Development of thin film composite nanofiltration membranes with layer by layer polyelectrolyte deposition
tarafından
 
Tekinalp, Önder, author.

Başlık
Development of thin film composite nanofiltration membranes with layer by layer polyelectrolyte deposition

Yazar
Tekinalp, Önder, author.

Yazar Ek Girişi
Tekinalp, Önder, author.

Fiziksel Tanımlama
xii, 62 leaves:+ 1 computer laser optical disc.

Özet
Nanofiltration (NF) membranes are usually prepared in thin film composite (TFC) structure through polymerization of various monomers or coating of previously synthesized polymer on porous support membranes. Layer by layer (LbL) deposition of polyelectrolytes on a porous support is a facile and convenient method for the sake of producing NF membranes. This study intends to manufacture TFC NF membrane via alternating polyelectrolyte deposition with limited number of layers on polysulfone/sulfonated polyethersulfone (PSF/SPES) porous support membrane. Polyethyleneimine (PEI) and alginate (ALG) were chosen as polyelectrolyte pairs. The support membranes with different pore sizes were prepared via nonsolvent induced phase inversion method by changing compositions and thickness of casting solution as well as composition of coagulation bath. The polyelectrolytes were deposited dynamically in a dead end filtration module at 1 bar. The influences of supporting electrolyte, polyelectrolyte pH and concentration as well as type of coating method on the membrane performances were investigated. The membranes were characterized by SEM, AFM, staining, and contact angle measurements. Stability and fouling tendency of produced membranes were determined. It was demonstrated that NF membrane (83% PEG1000 rejection) with a high flux (14 L/m2.h.bar) can be manufactured by depositing only a single layer of PEI. Further deposition of ALG on PEI-coated membrane resulted in water permeability of 15.5±0.3 L/m2.h.bar with 89.1±0.6% PEG1000 rejection by adjusting PSF:SPES ratio to 4:1.

Konu Başlığı
Membrane separation.
 
Nanofiltration.

Yazar Ek Girişi
Alsoy Altınkaya, Sacide,

Tüzel Kişi Ek Girişi
İzmir Institute of Technology. Chemical Engineering.

Tek Biçim Eser Adı
Thesis (Master)--İzmir Institute of Technology: Chemical Engineering.
 
İzmir Institute of Technology: Chemical Engineering--Thesis (Master).

Elektronik Erişim
Access to Electronic Versiyon.


LibraryMateryal TürüDemirbaş NumarasıYer Numarası
IYTE LibraryTezT001626TP248.25.M46 T26 2017