Cover image for Fundamentals of Conjugated Polymer Blends, Copolymers and Composites : Synthesis, Properties, and Applications.
Fundamentals of Conjugated Polymer Blends, Copolymers and Composites : Synthesis, Properties, and Applications.
Title:
Fundamentals of Conjugated Polymer Blends, Copolymers and Composites : Synthesis, Properties, and Applications.
Author:
Saini, Parveen.
ISBN:
9781119137115
Personal Author:
Edition:
1st ed.
Physical Description:
1 online resource (802 pages)
Contents:
Cover -- Title Page -- Copyright Page -- Contents -- Foreword -- Preface -- Part 1: Multiphase Systems: Synthesis, Properties and Applications -- 1 Conjugated Polymer-based Blends, Copolymers, and Composites: Synthesis, Properties, and Applications -- 1.1 Introduction -- 1.2 CPs/ICPs-Based Blends -- 1.2.1 Classification of CPs/ICPs-Based Blends -- 1.3 CPs/ICPs-Based Copolymers (CCPs) -- 1.3.1 Types of CPs/ICPs-Based Copolymers -- 1.3.2 Sub-Classification of Linear or Graft BCPs -- 1.4 CPs/ICPs-Based Composites/Nanocomposites/Hybrids -- 1.4.1 Categorization of CPs/ICPs-Based NCs -- 1.5 Interpenetrating/Semi-Interpenetrating Polymer Network (IPN/SIPN) -- 1.6 Synthesis of CPs/ICPs-Based BLNs, CCPs, and CMPs/NCs/HYBs -- 1.6.1 Synthesis of Undoped CPs-Based BLNs -- 1.6.2 Synthesis of Conjugated Polymers-Based Copolymers -- 1.6.3 CPs/ICPs-Based CMPs/NCs -- 1.7 Applications of CPs/ICPs-Based BLNs, CCPs, and CMPs/NCS/HYBs -- 1.7.1 ICP-Based Systems -- 1.7.2 CPs-Based Systems -- 1.8 Conclusions -- Acknowledgments -- References -- 2 Progress in Polyaniline Composites with Transition Metal Oxides -- 2.1 Introduction -- 2.2 PANI/Transition Metal Oxide Composites -- 2.2.1 PANI Composites with Oxides of the Copper Group of Transition Metals -- 2.2.2 PANI Composites with Oxides of the Zinc Group of Transition Metals -- 2.2.3 PANI Composites with Oxides of the Scandium Group of Transition Metals -- 2.2.4 PANI Composites with Oxides of the Titanium Group of Transition Metals -- 2.2.5 PANI Composites with Oxides of the Vanadium Group of Transition Metals -- 2.2.6 PANI Composites with Oxides of the Chromium Group of Transition Metals -- 2.2.7 PANI Composites with Oxides of the Manganese Group of Transition Metals -- 2.2.8 PANI Composites with Oxides of Iron, Cobalt, and Nickel Groups of Transition Metals -- 2.3 Conclusions and Outlook -- Abbreviations -- References.

