Snythesis and spectroscopic characterization of some new [tris (3,5-dimethyl-pyrazol) borato] molybdebum complexex için kapak resmi
Snythesis and spectroscopic characterization of some new [tris (3,5-dimethyl-pyrazol) borato] molybdebum complexex
Başlık:
Snythesis and spectroscopic characterization of some new [tris (3,5-dimethyl-pyrazol) borato] molybdebum complexex
Yazar:
İrdem, Seçkin Dülger.
Yazar Ek Girişi:
Yayın Bilgileri:
[s.l.]: [s.n.], 2003.
Fiziksel Tanımlama:
xiv, 60 leaves. : ill.+ 1 computer laser optical disc.
Özet:
In this study, the new binuclear oxo bridged imido Mo(V) complexes [MoTp*(O)Cl](.-O)[MoTp*(Cl)(.NC6H4X)], (p-X . Cl, Br) and [MoTp*(O)Cl](.-O) [MoTp*(Cl)(.NC6H4Y)], (m-Y . I, F) have been synthesized by the reaction oxo molybdenum (V) precursor [MoTp*(O)Cl2]; [Tp* . Tris(3, 5-dimethyl-pyrazol)borato] with p- and m- functionalized anilines, H2NC6H4X and H2NC6H4Y (p-X . Cl, Br; m-Y.I, F) in toluene solution.The complexes have been characterised by 1H-NMR, IR spectroscopy and FAB-Mass spectrometry.The structures of [MoTp*(O)Cl](.-O)[MoTp*(Cl)(.NC6H4X)], (p-X . Br) and [MoTp*(O)Cl](.-O)[MoTp*(Cl)(.NC6H4Y)], (m-Y . I, F) have been characterised by X-Ray diffaction method.
Konu Başlığı:
Yazar Ek Girişi:
Tek Biçim Eser Adı:
Thesis (Master)--İzmir Institute of Technology:Chemistry.

İzmir Institute of Technology:Chemistry--Thesis (Master).
Elektronik Erişim:
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