
Dendrimers : Towards Catalytic, Material and Biomedical Uses.
Başlık:
Dendrimers : Towards Catalytic, Material and Biomedical Uses.
Yazar:
Caminade, Anne-Marie.
ISBN:
9781119976523
Yazar Ek Girişi:
Basım Bilgisi:
1st ed.
Fiziksel Tanımlama:
1 online resource (558 pages)
İçerik:
Dendrimers: Towards Catalytic, Material and Biomedical Uses -- Contents -- Preface -- Part 1: Generalities, Syntheses, Characterizations, and Physicochemical Properties -- 1: Syntheses of Dendrimers and Dendrons -- 1.1 Introduction: What Are Dendrimers and Dendrons? -- 1.2 Syntheses of Poly(propyleneimine) Dendrimers (PPI) -- 1.3 Synthesis of Poly(amidoamine) Dendrimers (PAMAM) -- 1.4 Syntheses of Poly(ether) Dendrimers -- 1.5 Syntheses of Poly(ester) Dendrimers -- 1.6 Synthesis of Poly(lysine) Dendrimers -- 1.7 Syntheses of Silicon-Containing Dendrimers -- 1.8 Syntheses of Phosphorus-Containing Dendrimers -- 1.9 Syntheses of Carbon-Based Dendrimers -- 1.10 Syntheses of Dendrimers Constituted of Nitrogen Heterocycles -- 1.11 Syntheses by Self-Assembly -- 1.12 Accelerated Syntheses -- 1.13 Conclusion -- References -- 2: Methods of Characterization of Dendrimers -- 2.1 Introduction -- 2.2 Spectroscopy and Spectrometry -- 2.2.1 Nuclear Magnetic Resonance (NMR) -- 2.2.2 Mass Spectrometry -- 2.2.3 X-ray Diffraction -- 2.2.4 Infrared (IR) and Raman Spectroscopy -- 2.2.5 Ultraviolet-Visible (UV-vis) Spectroscopy -- 2.2.6 Fluorescence -- 2.2.7 Chirality, Optical Rotation, and Circular Dichroism (CD) -- 2.2.8 Electron Paramagnetic Resonance (EPR) -- 2.2.9 Electrochemistry -- 2.2.10 Magnetometry -- 2.2.11 Mössbauer Spectroscopy -- 2.2.12 X-ray Spectroscopies -- 2.3 Scattering Techniques -- 2.3.1 Laser Light Scattering (LLS) -- 2.3.2 Small-Angle Neutron Scattering (SANS) -- 2.3.3 Small-Angle X-ray Scattering (SAXS) and Wide-Angle X-ray Scattering (WAXS) -- 2.4 Microscopy -- 2.4.1 Transmission Electron Microscopy (TEM) -- 2.4.2 Atomic Force Microscopy (AFM) -- 2.4.3 Polarizing Optical Microscopy (POM) -- 2.5 Rheology and Physical Characterizations -- 2.5.1 Intrinsic Viscosity -- 2.5.2 Differential Scanning Calorimetry (DSC).
2.5.3 Dielectric Spectroscopy (DS) -- 2.5.4 Dipole Moments -- 2.6 Separation Techniques -- 2.6.1 Size Exclusion Chromatography -- 2.6.2 Electrophoresis -- 2.7 Conclusion -- References -- 3: Luminescent Dendrimers -- 3.1 Introduction -- 3.2 Dendrimers with Fluorescent Terminal Groups -- 3.2.1 Fully Substituted Dendrimers -- 3.2.2 Partially Substituted Dendrimers -- 3.3 Luminescent Group at the Core of Dendrimers and Energy/Light-Harvesting Properties -- 3.3.1 Organic Fluorophores as Cores -- 3.3.2 Porphyrins and Phthalocyanines as Cores -- 3.3.3 Metallic Cores -- 3.4 Fluorescent Groups inside the Structure of Dendrimers -- 3.5 Intrinsically Fluorescent Dendrimers -- 3.5.1 Fluorescent Groups throughout the Dendrimeric Structure -- 3.5.2 Fluorescence of Dendrimers without Known Fluorophores -- 3.6 Two-Photon-Excited Fluorescence of Dendrimers -- 3.7 Conclusion -- References -- 4: Stimuli-Responsive Dendrimers -- 4.1 Introduction -- 4.2 Photoresponsive Dendrimeric Structures -- 4.2.1 Azobenzene-Containing Dendrimers and Dendrons -- 4.2.2 Other Types of Photoresponsive Dendrimers -- 4.3 Thermoresponsive Dendrimeric Structures -- 4.3.1 Thermoresponsive Properties of Dendrimers -- 4.3.2 Thermoresponsive Properties of Dendrons and Dendronized Polymers -- 4.4 Dendrimers Responsive to Solution Media Changes -- 4.4.1 pH-Responsive Dendrimers -- 4.4.2 Dendrimers Disassembly -- 4.5 Conclusion -- References -- 5: Liquid Crystalline Dendrimers -- 5.1 Introduction -- 5.2 Mesogenic Groups as Terminal Functions of Dendrons -- 5.3 Mesogenic Groups as Terminal Functions of Dendrimers -- 5.4 Mesogenic Groups as Branches of Dendrimers -- 5.5 Conclusion -- References -- 6: Dendrimers and Nanoparticles -- 6.1 Introduction -- 6.2 Dendrimers or Dendrons for Coating Nanoparticles -- 6.2.1 Dendronization of Nanoparticles by Ligand Exchange.
