Palladium catalyzed cross coupling reactions of alkenyl epoxides and organoboronic acid esters için kapak resmi
Palladium catalyzed cross coupling reactions of alkenyl epoxides and organoboronic acid esters
Başlık:
Palladium catalyzed cross coupling reactions of alkenyl epoxides and organoboronic acid esters
Yazar:
Eren, Ahmet, author.
Yazar Ek Girişi:
Fiziksel Tanımlama:
x, 92 leaves: illustrarions, charts;+ 1 computer laser optical disc.
Özet:
In organic chemistry, it is a useful method to form a new allylic compounds as a result of 1-3 substitution reactions of allylic compounds which have a good leaving group. These reactions usually require a metal catalyst but one of the most challenging aspects of these applications is the process regio and stereo selectivity for a wide variety of substrate types. Other compounds such as alkenyl epoxides are also useful for 1-3 substitution reactions. An advantage of using alkenyl oxirane compounds is that the oxirane ring is opened in the substitution step to form a hydroxyl group and resulted in the formation of allylic alcohols which are important intermediate product. Metal catalysed and regioselective reactions of terminal alkenyl epoxides with organoborons have been reported in the literature. However, there is no successful method for internal alkenyl oxiranes. Thus, in this study, 1-3 substitution reactions of alkenyl oxiranes were successfully applied, which yielded allylic alcohols with high regio- and stereoselectivity.
Konu Başlığı:
Yazar Ek Girişi:
Tek Biçim Eser Adı:
Thesis (Master)--İzmir Institute of Technology: Chemistry.

İzmir Institute of Technology: Chemistry--Thesis (Master).
Elektronik Erişim:
Access to Electronic Versiyon.
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