Oxo-Imido molybdenum tripyrazolyl borate complexes
tarafından
 
Günyar, Alev.

Başlık
Oxo-Imido molybdenum tripyrazolyl borate complexes

Yazar
Günyar, Alev.

Yazar Ek Girişi
Günyar, Alev.

Yayın Bilgileri
[s.l.]: [s.n.], 2004

Fiziksel Tanımlama
xii, 56 leaves.:ill.+ 1 computer laser optical disc

Özet
Reaction of the oxo-molybdenum(V) compound, [MoTp*(O)Cl2], [Tp* . hydrotris(3,5-dimetylpyrazol-1-yl)borate] with p-functionalized anilines[NH2C6H4R]( R . OMe, OEt, OPr, NO2) in the presence of Et3N under nitrogen, in toluene solution,afforded the novel oxo bridged oxo(arylimido) molybdenum(V) compounds [MoTp*(O)Cl](m-O)[MoTp*(Cl)(NC6H4R)] ( R . OMe, OEt, OPr, NO2). Under same conditions, the reaction with aniline produced oxo bridged oxomolybdenum (V) compound, [MoTp*OCl]2(m-O).The new compounds were characterized by FT-IR, FAB-Mass, and 1H-NMR spectra. The single crystal X-ray crystallographic determination of [MoTp*(O)Cl](m-O)[MoTp*(Cl)(NC6H4OMe)] was carried out to confirm that there is a Mo-O-Mo bridge and a near linear arylimido group in the structure.

Konu Başlığı
Borates.
 
Scorpionates

Yazar Ek Girişi
Topaloğlu Sözüer, Işıl

Tüzel Kişi Ek Girişi
İzmir Institute of Technology. Chemistry

Tek Biçim Eser Adı
Thesis (Master)--İzmir Institute of Technology:Chemistry
 
İzmir Institute of Technology:Chemistry--Thesis (Master).

Elektronik Erişim
Access to Electronic Version.


LibraryMateryal TürüDemirbaş NumarasıYer NumarasıDurumu/İade Tarihi
IYTE LibraryTezT000464QD181.B1 G57 2004Tez Koleksiyonu