6.2.2 Direct Synthesis of Dendronized Nanoparticles -- 6.2.3 Dendrimer Coated Nanoparticles -- 6.2.4 Nanocomposites with Interdendrimer Nanoparticles -- 6.3 Dendrimers as Templates for the Synthesis of Dendrimer-Encapsulated Nanoparticles (DENs ) -- 6.3.1 Catalysis with Dendrimer-Encapsulated Nanoparticles -- 6.3.2 Other Uses of Dendrimer-Encapsulated Nanoparticles -- 6.4 Conclusion and Perspectives -- References -- Part 2: Applications in Catalysis -- 7: Terminal Groups of Dendrimers as Catalysts for Homogeneous Catalysis -- 7.1 General Introduction -- 7.1.1 The "Dendrimer Effect" -- 7.1.2 Recycling the Catalysts -- 7.2 Catalytic Organometallic Sites as Catalysts for Homogeneous Catalysis -- 7.2.1 Formation of C-X Bond (X = C, N, O) -- 7.2.2 Addition Reactions on a C=X Double Bond (X = C, O) -- 7.2.3 Oxidation Reactions -- 7.3 Organocatalysis with Dendrimers -- 7.4 Conclusion -- References -- 8: Catalytic Sites inside the Dendrimeric Structure for Homogeneous Catalysis -- 8.1 Introduction -- 8.2 Catalytic Sites as the Core of Dendrimers -- 8.2.1 Dendrimers Bearing a Transition-Metal-Based Complex at the Core -- 8.2.2 Dendrimers Bearing an Organocatalyst at the Core -- 8.3 Catalytic Sites inside the Branches of Dendrimers -- 8.3.1 Formation of C-X Bonds (X = C, N, O) -- 8.3.2 Addition Reactions on a C=C Double Bond: Olefin Hydrogenation -- 8.4 Conclusion -- References -- 9: Dendrimers as Homogeneous Enantioselective Catalysts -- 9.1 Introduction -- 9.2 Catalytic Organometallic Sites as Catalysts for Homogeneous Catalysis -- 9.2.1 Formation of C-X Bonds (X = C, N, O) -- 9.2.2 Addition Reactions on a C=X Double Bond (X = C, O) -- 9.3 Organocatalysis with Dendrimers -- 9.3.1 Aldolizations -- 9.3.2 Aza-Morita-Baylis-Hillmann Reactions -- 9.3.3 Transaminations -- 9.4 Conclusion -- References -- 10: Catalysis with Dendrimers in Particular Media.
