Inorganic Hydrazine Derivatives: Synthesis, Properties and Applications -- Contents -- List of Contributors -- Foreword -- Preface -- Acknowledgements -- 1 Hydrazine and Its Inorganic Derivatives -- 1.1 Introduction -- 1.1.1 Properties of Hydrazine -- 1.1.1.1 Redox Properties -- 1.1.2 Hydrazine versus Hydrazine Hydrate -- 1.1.2.1 Reducing Property of Hydrazine Hydrate -- 1.2 Inorganic Hydrazine Derivatives -- 1.2.1 Hydrazine Salts -- 1.2.1.1 Synthesis -- 1.2.1.2 Structure - Single-Crystal X-Ray Studies -- 1.2.2 Metal Hydrazines -- 1.2.2.1 Synthesis -- 1.2.2.2 Structure - Single-Crystal X-Ray Studies -- 1.2.3 Metal Hydrazine Carboxylates -- 1.2.3.1 Synthesis -- 1.2.3.2 Structure - Single-Crystal X-Ray Studies -- 1.2.4 Hydrazinium Metal Complexes -- 1.2.4.1 Synthesis -- 1.2.4.2 Structure - Single-Crystal X-Ray Studies -- 1.3 Characterization of Inorganic Hydrazine Derivatives -- 1.3.1 Analytical Techniques -- 1.3.2 Spectroscopic Methods -- 1.3.2.1 Infrared Spectroscopy -- 1.3.2.2 X-Ray Methods -- 1.3.3 Thermal Methods -- 1.4 Applications of Inorganic Hydrazine Derivatives -- References -- 2 Hydrazine Salts -- 2.1 Introduction -- 2.2 Salts of the Monovalent Cation (N2H5+) - N2H5A -- 2.2.1 Simple Hydrazinium Salts (A- = F, Cl, Br, I, NO3, N3, VO3, HF2, HSO4, SCN, SO3NH2, COOCH3) -- 2.2.1.1 Synthesis -- 2.2.1.2 Infrared Spectra -- 2.2.1.3 Thermal Properties -- 2.2.2 Hydrazinium Salts with Oxidizing Anions - N2H5A (A- = N3, NO2, NO3, ClO4, etc.) -- 2.2.2.1 Synthesis -- 2.2.2.2 Thermal Properties -- 2.3 Salts of the Divalent Cation [(N2H5) 2+ and N2H6 2+] -- 2.3.1 Dihydrazinium Salts (N2H5)2 2+) - [(N2H5)2B, B2-=SO3, SO4, C2O4, CO3, HPO4] -- 2.3.1.1 Synthesis, Infrared Spectra, and Thermal Properties -- 2.3.2 Hydrazonium Salts (N2H6 2+) - N2H6(A)2 or N2H6B -- 2.3.2.1 Synthesis, Infrared Spectra, and Thermal Properties.

2.4 Salts of Monovalent (N2H5 +) and Divalent [(N2H5)2 2+ , N2H6 2+] Cations -- 2.4.1 Hydrazine Fluorides - Hydrazinium Fluoride (N2H5F), Hydrazinium Bifluoride (N2H5HF2), and Hydrazonium Fluoride (N2H6F2) -- 2.4.1.1 Synthesis -- 2.4.1.2 Infrared Spectra -- 2.4.1.3 Thermal Properties -- 2.4.2 Hydrazine Sulfates - Hydrazinium Bisulfate (N2H5HSO4), Dihydrazinium Sulfate [(N2H5)2SO4], and Hydrazonium Sulfate (N2H6SO4) -- 2.4.2.1 Synthesis -- 2.4.2.2 Infrared Spectra -- 2.4.2.3 Thermal Properties -- 2.4.3 Hydrazine Oxalates - Hydrazinium Hydrogen Oxalate (N2H5HC2O4) and Dihydrazinium Oxalate [(N2H5)2C2O4] -- 2.4.3.1 Synthesis -- 2.4.3.2 Thermal Properties -- 2.4.4 Hydrazine Phosphates - Monohydrazinium Phosphate (N2H5H2PO4) and Dihydrazinium Phosphate [(N2H5)2HPO4] -- 2.4.4.1 Synthesis -- 2.4.4.2 Thermal Properties -- 2.4.5 Hydrazine Perchlorates - Hydrazinium Perchlorate (N2H5ClO4), Hydrazinium Perchlorate Monohydrate (N2H5ClO4H2O), Hydrazinium Perchlorate Hemihydrate (N2H5ClO40.5H2O), and Hydrazonium Perchlorate [N2H6(ClO4)2] -- 2.4.5.1 Synthesis -- 2.4.5.2 Infrared Spectra -- 2.4.5.3 Thermal Properties -- 2.4.5.4 Nature of Water Present in Hydrazinium Perchlorate Hydrates, N2H5ClO40.5H2O and N2H6(ClO4)22H2O -- 2.4.6 Hydrazine Perchlorate Ammoniates - N2H5ClO4NH3 and N2H6(ClO4)22NH3 -- 2.4.6.1 Synthesis, Infrared Spectra, and Thermal Properties -- 2.5 Hydrazine Salts of Organic Acids -- 2.6 Summary -- References -- 3 Metal Hydrazines -- 3.1 Introduction -- 3.2 Metal Hydrazines - MX(N2H4)n, M=metal, X=SO4, SO3, N3, NCS, NO3, ClO4, RCOO, and so on, (n=1-3) -- 3.2.1 Metal Isothiocyanate Hydrazines [M(NCS)2 (N2H4)2] -- 3.2.2 Metal Sulfate Hydrazines [MSO4xN2H4] -- 3.2.3 Metal Formate Hydrazines [M(HCOO)2(N2H4)2] -- 3.2.4 Metal Acetate Hydrazines [M(CH3COO)2(N2H4)2] -- 3.2.4.1 Mixed Metal Acetate Hydrazines.

