Characterization and catalytic applications of hydrothermally synthesized poyoxotungstate clusters containing organic-inorganic hybrid materials için kapak resmi
Characterization and catalytic applications of hydrothermally synthesized poyoxotungstate clusters containing organic-inorganic hybrid materials
Başlık:
Characterization and catalytic applications of hydrothermally synthesized poyoxotungstate clusters containing organic-inorganic hybrid materials
Yazar:
Ece, Özlem, author.
Yazar Ek Girişi:
Fiziksel Tanımlama:
xii, 99 leaves: color illustrarions, charts;+ 1 computer laser optical disc
Özet:
Many scientists have been interested in hydrothermal synthesis and characterization of polyoxometalate clusters containing organic-inorganic hybrid materials recently because of having different applications in lots of fields, especially, using as catalysis in chemical reactions. In this study, three novel polyoxotungstate clusters were synthesized using hydrothermal method and catalytic activities of these three novel polyoxometalates and in addition two crystals previously synthesized in our group were studied. The first compound, [(4,4’-bpyH2)3][PCuW11O39] yellow crystals, crystallize in the space group P2(1)/n of the monoclinic system with four formula units in a cell. The crystal is a Keggin polyoxometalate and includes free 4,4’-bipyridine groups between the clusters. The second compound, (4,4’-bpyH2)[H2PW12O40]2.H2O colorless crystals, crystallize in the space group Ia-3 of the cubic system with twelve formula units in a cell. The crystal is a Keggin polyoxometalate and consists of two polyoxotungstate clusters, a free 4,4’-bipyridine group and a water molecule. The third and the last novel compound, (4,4’-bpyH2)4[H2P2W18O62]2 dark yellow crystals, crystallize in the space group P-1 of the triclinic system with four formula units in a cell. The crystal is a Wells-Dawson polyoxometalate and contains two polyoxotungstate clusters and free 4,4’-bipyridine groups between clusters. The catalytic study has been carried out using starch hydrolysis reactions by using hydrothermal synthesis and five different crystals were tried and conversion results were obtained. Starch samples converted to D-glucose with glucose yields above 90 wt.%. Catalyst reusability was performed for each crystal. No appreciable loss was observed in activity after five reaction cycles for each crystal.
Yazar Ek Girişi:
Tek Biçim Eser Adı:
Thesis (Doctoral)--İzmir Institute of Technology:Chemistry.

İzmir Institute of Technology:Chemistry--Thesis (Doctoral).
Elektronik Erişim:
Access to Electronic Versiyon.
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