting (SASIG) -- 3. NANOPARTICLES SUPPORTED IN MESOPOROUS MATERIALS AS HETEROGENEOUS CATALYSTS -- 3.1. Introduction -- 3.2. Enhanced Catalytic Activity of Nanoparticles Supported on Mesoporous Materials -- 3.3. Methods toward Synthesizing Nanoparticle/Mesoporous Materials Composites -- 4. MESOPOROUS MATERIALS SUPPORTED ORGANOMETALLIC CATALYSTS -- 4.1. Introduction -- 4.2. Mesoporous Silica Supported Organometallic Catalysts by Co-Condensation -- 4.3. Mesoporous Silica Supported Organometallic Catalysts by Grafting -- 5. CONCLUSION AND FUTURE OUTLOOKS -- ACKNOWLEDGMENTS -- REFERENCES -- COBALT(III)-SUPPORTED CHEMICALLY MODIFIED MESOPOROUS SILICAS AS HETEROGENEOUS OXIDATION CATALYSTS -- ABSTRACT -- 1. INTRODUCTION -- 2. HYBRID INORGANIC-ORGANIC MESOPOROUS SILICATES -- 3. SILICA-SUPPORTED COBALT(III) CATALYSTS -- 4. PREPARATION OF COBALT(III)-BASED CATALYSTS -- 4.1. Preparation of CMS-CH2CH2CO2H -- 4.2. Synthesis and Characterization of Oxo-Cobalt(III) Carboxylate Clusters -- 4.3. Immobilization of Co(III) Species on CMS -- 5. CHARACTERIZATION OF CATALYSTS -- 5.1. N2 Adsorption Studies -- 5.2. Vibrational Spectroscopy -- 5.3. Electronic Spectroscopy -- 5.4. Scanning Electron Microscopy -- 6. CATALYTIC USE OF CO(III)-CMS MATERIALS -- 6.1. Oxidation of Ethylbenzene -- 6.2. Oxidation of α-Pinene -- 6.3. Oxidation of Alcohols -- CONCLUSION -- REFERENCES -- SELECTIVE ALKYLATION OF AROMATIC SUBSTRATES ON SPINELS -- ABSTRACT -- 1. INTRODUCTION -- 2. SPINELS -- 2.1. Structural Aspects of Spinels -- 2.2. Catalytic Activity of Spinels -- 3. ALKYLATION OF AROMATIC SUBSTRATES -- 3.1. Phenol Alkylation -- 3.2. Phenol Alkylation with Bulky Alkyl Groups.

3.3. Alkylation of M-Cresol to Thymol -- 3. 4. N-Methylationof Aniline -- 3.4a Active Spacer and Stabilizer Role of Zn in Cu1-Xznxfe2o4 -- 3.4b Surface Acidity -- 3.4c Aniline N-Methylation Mechanism on Cu1-Xznxfe2o4 -- 4. ALKYLATION OF HETEROCYLCES -- 5. CONCLUSION -- ACKNOWLEDGMENTS -- REFERENCES -- HETEROGENEOUS FENTON CATALYSIS FOR THE DEGRADATION OF AZO TEXTILE DYES -- ABSTRACT -- INTRODUCTION -- HOMOGENOUS CATALYSIS -- Hydroxyl Radical Hypotheses -- Ferryl Ion and Hydroxyl Radical Hypotheses -- Ferryl Ion and Binuclear Species Intermediates Hypotheses -- Catalytic Activation of Hydrogen Peroxide -- Organic Degradation by Fentonś Reagent -- HETEROGENEOUS CATALYSIS -- Fly Ash -- Iron Oxide Supported on Cerium Oxides -- CONCLUSIONS -- REFERENCES -- REFLECTIONS ON APPLIED CATALYSIS AND FUNDAMENTAL MODEL STUDIES -- ABSTRACT -- 1. INTRODUCTION -- 2. STUDIES ON FUNCTIONALITY-ORIENTED APPLIED CATALYSIS -- 2.1. Catalytic Decomposition of Freon-12 on Solid Acids -- 2.2. Designing Novel Tio2-Based Gold Catalysts with Improved Performance -- 2.3. Designing Novel Carbon-Based Gold Catalysts with Improved Performance -- 3. STUDIES ON CATALYTIC INSIGHT-DRIVEN MODEL STUDIES -- 3.1. Influence of Residual H2O2 on the Reaction Testing of Phenol Hydroxylation -- 3.2. Decarbonylation of Organic Molecules on Platinum Surface -- 3.3. Solvent Effect on the Desorption of Chiral Modifier Used in Chiral Hydrogenation -- 4. DISCUSSION AND PERSPECTIVE -- 5. FURTHER READING -- 5.1. Our Reviews on Heterogeneous Catalysis -- 5.2. Our Reviews on Surface Chemistry of Catalysis Relevance -- 5.2. Our Reviews on Surface Chemistry of Catalysis Relevance -- 6. CONCLUSION -- ACKNOWLEDGMENTS -- REFERENCES -- SUPPORTED POLYOXOMETALATE-BASED HETEROGENEOUS CATALYSIS FOR LIQUID PHASE SELECTIVE OXIDATIONS -- ABSTRACT -- 1. INTRODUCTION -- 2. CHEMICAL BINDING OF POMS TO SUPPORTS.