3.2.5 Metal Oxalate Hydrazines [MC2O4(N2H4)2] -- 3.2.5.1 Synthesis -- 3.2.5.2 Spectral and Thermal Analysis -- 3.2.5.3 Temperature Profile Studies -- 3.2.6 Mixed Metal Oxalate Hydrazines -- 3.2.7 Metal Sulfite Hydrazine Complexes -- 3.2.7.1 Metal Sul.te Hydrazines [MSO3xN2H4yH2O] -- 3.2.7.2 Mixed Metal Sulfite Hydrazines -- 3.2.7.3 Magnesium Bisulfite Hydrazine Hydrate -- 3.2.8 Metal Azide Hydrazines [M(N3)2(N2H4)2] -- 3.2.8.1 Synthesis -- 3.2.8.2 Spectral, Structural, and Thermal Data -- 3.2.8.3 Dinitrogen Compound -- 3.2.9 Metal Nitrate Hydrazines [M(NO3)2(N2H4)n] -- 3.2.9.1 Synthesis -- 3.2.10 Metal Perchlorate Hydrazines [M(ClO4)2(N2H4)2] -- 3.2.10.1 Synthesis and Properties -- 3.2.11 Metal Hydrazines of Organic Acids -- 3.3 Reactivity of Metal Salt Hydrazines (from Detonation to Deflagration to Decomposition) -- 3.3.1 Precautions in Handling Explosive Materials -- 3.4 Summary -- References -- 4 Metal Hydrazine Carboxylates -- 4.1 Introduction -- 4.2 Metal Hydrazine Carboxylates - M(N2H3COO)2 -- 4.3 Metal Hydrazine Carboxylate Hydrates - M(N2H3COO)nxH2O -- n=2, 3 -- 4.3.1 Lead Hydroxy Metal Hydrazine Carboxylate Hydrates - [PbMO(OH)2(N2H3COO)2xH2O] -- 4.3.2 Rare Earth Metal Hydrazine Carboxylate Hydrates - Ln(N2H3COO)33H2O -- 4.3.3 Metal Ion Doped Metal Hydrazine Carboxylate Hydrates -Mx+/M(N2H3COO)2xH2O -- 4.3.3.1 Manganese-Substituted Calcium Hydrazine Carboxylate Hydrate -- 4.3.3.2 Praseodymium-Substituted Cerium Hydrazine Carboxylate Hydrate -- 4.3.3.3 Europium-Substituted Yttrium Hydrazine Carboxylate Hydrate -- 4.4 Metal Hydrazine Carboxylate Hydrazines - M(N2H3COO)2(N2H4)2 -- 4.5 Hydrazinium Metal Hydrazine Carboxylate Hydrates - N2H5M(N2H3COO)3H2O -- 4.5.1 Cobalt-Substituted Hydrazinium Iron Hydrazine Carboxylate Hydrate -- 4.5.2 Manganese-Substituted Hydrazinium Zinc Hydrazine Carboxylate Hydrate.

