Synthesis, characterization and computational studies of oxomolybdenum compounds with nitrogen donor ligands
tarafından
Kıyak, Harika.
Başlık
:
Synthesis, characterization and computational studies of oxomolybdenum compounds with nitrogen donor ligands
Yazar
:
Kıyak, Harika.
Yazar Ek Girişi
:
Kıyak, Harika.
Yayın Bilgileri
:
[s.l.]: [s.n.], 2010.
Fiziksel Tanımlama
:
xii, 153 leaves.: ill. + 1 computer laser optical disc.
Özet
:
In the first part of the project, the reactions of the solvent-stabilized compound [MoO2Cl2(THF)2] with varios phenylenediamine and some napthalenediamin derivatives in THF at room temperature were investigated. These reactions yielded mononuclear and dinuclear compounds of the type [MoO2Cl2L] and [Mo2O3(.2- O)Cl4(L)2] respectively. In the second part, the reactions of [Mo2O3Cl4(DMF)4] with phenylenediamine and napthalenediamin derivatives were studied under similar conditions and Mo-O-Mo bridged dinuclear oxomolybdenum compounds of the type [Mo2O3(.2-O)Cl4(L)] were obtained. The new compounds were comparatively examined by elemental analysis, FTIR, 1H-NMR and 13C-NMR techniques. In addition, quantum chemical calculations including semi empirical PM3 and DFT methods were carried out to discuss the stability and geometry of the compounds.
Konu Başlığı
:
Molybdenum compounds.
Molybdenum -- Analysis.
Yazar Ek Girişi
:
Topaloğlu Sözüer, Işıl.
Tüzel Kişi Ek Girişi
:
İzmir Institute of Technology. Chemistry
Tek Biçim Eser Adı
:
Thesis (Master)--İzmir Institute of Technology:Chemistry.
İzmir Institute of Technology:Chemistry--Thesis (Master).
Elektronik Erişim
:
Library | Materyal Türü | Demirbaş Numarası | Yer Numarası | Durumu/İade Tarihi |
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IYTE Library | Tez | T000827 | QD181.M7 K99 2010 | Tez Koleksiyonu |