Oxo-Imido molybdenum tripyrazolyl borate complexes
tarafından
Günyar, Alev.
Başlık
:
Oxo-Imido molybdenum tripyrazolyl borate complexes
Yazar
:
Günyar, Alev.
Yazar Ek Girişi
:
Günyar, Alev.
Yayın Bilgileri
:
[s.l.]: [s.n.], 2004
Fiziksel Tanımlama
:
xii, 56 leaves.:ill.+ 1 computer laser optical disc
Özet
:
Reaction of the oxo-molybdenum(V) compound, [MoTp*(O)Cl2], [Tp* . hydrotris(3,5-dimetylpyrazol-1-yl)borate] with p-functionalized anilines[NH2C6H4R]( R . OMe, OEt, OPr, NO2) in the presence of Et3N under nitrogen, in toluene solution,afforded the novel oxo bridged oxo(arylimido) molybdenum(V) compounds [MoTp*(O)Cl](m-O)[MoTp*(Cl)(NC6H4R)] ( R . OMe, OEt, OPr, NO2). Under same conditions, the reaction with aniline produced oxo bridged oxomolybdenum (V) compound, [MoTp*OCl]2(m-O).The new compounds were characterized by FT-IR, FAB-Mass, and 1H-NMR spectra. The single crystal X-ray crystallographic determination of [MoTp*(O)Cl](m-O)[MoTp*(Cl)(NC6H4OMe)] was carried out to confirm that there is a Mo-O-Mo bridge and a near linear arylimido group in the structure.
Konu Başlığı
:
Borates.
Scorpionates
Yazar Ek Girişi
:
Topaloğlu Sözüer, Işıl
Tüzel Kişi Ek Girişi
:
İzmir Institute of Technology. Chemistry
Tek Biçim Eser Adı
:
Thesis (Master)--İzmir Institute of Technology:Chemistry
İzmir Institute of Technology:Chemistry--Thesis (Master).
Elektronik Erişim
:
Library | Materyal Türü | Demirbaş Numarası | Yer Numarası | Durumu/İade Tarihi |
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IYTE Library | Tez | T000464 | QD181.B1 G57 2004 | Tez Koleksiyonu |