10.1 Introduction -- 10.2 Two-Phase (Liquid-Liquid) Media -- 10.3 Catalysis in Ionic Liquids -- 10.4 Catalysis in Supercritical Media -- 10.5 Catalysis in Aqueous Media -- 10.6 Conclusions -- References -- 11: Heterogeneous Catalysis with Dendrimers -- 11.1 Introduction -- 11.2 Catalysis with Dendrons Synthesized from a Solid Material -- 11.2.1 Silica as an Inorganic Support -- 11.2.2 Polymers and Resins as Organic Supports -- 11.3 Catalysis with Dendrons or Dendrimers Grafted on to a Solid Surface -- 11.4 Catalysis with Insoluble Dendrimers -- 11.5 Conclusion -- References -- Part 3: Applications for the Elaboration or Modifications of Materials -- 12: Dendrimers inside Materials -- 12.1 Introduction -- 12.2 Dendrimers for the Elaboration of Gels -- 12.2.1 Dendrimers for the Elaboration of Supramolecular Hydrogels -- 12.2.2 Dendrimers for the Elaboration of Polymer-Type Hydrogels -- 12.2.3 Dendrimers for the Elaboration of Organogels -- 12.3 Dendrimers inside Silica Gels -- 12.4 Dendrimers inside Other Types of Materials -- 12.5 Dendrimers for the Elaboration of OLEDs -- 12.5.1 Fluorescent Dendrimers for the Elaboration of OLEDs -- 12.5.2 Phosphorescent Dendrimers for the Elaboration of OLEDs -- 12.6 Conclusion -- References -- 13: Self-Assembly of Dendrimers in Layers -- 13.1 Introduction -- 13.2 Langmuir-Blodgett Films of Dendrons and Dendrimers -- 13.2.1 Poly(benzyl ether) Derivatives -- 13.2.2 Poly(amidoamine) and Poly(propyleneimine) Derivatives -- 13.2.3 Azobenzene Derivatives -- 13.2.4 Poly(carbosilane) Dendrimer Derivatives -- 13.2.5 Fullerene C60 Derivatives -- 13.2.6 Other Examples -- 13.3 Assemblies of Dendrons and Dendrimers on Solid Surfaces -- 13.3.1 Assembly of Dendrons and Dendrimers on Gold Surfaces -- 13.3.2 Assembly of Dendrons and Dendrimers on Silicon Substrates or Related Substrates.
13.4 Several Routes for the Formation of Dendron or Dendrimer Multilayers -- 13.5 Nanoimprinting of Dendrons and Dendrimers on Solid Surfaces -- 13.5.1 Dendrimer-Based Self-Assembled Monolayers as Resists for Scanning Probe Lithography -- 13.5.2 Microprinting, Transfer Printing, and Dip-Pen Nanolithography with Dendrimers -- 13.6 Conclusion -- References -- 14: Dendrimers as Chemical Sensors -- 14.1 Introduction -- 14.2 Dendrimers as Chemical Sensors in Solution -- 14.2.1 Porphyrins and Other Macrocyclic Derivatives as the Core or Branches of Dendrimeric Sensors -- 14.2.2 Terminal Groups of Dendrimers as Sensors in Solution -- 14.3 Dendrimers as Electrochemical Sensors -- 14.4 Dendrimers on Modified Surfaces as Chemical Sensors -- 14.4.1 Dendrimers on Surfaces at the Interface with a Solution -- 14.4.2 Dendrimers on Surfaces at the Interface with a Vapor -- 14.5 Conclusion -- References -- 15: Dendrimers as Biological Sensors -- 15.1 Introduction -- 15.2 Dendrimers as Sensors in Solutions of Biological Media -- 15.3 Detection by Electrochemical Methods -- 15.4 Dendrimers or Dendrons for DNA Microarrays -- 15.5 Dendrimers for Other Types of Biomicroarrays -- 15.6 Dendrimers on Other Types of Support -- 15.7 Dendrimers as Multiply Labeled Entities Connected to the Target -- 15.8 Conclusion -- References -- Part 4: Applications in Biology/Medicine -- 16: Dendrimers for Imaging -- 16.1 Introduction -- 16.2 Magnetic Resonance Imaging with Dendrimers -- 16.2.1 Paramagnetic Dendrimer-Based Contrast Agents -- 16.2.2 PARACEST Dendrimer-Based Contrast Agents -- 16.2.3 Superparamagnetic Dendrimer-Based Contrast Agents -- 16.2.4 Dendrimer-Based 129Xe HYPER-CEST MRI Contrast Agents -- 16.2.5 19F Dendrimer-Based MRI Contrast Agents -- 16.3 Other Types of Imaging with Dendrimers -- 16.3.1 Dendrimers for Optical Imaging.
16.3.2 Dendrimers for Nuclear Medicine (NM) Imaging and Computed Tomography X-Ray Imaging (CT).
Özet:
This book will be mainly focussed on the properties and uses of dendrimers and dendrons. The aim of this book is to be the reference book about dendrimers applications. It will not describe all details, but it will give the reader a unique overview of what has currently been done with dendrimers, with numerous references and illustrations. It will be divided in four main parts: Part 1) Generalities, syntheses, characterizations and properties; Part 2) Applications in catalysis; Part 3) Applications for the elaboration or modification of materials; and Part 4) Applications in biology/medicine. The role of the nanometric size and the multiple functions of dendrimers on the properties will be emphasized.
Notlar:
Electronic reproduction. Ann Arbor, Michigan : ProQuest Ebook Central, 2017. Available via World Wide Web. Access may be limited to ProQuest Ebook Central affiliated libraries.
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