2.1. Electrostatic Attachment -- 2.2. Dative Binding -- 2.3. Covalent Binding -- 3. COMPOSITE POM MATERIALS -- 4. CONCLUSION -- ACKNOWLEDGMENTS -- REFERENCES -- NEW APPROACHES FOR REUSABLE CHIRAL HETEROGENEOUS CATALYSTS FOR EPOXIDE RING OPENING REACTION -- ABSTRACT -- INTRODUCTION -- Kinetic Resolution of Racemic Epoxides -- Hydro Kinetic Resolution (HKR) of Racemic Epoxides -- ARO of Epoxides with Phenols and Alcohols as Nucleophiles -- ASYMMETRIC RING OPENING REACTION OF EPOXIDES WITH TRIMETHYLSILYL AZIDE (TMSN3) -- AMINOLYTIC KINETIC RESOLUTION OF RACEMIC EPOXIDES WITH AMINES AS NUCLEOPHILE -- CONCLUSION AND OUT LOOK -- ACKNOWLEDGEMENTS -- REFERENCES -- LEAD-RUTHENATE PYROCHLORE MODIFIED NAFION® MEMBRANE FOR TUNABLE HETEROGENEOUS CATALYTIC OXIDATION REACTIONS -- ABSTRACT -- 1. INTRODUCTION -- 2. PREPARATION OF

Peptide Synthesis in Flow Mode -- Synthesis of Oxazole Derivates -- CROSS-COUPLING REACTIONS -- Kumada Reaction -- Suzuki-Miyaura Reaction -- Knoevenagel Condensation -- MICHAEL ADDITION -- PROTECTION OF KETONES AND ALDEHYDES -- ENANTIOSELECTIVE REACTIONS -- Enantioselective Synthesis of Grossamide -- Enantioselective Glyoxylate-Ene Reaction -- HETEROGENEOUS CATALYSIS UNDER SUPERCRITICAL FLOW CONDITIONS -- HYDROGENATION UNDER SUPERCRITICAL FLOW CONDITIONS -- HYDROFORMYLATION UNDER SUPERCRITICAL FLOW CONDITIONS -- ENZYMATIC REACTIONS IN SUPERCRITICAL FLOW MODE -- MICROWAVE ASSISTED SYNTHESISUNDER CONTINUOUS-FLOW CONDITIONS -- CROSS-COUPLING REACTIONS IN MICROWAVE-FLOW MODE -- OXIDATION REACTIONS UNDER MICROWAVE-FLOW CONDITIONS -- BATCH VERSUS FLOW CONDITIONS -- CONCLUSION -- REFERENCES -- INDEX.