3 Conjugated-Polymer/Quantum-Confined Nanomaterials- Based Hybrids for Optoelectronic Applications -- 3.1 Introduction -- 3.2 Quantum-Confined Nanomaterials (QCNs) -- 3.2.1 Inorganic Quantum-Confined Nanomaterials (QCNs) -- 3.2.2 Organic Quantum-Confined Nanomaterials (QCNs) -- 3.3 Synthetic Approaches for Quantum-Confined Nanomaterials (QCNs) -- 3.3.1 Synthesis of Inorganic Quantum-Confined Nanomaterials -- 3.3.2 Synthesis of Organic Quantum-Confined Nanomaterials -- 3.3.3 Optical Properties -- 3.4 Conjugated-Polymer/Quantum-Confined Nanomaterials (CP/QCN) Hybrids -- 3.4.1 Methodologies for Making Conjugated-Polymer/ Inorganic QCN Hybrids -- 3.4.2 Chemical Methods -- 3.5 Optoelectronic Applications of Hybrids -- 3.5.1 Hybrid Solar Cell -- 3.5.2 Light-Emitting Diodes -- 3.5.3 GQDs/Conjugated-Polymer-Based Counter Electrode for Dye-Sensitized Solar Cells -- 3.6 Outlook and Perspective: Current Challenges and FutureScope/Prospects -- Acknowledgments -- References -- 4 Graphene/Conjugated Polymer Nanocomposites for Optoelectronic and Biological Applications -- 4.1 Introduction -- 4.2 Graphene/Conjugated Polymer Nanocomposites -- 4.2.1 Preparation of Graphene/Conjugated Polymer Nanocomposites -- 4.2.2 Different Types of Conjugated Polymer Nanocomposites and Their Properties -- 4.2.3 Characterizations of Graphene/Conjugated Polymer Nanocomposites -- 4.3 Applications of Graphene/Conjugated Polymer Nanocomposites -- 4.3.1 Optoelectronic Application -- 4.3.2 Biological Applications -- 4.4 Conclusions and Future Scope -- Acknowledgements -- References -- Part 2: Energy Harvesting and Storage Materials -- 5 Conjugated Polymers-Based Blends, Composites and Copolymers for Photovoltaics -- 5.1 Introduction -- 5.2 Organic Photovoltaic (OPV) Cells -- 5.3 OPV Device Architecture and Working Mechanism -- 5.4 Solar Cell Terminologies and Characterization Parameters.

5.4.1 Air Mass (AM) -- 5.4.2 Open-Circuit Voltage (Voc) -- 5.4.3 Short Circuit Current Density (Jsc) -- 5.4.4 Fill Factor (FF) -- 5.4.5 Power Conversion Efficiency (PCE) (ƞ) -- 5.4.6 Quantum Efficiency (QE) -- 5.5 CPs-Based Blends, Composites and Copolymers for OPVs -- 5.5.1 Polymer-Fullerene BHJ Blends -- 5.5.2 Organic-Inorganic Composites/Hybrids -- 5.5.3 Polymer/Carbon Nanotube Composites -- 5.5.4 Polymer/Graphene-Based Composites -- 5.6 Conjugated Copolymers for PVs -- 5.6.1 Donor-Acceptor Type Alternating Copolymers -- 5.6.2 Block Copolymers with Built in p-Type Donor and n-Type Acceptor -- 5.7 Conclusions: Current Challenges and Prospects -- Acknowledgements -- References -- 6 Conducting Polymer-Based Nanocomposites for Thermoelectric Applications -- 6.1 Introduction -- 6.2 Synthesis Methods -- 6.2.1 In Situ Polymerization -- 6.2.2 Solution Mixing -- 6.2.3 Mechanical Mixing -- 6.3 TE Properties of CP/Inorganic Nanocomposites -- 6.3.1 CP/CNT Composite -- 6.3.2 CP/Graphene Composites -- 6.3.3 CP/Metal Composites -- 6.3.4 CP/Metal Compounds Composites -- 6.4 Summary -- References -- 7 Conjugated-Polymer/Inorganic Nanocomposites as Electrode Materials for Li-Ion Batteries -- 7.1 Introduction -- 7.2 Nanocomposites of Conjugated Polymer/ Inorganic as Cathode Materials -- 7.2.1 LiFePO4 -- 7.2.2 MnO2 -- 7.2.3 V2O5 -- 7.3 Nanocomposites of Conjugated Polymers/ Inorganic as Anode Materials -- 7.3.1 Silicon -- 7.3.2 SnO2 -- 7.3.3 Other Conjugated Polymer-Based Anode Materials -- 7.4 Conclusion -- Acknowledgments -- References -- 8 Polypyrrole/Inorganic Nanocomposites for Supercapacitors -- 8.1 Introduction -- 8.2 Polypyrrole/Carbon Nanocomposites -- 8.2.1 Carbon Nanoparticles -- 8.2.2 Carbon Nanofibers -- 8.2.3 Carbon Nanotubes -- 8.2.4 Graphene and Derivatives -- 8.3 Polypyrrole/Metal Oxide Nanocomposites -- 8.3.1 Manganese Oxides.

