Rhodium-catalyzed reactions of (Z)-2-EN-4yne acetates with arylboronic acids
tarafından
Karakuş, Erman.
Başlık
:
Rhodium-catalyzed reactions of (Z)-2-EN-4yne acetates with arylboronic acids
Yazar
:
Karakuş, Erman.
Yazar Ek Girişi
:
Karakuş, Erman.
Yayın Bilgileri
:
[s.l.]: [s.n.], 2011.
Fiziksel Tanımlama
:
x, 188 leaves.: ill. + 1 computer laser optical disc.
Özet
:
This study is the first example of rhodium(I)-catalyzed arylative SN2ʺ type reaction of (Z)-2-en-4-yne acetates with arylboronic acids leading to E-configured vinyl-allenes with an aryl moiety. The coordinative interaction of the rhodium with carbonyl oxygen promoted the -elimination of Rh(I)-OAc from the alkenylrhodium intermediate in both syn- and anti-modes, with the syn-elimination being the major path. DFT calculations revealed that a conformer of this intermediate which can lead to the E-configured vinylallene product via the syn-elimination mode, is energetically the most favorable conformer. The rhodium-catalyzed procedure is not applicable to reactions involving (E)- configured enyne acetates, because the geometry of the alkenylrhodium intermediate that is derived from the corresponding E-enyne acetate would not allow such coordinative interaction to occur.
Konu Başlığı
:
Rhodium catalysts.
Acetates.
Yazar Ek Girişi
:
Artok, Levent.
Tüzel Kişi Ek Girişi
:
İzmir Institute of Technology. Chemistry.
Tek Biçim Eser Adı
:
Thesis (Master)--İzmir Institute of Technology: Chemistry.
İzmir Institute of Technology: Chemistry--Thesis (Master).
Elektronik Erişim
:
Kütüphane | Materyal Türü | Demirbaş Numarası | Yer Numarası | Durumu/İade Tarihi |
---|
IYTE | Tez | T000914 | QD505 .K181 2011 | Tez Koleksiyonu |