Separation of trace antimony and arsenic prior to hydride generation atomic absortion spectrometric determination
tarafından
Yersel, Müşerref.
Başlık
:
Separation of trace antimony and arsenic prior to hydride generation atomic absortion spectrometric determination
Yazar
:
Yersel, Müşerref.
Yazar Ek Girişi
:
Yersel, Müşerref.
Yayın Bilgileri
:
[s.l.]: [s.n.], 2005
Fiziksel Tanımlama
:
xi, 37 leaves.: ill. + 1 computer laser optical disc
Özet
:
A separation method utilizing a synthetic zeolite (mordenite) was developed in order to eliminate the gas phase interference of Sb(III) on As(III) during quartz furnace hydride generation atomic absorption spectrometric (HGAAS) determination. The efficiency of the proposed separation method in the reduction of suppression effects of several metal ions on As(III) signal was also investigated. Among the volatile hydride forming elements and their different oxidation states tested (Sb(III), Sb(V), Se(IV), Se(VI), Te(IV), and Te(VI)), only Sb(III) was found to have a signal depression effect even at low (µg l-1) concentrations under the experimental conditions employed. It has been shown that mordenite adsorbs Sb(III) quantitatively, even at a concentration of 1000 µg l-1, at pHs greater than 2, and also, it reduces the initial concentrations of the metal ions to lower levels which can be tolerated in many studies. The adsorption of Sb(III) on mordenite follows the Freundlich isotherm and is endothermic in nature.
Konu Başlığı
:
Arsenic
Antimony
Atomic absorption spectroscopy
Yazar Ek Girişi
:
Eroğlu, Ahmet E.thesis advisor.
Tüzel Kişi Ek Girişi
:
İzmir Institute of Technology. Chemistry
Tek Biçim Eser Adı
:
Thesis (Master)--İzmir Institute of Technology:Chemistry
İzmir Institute of Technology:Chemistry--Thesis (Master).
Elektronik Erişim
:
Library | Materyal Türü | Demirbaş Numarası | Yer Numarası | Durumu/İade Tarihi |
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IYTE Library | Tez | T000392 | TP245.A8.Y47 2005 C.1 | Tez Koleksiyonu |