Palladium catalyzed cross coupling reactions of alkenyl epoxides and organoboronic acid esters
tarafından
 
Eren, Ahmet, author.

Başlık
Palladium catalyzed cross coupling reactions of alkenyl epoxides and organoboronic acid esters

Yazar
Eren, Ahmet, author.

Yazar Ek Girişi
Eren, Ahmet, author.

Fiziksel Tanımlama
x, 92 leaves: illustrarions, charts;+ 1 computer laser optical disc.

Özet
In organic chemistry, it is a useful method to form a new allylic compounds as a result of 1-3 substitution reactions of allylic compounds which have a good leaving group. These reactions usually require a metal catalyst but one of the most challenging aspects of these applications is the process regio and stereo selectivity for a wide variety of substrate types. Other compounds such as alkenyl epoxides are also useful for 1-3 substitution reactions. An advantage of using alkenyl oxirane compounds is that the oxirane ring is opened in the substitution step to form a hydroxyl group and resulted in the formation of allylic alcohols which are important intermediate product. Metal catalysed and regioselective reactions of terminal alkenyl epoxides with organoborons have been reported in the literature. However, there is no successful method for internal alkenyl oxiranes. Thus, in this study, 1-3 substitution reactions of alkenyl oxiranes were successfully applied, which yielded allylic alcohols with high regio- and stereoselectivity.

Konu Başlığı
Palladium catalysts.

Yazar Ek Girişi
Artok, Levent,

Tüzel Kişi Ek Girişi
İzmir Institute of Technology. Chemistry.

Tek Biçim Eser Adı
Thesis (Master)--İzmir Institute of Technology: Chemistry.
 
İzmir Institute of Technology: Chemistry--Thesis (Master).

Elektronik Erişim
Access to Electronic Versiyon.


LibraryMateryal TürüDemirbaş NumarasıYer NumarasıDurumu/İade Tarihi
IYTE LibraryTezT001740QD505 .E67 2018Tez Koleksiyonu