8.3.2 Titanium Oxides -- 8.3.3 Ruthenium Oxides -- 8.3.4 Other Metal Oxides -- 8.4 Polypyrrole/Clay Nanocomposites -- 8.5 Other Polypyrrole/Inorganic Nanocomposites -- 8.6 Polypyrrole Ternary Composites -- 8.7 Conclusion and Perspectives -- Acknowledgments -- References -- Part 3: Advanced Materials for Environmental Applications -- 9 Intrinsically Conducting Polymer-Based Blends and Composites for Electromagnetic Interference Shielding: Theoretical and Experimental Aspects -- 9.1 Introduction -- 9.2 Shielding Phenomenon -- 9.2.1 Theoretical Shielding Effectiveness -- 9.2.2 Experimental Shielding Effectiveness -- 9.2.3 Complex Permittivity and Permeability -- 9.2.4 Shielding Materials and Design Considerations -- 9.2.5 Synthesis of ICPs-Based Hybrids (Blends and Composites) -- 9.2.6 Electrical Properties of ICPs-Based Blends and Composites -- 9.2.7 EMI Shielding Performance of ICPs-Loaded Blends and Composites -- 9.2.8 EMI Shielding Performance of ICP-Matrix-Based Composites -- 9.2.9 EMI Shielding and Microwave Absorbing Performance of ICPs/Filler Hybrid-Loaded Polymer Matrix Composites -- 9.3 Conclusions -- References -- 10 Anticorrosion Coatings Based on Conjugated Polymers -- 10.1 Introduction -- 10.2 Basic Concepts of Corrosion -- 10.3 Corrosion Prevention -- 10.4 Corrosion Tests -- 10.4.1 Immersion Tests -- 10.4.2 Cabinet Tests -- 10.4.3 Electrochemical Tests -- 10.5 Conjugated Polymers as Anticorrosion Layers -- 10.6 Conjugated Polymers Nanocomposite as Anticorrosion Layers -- 10.7 Conclusions -- References -- 11 Conjugated Polymer-Based Composites for Water Purification -- 11.1 Introduction -- 11.2 Adsorption Phenomenon -- 11.2.1 Adsorption Isotherms -- 11.2.2 Adsorption Kinetics -- 11.2.3 Adsorption Thermodynamics -- 11.3 PANI-Related Composites in Water Purification -- 11.3.1 PANI/Inorganic Composites -- 11.3.2 PANI/Organic Composites.

11.4 PPy-Related Composites in Water Purification -- 11.4.1 PPy/Inorganic Composites -- 11.4.2 PPy/Organic Composites -- 11.5 Miscellaneous Conjugated Polymer Composites in Water Purification -- 11.6 Conclusion -- Acknowledgment -- References -- Part 4: Sensing and Responsive Materials -- 12 Conjugated Polymer Nanocomposites-Based Chemical Sensors -- 12.1 Introduction -- 12.2 Conjugated Polymer Nanocomposites as Chemical Receptor -- 12.3 General Methods for Preparation of Conjugated Polymer Nanocomposite -- 12.3.1 Ex-situ Method -- 12.3.2 In-situ Method -- 12.4 Influence of Properties of Conjugated Polymer by Interaction with Nano-Filler -- 12.5 Fabrication of Conjugated Polymer Nanocomposite Layer/Film for Sensor -- 12.5.1 Electrochemical Deposition -- 12.5.2 Pellet Preparation -- 12.5.3 Dip Coating -- 12.5.4 Spin Coating -- 12.5.5 Drop Coating -- 12.5.6 Film Casting -- 12.5.7 Printing -- 12.5.8 Other Methods -- 12.6 Chemical Sensing Performance of Conjugated Polymer-Based Nanocomposites -- 12.6.1 Sensing by Conjugated Polymer/Organic Nanocomposites -- 12.6.2 Sensing by Conjugated Polymer/Inorganic Nanocomposites -- 12.7 Mechanism of Chemical Sensing by Conjugated Polymer Nanocomposite -- 12.7.1 Strong Chemical Interaction with the Conjugated Polymer -- 12.7.2 Weak Physical Interaction with the Conjugated Polymer -- 12.7.3 Weak Physical Interaction with the Nanomaterial -- 12.8 Challenges and Prospects 679 References -- 13 Conjugated Polymer Nanocomposites for Biosensors -- 13.1 Introduction -- 13.2 Synthesis of Conducting Polymer Nanocomposites -- 13.2.1 Conducting Polymer Nanocomposites with Carbon Nanotubes (CNTs) -- 13.2.2 Conducting Polymer Nanocomposites with Metal Nanoparticles -- 13.2.3 Conducting Polymer Nanocomposites with Metal Oxides -- 13.2.4 Conducting Polymer Nanocomposites with Metal Phthalocyanines and Porphyrins.

