Snythesis and spectroscopic characterization of some new [tris (3,5-dimethyl-pyrazol) borato] molybdebum complexex
tarafından
İrdem, Seçkin Dülger.
Başlık
:
Snythesis and spectroscopic characterization of some new [tris (3,5-dimethyl-pyrazol) borato] molybdebum complexex
Yazar
:
İrdem, Seçkin Dülger.
Yazar Ek Girişi
:
İrdem, Seçkin Dülger.
Yayın Bilgileri
:
[s.l.]: [s.n.], 2003.
Fiziksel Tanımlama
:
xiv, 60 leaves. : ill.+ 1 computer laser optical disc.
Özet
:
In this study, the new binuclear oxo bridged imido Mo(V) complexes [MoTp*(O)Cl](.-O)[MoTp*(Cl)(.NC6H4X)], (p-X . Cl, Br) and [MoTp*(O)Cl](.-O) [MoTp*(Cl)(.NC6H4Y)], (m-Y . I, F) have been synthesized by the reaction oxo molybdenum (V) precursor [MoTp*(O)Cl2]; [Tp* . Tris(3, 5-dimethyl-pyrazol)borato] with p- and m- functionalized anilines, H2NC6H4X and H2NC6H4Y (p-X . Cl, Br; m-Y.I, F) in toluene solution.The complexes have been characterised by 1H-NMR, IR spectroscopy and FAB-Mass spectrometry.The structures of [MoTp*(O)Cl](.-O)[MoTp*(Cl)(.NC6H4X)], (p-X . Br) and [MoTp*(O)Cl](.-O)[MoTp*(Cl)(.NC6H4Y)], (m-Y . I, F) have been characterised by X-Ray diffaction method.
Konu Başlığı
:
Molybdenum compounds.
Yazar Ek Girişi
:
Topaloğlu Sözüer, Işıl.
Tüzel Kişi Ek Girişi
:
İzmir Institute of Technology. Chemistry.
Tek Biçim Eser Adı
:
Thesis (Master)--İzmir Institute of Technology:Chemistry.
İzmir Institute of Technology:Chemistry--Thesis (Master).
Elektronik Erişim
:
| Library | Materyal Türü | Demirbaş Numarası | Yer Numarası | Durumu/İade Tarihi |
|---|
| IYTE Library | Tez | T000252 | QD181.M7 I65 2003 | Tez Koleksiyonu |