Integration of red & blue TL materials to different polymer end-use için kapak resmi
Integration of red & blue TL materials to different polymer end-use
Başlık:
Integration of red & blue TL materials to different polymer end-use
Yazar:
İncel, Anıl, author.
Yazar Ek Girişi:
Fiziksel Tanımlama:
xii, 54 leaves: color illustraltions.+ 1 computer laser optical disc.
Özet:
Triboluminescence (TL) is known as the emission of light upon the application of any mechanical force. In this master thesis, two organometallic-based TL crystals, which are EuD4TEA and Cu(NCS)(py)2(PPh3) were obtained and they were integrated in the transparent polymers: poly (methylmetacrylate) (PMMA), poly (styrene) (PS), poly (urethane) (PU) and polyvinylidene fluoride (PVDF) for different end-use. In the development of composites, two different processes were carried out: i) embedding (or blending) and ii) surface impregnation. The different end-use polymers were used as transparent polymer film, electrospun nanofibers, and nanobeads. TL performance of composites were investigated by using drop tower system which was specficically designed for this research. Atomic force microscopy (AFM), scanning electron microscopy (SEM) were used to characterize the topographic and morphologic properties of both polymers and composites. Additionally, fluorescence microscopy helped to understand the signal of emitted light by composites. Lastly, piezoelectric properties of composite materials were invetigated by oscilloscope. According to results, type of process, particle size of crystal, surface property and form of host material (polymer), the concentration of crystalline particles in composites were determined as the main parameters and the results were estimated with respect to these parameters. PU-based composite film and fiber show better stability towards mechnical stress rather than PMMA, PS, and PVDF due to the roughness surface of thin-film surface for film-based composites, smallest wickerwork formation of electrospun mats for fiber-based composite, and the chemical affinity of PU with TL crystals.
Yazar Ek Girişi:
Tek Biçim Eser Adı:
Thesis (Master)--İzmir Institute of Technology:Materials Science and Engineering.

İzmir Institute of Technology:Materials Science and Engineering--Thesis (Master).
Elektronik Erişim:
Access to Electronic Versiyon.
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