4.6 Solid Solutions of Hydrazinium Metal Hydrazine Carboxylate Hydrates - N2H5M1/3 (Co/Fe/Mn)2/3 (N2H3COO)3H2O -- 4.6.1 Synthesis -- 4.6.2 XRD Data -- 4.6.3 Thermal Properties -- 4.7 Summary -- References -- 5 Hydrazinium Metal Complexes -- 5.1 Introduction -- 5.2 Hydrazinium Metal Sulfates -- 5.2.1 Hydrazinium Metal Sulfates - (N2H5)2M(SO4)2 -- 5.2.1.1 Synthesis, Spectra, and Thermal Analysis -- 5.2.1.2 Single-Crystal Structures of (N2H5)2M(SO4)2, M = Transition Metal -- 5.2.2 Hydrazinium Rare Earth Metal Sulfate Hydrates - N2H5Ln(SO4)2H2O -- 5.2.2.1 Synthesis, Spectra, and Thermal Analysis -- 5.2.2.2 Single-Crystal Structure of N2H5Nd(SO4)2H2O -- 5.3 Hydrazinium Metal Oxalates -- 5.3.1 Hydrazinium Metal Oxalates - (N2H5)2M (C2O4)2nH2O,M= Co, Ni, Cu, and so on -- 5.3.1.1 Synthesis, Spectra, and Thermal Analysis -- 5.3.1.2 Single-Crystal Structure of (N2H5)2Cu (C2O4)2nH2O -- 5.3.2 Hydrazinium Uranyl Oxalates -- 5.3.2.1 Synthesis, Spectra, and Thermal Analysis -- 5.3.2.2 Single-Crystal Structures of (N2H5)6[(UO2)2(C2O4)5]2H2O and (N2H5)2(UO2)(C2O4)2H2O -- 5.4 Hydrazinium Metal Halides -- 5.4.1 Hydrazinium Metal Chloride Hydrates - (N2H5)2MCl42H2O,M= Transition Metal -- 5.4.1.1 Synthesis, Spectra, and Thermal Analysis -- 5.4.1.2 Single-Crystal Structures of (N2H5)2FeCl42H2O and (N2H5)2PtCl42H2O -- 5.4.2 Hydrazinium Metal Bromide Hydrates - (N2H5)2MBr44H2O,M= Transition Metal -- 5.4.2.1 Synthesis, Spectra, and Thermal Analysis -- 5.4.3 Anhydrous Hydrazinium Metal Chlorides - N2H5CuCl3, (N2H5)2ZnCl4, (N2H5)3MnCl5, and (N2H5)4FeCl6 -- 5.4.3.1 Synthesis, Spectra, and Thermal Analysis -- 5.4.3.2 Single-Crystal Structure of (N2H5)3MnCl5 -- 5.5 Hydrazinium Metal Thiocyanates - (N2H5)2M(NCS)42H2O,M= Co and Ni -- 5.5.1 Synthesis, Spectra, and Thermal Analysis -- 5.5.2 Single-Crystal Structure of (N2H5)2Co (NCS)42H2O.

5.6 Recent Studies on Hydrazinium Metal Complexes -- 5.7 Summary -- References -- 6 Applications of Inorganic Hydrazine Derivatives -- 6.1 Introduction -- 6.2 Applications of Hydrazine Salts -- 6.2.1 Synthesis of Hydrazinium Metal Complexes -- 6.2.2 Solid-State Synthesis of Ammonium Vanadyl Complex -- 6.2.3 Synthesis of 4-Amino-3,5-dimethyl-1,2,4-triazole -- 6.2.4 Hydrazinium Phosphates as Flame Retardants -- 6.2.5 Hydrazinium Thiocyanate as Analytical Reagent for the Quantitative Estimation of Copper -- 6.3 Energetic Materials -- 6.3.1 Explosives and Initiators -- 6.3.2 Energetic Oxidizers for Solid Propellants -- 6.3.2.1 Metal Perchlorate Hydrazines -- 6.3.2.2 Magnesium-Doped N2H5ClO40.5H2O -- 6.4 Combustible Metal Hydrazine Complexes -- 6.4.1 Synthesis of γ-Fe2O3 - Recording Material -- 6.4.2 Synthesis of Nano-Copper Chromite (CuCr2O4) Catalyst -- 6.4.3 Synthesis of Lithium Metal Oxide (LiMO2) - Battery Material -- 6.4.4 Synthesis of Nano-Titania - Photocatalyst -- 6.4.5 Metal Ion Substituted Oxide Materials -- 6.4.6 Synthesis of Nano-Cobaltites, -Ferrites, -Chromites, and -Manganites -- 6.4.7 Synthesis of Nano-Metal Powders as Catalysts -- 6.5 Miscellaneous Applications -- 6.5.1 Reducing Agents -- 6.5.2 Antibacterial Agents -- 6.5.2.1 Antibacterial Activity Testing -- 6.5.3 Synthesis of 1D and 2D Nanostructures -- References -- Index.