Oxo-Imido molybdenum tripyrazolyl borate complexes için kapak resmi
Oxo-Imido molybdenum tripyrazolyl borate complexes
Başlık:
Oxo-Imido molybdenum tripyrazolyl borate complexes
Yazar:
Günyar, Alev.
Yazar Ek Girişi:
Yayın Bilgileri:
[s.l.]: [s.n.], 2004
Fiziksel Tanımlama:
xii, 56 leaves.:ill.+ 1 computer laser optical disc
Özet:
Reaction of the oxo-molybdenum(V) compound, [MoTp*(O)Cl2], [Tp* . hydrotris(3,5-dimetylpyrazol-1-yl)borate] with p-functionalized anilines[NH2C6H4R]( R . OMe, OEt, OPr, NO2) in the presence of Et3N under nitrogen, in toluene solution,afforded the novel oxo bridged oxo(arylimido) molybdenum(V) compounds [MoTp*(O)Cl](m-O)[MoTp*(Cl)(NC6H4R)] ( R . OMe, OEt, OPr, NO2). Under same conditions, the reaction with aniline produced oxo bridged oxomolybdenum (V) compound, [MoTp*OCl]2(m-O).The new compounds were characterized by FT-IR, FAB-Mass, and 1H-NMR spectra. The single crystal X-ray crystallographic determination of [MoTp*(O)Cl](m-O)[MoTp*(Cl)(NC6H4OMe)] was carried out to confirm that there is a Mo-O-Mo bridge and a near linear arylimido group in the structure.
Konu Başlığı:

Yazar Ek Girişi:
Tek Biçim Eser Adı:
Thesis (Master)--İzmir Institute of Technology:Chemistry

İzmir Institute of Technology:Chemistry--Thesis (Master).
Elektronik Erişim:
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