Front Cover -- Solvent Extraction: Classical and Novel Approaches -- Copyright -- Contents -- Preface -- Introduction -- References -- Part I - Conventional (Classical) Principles and Practice of Solvent Extraction -- Chapter 1 - Modern (Classical) Fundamental Principles of Solvent Extraction -- 1. Introduction -- 2. Solvent Extraction By Solvation -- 3. Solvent Extraction with Chemical Reactions (By Complexation) -- 4. Driving Forces of Solvent Extraction -- 5. Influence of Kinetics Factors -- 6. Selectivity -- 7.Factors Affecting Extraction Process -- 8.Module Design Considerations -- 9.Experimental Determination of Distribution Ratios -- 10.Summarizing Remarks -- References -- Chapter 2 - Principles of Solvent Extraction of Organic and Mineral Acids -- 1. Introduction -- 2. Extraction of Acids by Carbon-Bonded Oxygen-Donor Extractants and Substituted Hydrocarbon Solvents -- 3. Phosphorus-bonded Oxygen Donor Extractants -- 4. Aliphatic Amine Extractants -- 5. Extraction of Strong (Inorganic) Acids -- 6. Summarizing Remarks -- References -- Chapter 3 - Chemistry of Metal Solvent Extraction -- 1.Introduction -- 2. Metal Extraction by Cation Exchangers (Acidic Extractants) -- 3 .Metal Extraction by Anion Exchangers (Ion Pair Formation) -- 4. Extraction Through Formation of H-Bonding and Solvating Complexes -- 5. Extraction Through Mixed Complex Formation -- 6. Extractable Complexation of Monovalent Metals -- 7. Extraction with Aqueous Biphasic Systems -- References -- Chapter 4 - Engineering Development of Solvent Extraction Processes -- 1. Introduction -- 2. Extraction Stage -- 3 .Stripping Organic Solutions -- 4 .Extraction Efficiency -- 5 .Equipment Design For Continuous Extraction-Stripping Processes -- 6.Solvent Losses -- 7.Economical Considerations -- 8. Problems With Scale-Up To Industrial Systems -- References.

Chapter 5 - Examples of Application of Solvent Extraction Techniques in Chemical, Radiochemical, Biochemical, Pharmaceutical, Analytical Separations, and Wastewater Treatment -- 1. Introduction -- 2. Extraction in Hydrometallurgy (Metals Extraction) -- 3.Solvent Extraction in Nuclear Chemistry and Technology -- 4. Solvent Extraction in Analytical Chemistry -- 5. Application of Solvent Extraction in Biochemical and Pharmaceutical Separations -- 6. Application of Solvent Extraction in Organic and Biofuels Separation -- 7.Solvent Extraction in Recovery of Waste and Wastewater Treatment -- References -- Part II - Novel Competitive Complexation/Solvation Theory (CCST) of Solvent Extraction: Principles and Practice -- Chapter 6 - Backgrounds of the Competitive Complexation/Solvation Theory of Solvent Extraction -- 1. Introduction -- 2. Complexation Through the H-Bonding and Proton Transfer -- 3. Distribution Isotherm -- 4. Modified Competitive Preferential Solvation Theory -- 5. Electronic Acid-Base Theory and Amphoterity -- 6. Aggregation -- References -- Chapter 7 - Competitive Complexation/Solvation Theory of Solvent Extraction: General Mechanisms and Kinetics -- 1. Basic Statements -- 2. traction Systems with Low Solute Concentrations in Organic Phase -- 3. Systems with Medium Concentrations of the Solute -- 4. Systems with High Solute Concentrations -- 5. Comparison of Conventional and Presented Theories Description -- 6. Summarizing Remarks for the CCST -- References -- Chapter 8 - CCST in Engineering Design, Procedures, and Calculations -- 1. Introduction -- 2.ngineering Considerations in Experimental Investigation of CCST -- 3. Experimental Techniques for the Presented Theory -- 4.Determination of Extraction Constant and its Comparison with Ccst Affinity Constant Ratios -- 5. Analytical methods used for the CCST verification.

6. Transferability of the Values of Affinity Constant Ratios -- References -- Chapter 9 - The CCST in Solvent Extraction of Acids by Amine-Based Extractants -- 1. Introduction -- 2. Acid-Amine Systems in the CCST Interpretation -- 3. The Systems with Active Solvent as an Additive -- 4. Experimental Application of the CCST in Carboxylic Acids Extraction -- 5. Summarizing Remarks -- References -- Chapter 10-Competitive Complexation/Solvation Theory in MetalSolvent Extraction -- 1. Introduction -- 2. Ccst Basic Statements -- 3. Mathematical Supplement For The Ccst In Metalextraction -- 4. Experimental Verification Of The Ccst Approach -- 5. Summarizing Remarks -- References -- Chapter 11 - Final Remarks on the Competitive Complexation/Solvation Theory of Solvent Extraction and its Application -- Part III - Modern and Future Trends in Fundamentals and Applications of Solvent Extraction -- 1 - Introduction -- Chapter 12 - Modern and Future Trends in Fundamentals of Solvent Extraction -- 1.Introduction -- 2. Novel Molecular Models Theoretical Approach -- 3. Low Energy Reactions Measurement -- 4 . Expected Advances in Kinetics Studies -- 5.Supramolecular (SUPRAS) Theoretical Approach -- References -- Chapter 13 - Advances in Development of Solvents for Liquid-Liquid Extraction -- 1. Introduction -- 2. Organic Solvents -- 3. Water as a Solvent -- 4. Renewable Water-Based Solvents -- 5. Ionic Liquids as Solvents for Extraction -- 6. Amphiphilic Compounds (Supramolecules) as Solvents in Solvent Extraction -- 7. Extraction by Microemulsion -- 8. Recovery of Reagents -- 9. Future Trends in the Development of New Solvents -- 10. Concluding Remarks -- References -- Chapter 14 - Recent Advances in Solvent Extraction Processes and Techniques -- 1. Introduction -- 2 .Equipment Design and Scale-up Considerations -- 3. Supercritical Fluid Extraction.

4 .Subcritical Water Extraction -- 5. Aqueous Two-Phase Systems -- 6. Extraction Processes with Ionic Liquids -- 7. Liquid Membrane and Nondispersive, Membrane-Based Solvent Extraction Techniques -- 8. Supramolecular-Based Extraction Techniques -- 9. Solid-Liquid Extraction Systems -- 10. Assisted Solvent Extracion -- 11. Extraction of Gas in Analytical Applications -- References -- Appendix -- 1. Fundamental Constants -- 2. SI fundamental (a) and derived (b) Units used in the book -- 3. Abbreviations for different Parameters, Constants, Coefficients, Commonly Used in book -- 4. Abbreviations for processes and techniques, described in the book -- 5. Abbreviations for Solvent extraction equipment -- 6. Detection techniques in analytical chemistry, connected with solvent extraction pretreatment -- 7. Abbreviations for Inorganic Compounds -- 8. Abbreviations for Organic Compounds -- 9. Structures of some extractants -- 10. Some Examples of Metal Complexes -- 11. Abbreviations for Environmental Protection Organisations and Program Mentioned in Book -- Referenced Sources for Appendix data -- Index.