13.2.5 Conducting Polymer Nanocomposites with Biological Materials.
Abstract:
Foreword xvPreface xviPart 1: Multiphase Systems: Synthesis, Properties and Applications 11 Conjugated Polymer-based Blends, Copolymers, and Composites: Synthesis, Properties, and Applications 3Parveen Saini1.1 Introduction 41.2 CPs/ICPs-Based Blends 71.3 CPs/ICPs-Based Copolymers (CCPs) 111.4 CPs/ICPs-Based Composites/Nanocomposites/Hybrids 231.5 Interpenetrating/Semi-Interpenetrating   Polymer Network (IPN/SIPN) 291.6 Synthesis of CPs/ICPs-Based BLNs, CCPs, and CMPs/NCs/HYBs 301.7 Applications of CPs/ICPs-Based BLNs, CCPs, and CMPs/NCS/HYBs 631.8 Conclusions 79Acknowledgments 80References 80 2 Progress in Polyaniline Composites with Transition Metal Oxides 119Gordana Ciric-Marjanovic2.1 Introduction 1192.2 PANI/Transition Metal Oxide Composites 1202.3 Conclusions and Outlook 151Abbreviations 152References 1533 Conjugated-Polymer/Quantum-Confined Nanomaterials Hybrids for Optoelectronic Applications 163Anuushka Pal, Parveen Saini, and Sameer Sapra3.1 Introduction 1633.2 Quantum-Confined  Nanomaterials  (QCNs) 1653.3 Synthetic Approaches for Quantum-Confined Nanomaterials  (QCNs) 168  3.4 Optoelectronic Applications of Hybrids 1903.5 Outlook and Perspective: Current Challenges and Future Scope/Prospects 210Acknowledgments 211 References 2114 Graphene/Conjugated Polymer Nanocomposites for Optoelectronic and Biological Applications 229Tapas Kuila, Yu Dong Sheng, and Naresh Chandra Murmu4.1 Introduction 2304.2 Graphene/Conjugated Polymer Nanocomposites 2314.3 Applications of Graphene/Conjugated Polymer Nanocomposites 2634.4 Conclusions and Future Scope 270Acknowledgements 271References 271Part 2: Energy Harvesting and Storage Materials 2815 Conjugated Polymers-Based Blends, Composites and Copolymers for Photovoltaics 283Ashish Dubey, Parveen Saini, Vikram Kumar, and Qiquan Qiao5.1 Introduction 2845.2 Organic Photovoltaic (OPV) Cells 2845.3 OPV

Device Architecture and Working Mechanism 2875.4 Solar Cell Terminologies and Characterization Parameters 2905.5 CPs-Based Blends, Composites and Copolymers for OPVs 2955.6 Conjugated Copolymers for PVs 3145.7 Conclusions: Current Challenges and Prospects 326Acknowledgements 327References 3276 Conducting Polymer-Based Nanocomposites for Thermoelectric  Applications 339Qin Yao, Lidong Chen, and Sanyin Qu6.1 Introduction 3406.2 Synthesis Methods 3466.3 TE Properties of CP/Inorganic Nanocomposites 3616.4 Summary 376References 3777 Conjugated-Polymer/Inorganic Nanocomposites as Electrode Materials for Li-Ion Batteries 379Qingsheng Gao, Lichun Yang, and Ning Liu7.1 Introduction 3797.2 Nanocomposites of Conjugated Polymer/Inorganic as Cathode Materials 3837.3 Nanocomposites of Conjugated Polymers/Inorganic as Anode Materials 4027.4 Conclusion 412Acknowledgments 413References 4138 Polypyrrole/Inorganic Nanocomposites for Supercapacitors 419Peng Liu8.1 Introduction 4198.2 Polypyrrole/Carbon Nanocomposites 4208.3 Polypyrrole/Metal Oxide Nanocomposites 4328.4 Polypyrrole/Clay Nanocomposites 4378.5 Other Polypyrrole/Inorganic Nanocomposites 4388.6 Polypyrrole Ternary Composites 4398.7 Conclusion and Perspectives 443Acknowledgments 444References 444Part 3: Advanced Materials for Environmental Applications 4499 Intrinsically Conducting Polymer-Based Blends and Composites for Electromagnetic Interference Shielding: Theoretical and Experimental AspectsParveen Saini9.1 Introduction 4519.2 Shielding Phenomenon 4539.3 Conclusions 507References 50810 Anticorrosion Coatings Based on Conjugated Polymers 519M. Federica De Riccardis10.1 Introduction 51910.2 Basic Concepts of Corrosion 52210.3 Corrosion Prevention 52410.4 Corrosion Tests 52710.5 Conjugated Polymers as Anticorrosion Layers 53810.6 Conjugated Polymers Nanocomposite as Anticorrosion Layers 55210.7

Conclusions 574References 57511 Conjugated Polymer-Based Composites for Water Purification 581Jiaxing Li, Yongshun Huang, and Dadong Shao11.1 Introduction 58211.2 Adsorption Phenomenon 58311.3 PANI-Related Composites in Water Purification 59111.4 PPy-Related Composites in Water Purification 60111.5 Miscellaneous Conjugated Polymer Composites in Water Purification 60611.6 Conclusion 609Acknowledgment 609References 609Part 4: Sensing and Responsive Materials 61912 Conjugated Polymer Nanocomposites-Based Chemical Sensors 621Pradip Kar, Arup Choudhury, and Sushil Kumar Verma12.1 Introduction 62212.2 Conjugated Polymer Nanocomposites as Chemical Receptor 62612.3 General Methods for Preparation of Conjugated Polymer Nanocomposite 63112.4 Influence of Properties of Conjugated Polymer by Interaction with Nano-Filler 64412.5 Fabrication of Conjugated Polymer Nanocomposite Layer/Film for Sensor 64712.6 Chemical Sensing Performance of Conjugated Polymer-Based Nanocomposites 65612.7 Mechanism of Chemical Sensing by Conjugated Polymer Nanocomposite 67012.8 Challenges and Prospects 679References 68113 Conjugated Polymer Nanocomposites for Biosensors 687Deepshikha Saini13.1 Introduction 68713.2 Synthesis of Conducting Polymer Nanocomposites 69013.3 Current and Emerging Applications of Conducting Polymer Nanocomposites in Biosensors 70613.4 Conclusions and Outlook 719References 72214 Polyaniline Nanocomposites for Smart Electrorheological Fluid Applications 731Jianbo Yin and Xiaopeng Zhao14.1 Introduction 73114.2 PANI as Filler for ER Fluids 73414.3 Core/Shell-Structured PANI Nanocomposites for ER Fluids 73714.4 Pani-Intercalated Nanocomposites for ER Fluids 74714.5 Conclusions 752Acknowledgments 752References 752.
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Electronic reproduction. Ann Arbor, Michigan : ProQuest Ebook Central, 2017. Available via World Wide Web. Access may be limited to ProQuest Ebook Central affiliated libraries.
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